一种新型C60-硫醚衍生物分子在金表面上的自组装

doi:10.3866/PKU.WHXB20011104

Acta Phys. -Chim. Sin. ›› 2001, Vol. 17 ›› Issue (11): 978-981.doi: 10.3866/PKU.WHXB20011104

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FullereneTerminated SAMs on Gold(111)：Formation and Characterization

Dong Dong;Zhang Sheng;Zhu Tao;Gan Liang-Bing;Liu Zhong-Fan

Center for Nanoscale Science ＆ Technology (CNST) and State Key Laboratory of Rare Earth Materials Chemistry ＆ Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing　100871

Received:2001-04-02 Revised:2001-06-28 Published:2001-11-15
Contact: Liu Zhong-Fan E-mail:lzf@chem.pku.edu.cn

Abstract

Abstract: We report in this paper the formation of new fullereneterminated selfassembled monolayers(SAMs) from the adsorption of unsymmetrical dialkylmonosulfide compound onto the Au(111) substrate via goldsulfur bonding. The highresolution STM images verified that C60 moieties are located at the outer surface and the XPS results provided clear evidence for S－C cleavage and Au－S bonding during the selfassembling process of this specific C60organosulfide on gold.

Key words: Fullerene, Organosulfide, Gold(111), SAM, STM, XPS

Dong Dong;Zhang Sheng;Zhu Tao;Gan Liang-Bing;Liu Zhong-Fan. FullereneTerminated SAMs on Gold(111)：Formation and Characterization[J]. Acta Phys. -Chim. Sin. 2001, 17(11), 978-981. doi: 10.3866/PKU.WHXB20011104

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FullereneTerminated SAMs on Gold(111)：Formation and Characterization

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