基于裂结技术的单分子尺度化学反应研究进展

doi:10.3866/PKU.WHXB201811027

Abstract

Abstract:

Molecular electronics has been the subject of increasing interest since 1974. Although it describes the utilization of single molecules as active components of electrical devices, molecular electronics remains a fundamental subject to date. Considering that the length of a single molecule is typically several nanometers, the electrical characterization of a probe molecule is a significant experimental challenge. A metal/molecule/metal junction can bridge the gap between nanometer-sized molecules and the macroscopic measuring circuit and is, thus, generally considered as the most common prototype in molecular electronics. For the fabrication and characterization of single-molecule junctions, break junction methods, which include the mechanically controllable break junction (MCBJ) technique and the scanning tunneling microscopy-break junction (STM-BJ) technique, were proposed at the turn of the century and have been developed rapidly in recent years. These methods are widely employed in the experimental study of charge transport through single-molecule junctions and provide a platform to investigate the physical and chemical processes at the single-molecule level. In this review, we mainly focus on MCBJ and STM-BJ techniques applicable for single-molecule conductance measurement and highlight the progress of these techniques in the context of identification and modulation of chemical reactions and evaluation of their reaction kinetics at the single-molecule level. We begin by presenting the operation principles of MCBJ and STM-BJ and stating their brief comparison. Subsequently, we summarize the recent advances in modulating single-molecule chemical reactions. In this regard, we introduce several examples that involve changing the environmental solution, applying an external electrical field, and resorting to electrochemical gating. Next, we overview the application of the break junction techniques in the investigation of reaction kinetics at the single-molecule level. In this section, we also present a brief introduction to studies on single-molecule reaction kinetics using graphene-based nanogaps, wherein conventional metallic electrodes were replaced by graphene electrodes. Furthermore, we discuss the combination of break junction techniques and surface-enhanced Raman spectroscopy for detecting single-molecule reactions occurring at nanometer-scale separation. We discuss the historical development of this combined method and present the latest advancement explaining the origin of the low conductance of 1, 4-benzenedithiol, which is a topic of significant concern in single-molecule electronics. Finally, we discuss some future issues in molecular electronics, including the expansion from simple molecules to complex molecular systems and the introduction of multi-physical fields into single-molecule junctions. Moreover, we provide a list of critical characterization tools in molecular electronics and discuss their potential applications.

Key words: Molecular electronics, Single molecule, Charge transport, Mechanically controllable break junction, STM break junction

Peikai YU, Anni FENG, Shiqiang ZHAO, Junying WEI, Yang YANG, Jia SHI, Wenjing HONG. Recent Progress of Break Junction Technique in Single-Molecule Reaction Chemistry[J]. Acta Physico-Chimica Sinica 2019, 35(8), 829-839. doi: 10.3866/PKU.WHXB201811027

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References 69

1	Aviram A. ; Ratner M. A. Chem. Phys. Lett. 1974, 29 (2), 277. doi: 10.1016/0009-2614(74)85031-1
2	Reed M. A. ; Zhou C. ; Muller C. J. ; Burgin T. P. ; Tour J. M. Science 1997, 278 (5336), 252. doi: 10.1126/science.278.5336.252
3	Xu B. ; Tao N. J. Science 2003, 301 (5637), 1221. doi: 10.1126/science.1087481
4	Guo X. ; Small J. P. ; Klare J. E. ; Wang Y. ; Purewal M. S. ; Tam I. W. ; Hong B. H. ; Caldwell R. ; Huang L. ; O'Brien S. ; et al Science 2006, 311 (5759), 356. doi: 10.1126/science.1120986
5	Yang Y. ; Liu J. Y. ; Yan R. W. ; Wu D. Y. ; Tian Z. Q. Chem. J. Chin. Univ. 2015, 36 (1), 9. doi: 10.7503/cjcu20140941
	杨扬; 刘俊扬; 晏润文; 吴德印; 田中群. 高等学校化学学报, 2015, 36 (1), 9. doi: 10.7503/cjcu20140941
6	Ho Choi S. ; Kim B. ; Frisbie C. D. Science 2008, 320 (5882), 1482. doi: 10.1126/science.1156538
7	Cai Z. ; Lo W. ; Zheng T. ; Li L. ; Zhang N. ; Hu Y. ; Yu L. J. Am. Chem. Soc. 2016, 138 (33), 10630. doi: 10.1021/jacs.6b05983
8	Zhen S. ; Mao J. C. ; Chen L. ; Ding S. ; Luo W. ; Zhou X. S. ; Qin A. ; Zhao Z. ; Tang B. Z. Nano Lett. 2018, 18 (7), 4200. doi: 10.1021/acs.nanolett.8b01082
9	Chen L. ; Wang Y. H. ; He B. ; Nie H. ; Hu R. ; Huang F. ; Qin A. ; Zhou X. S. ; Zhao Z. ; Tang B. Z. Angew. Chem. Int. Ed. 2015, 54 (14), 4231. doi: 10.1002/anie.201411909
10	Jia C. ; Migliore A. ; Xin N. ; Huang S. ; Wang J. ; Yang Q. ; Wang S. ; Chen H. ; Wang D. ; Feng B. ; et al Science 2016, 352 (6292), 1443. doi: 10.1126/science.aaf6298
11	Su T. A. ; Li H. ; Steigerwald M. L. ; Venkataraman L. ; Nuckolls C. Nat. Chem. 2015, 7, 215. doi: 10.1038/nchem.2180
12	Frisbie C. D. Science 2016, 352 (6292), 1394. doi: 10.1126/science.aag0827
13	Wen H. ; Li W. ; Chen J. ; He G. ; Li L. ; Olson M. A. ; Sue A. C. H. ; Stoddart J. F. ; Guo X. Sci. Adv. 2016, 2 (11), 1601113. doi: 10.1126/sciadv.1601113
14	Díez-Pérez I. ; Hihath J. ; Lee Y. ; Yu L. ; Adamska L. ; Kozhushner M. A. ; Oleynik I. I. ; Tao N. Nat. Chem. 2009, 1, 635. doi: 10.1038/nchem.392
15	Chen X. P. ; Roemer M. ; Yuan L. ; Du W. ; Thompson D. ; del Barco E. ; Nijhuis C. A. Nat. Nanotechnol. 2017, 12 (8), 797. doi: 10.1038/nnano.2017.110
16	Xiang D. ; Wang X. ; Jia C. ; Lee T. ; Guo X. Chem. Rev. 2016, 116 (7), 4318. doi: 10.1021/acs.chemrev.5b00680
17	Tao N. J. Nat. Nanotechnol. 2006, 1 (3), 173. doi: 10.1038/nnano.2006.130
18	Quek S. Y. ; Kamenetska M. ; Steigerwald M. L. ; Choi H. J. ; Louie S. G. ; Hybertsen M. S. ; Neaton J. B. ; Venkataraman L. Nat. Nanotechnol. 2009, 4, 230. doi: 10.1038/nnano.2009.10
19	Yang G. ; Wu H. ; Wei J. ; Zheng J. ; Chen Z. ; Liu J. ; Shi J. ; Yang Y. ; Hong W. Chin. Chem. Lett. 2018, 29 (1), 147. doi: 10.1016/j.cclet.2017.06.015
20	Venkataraman L. ; Klare J. E. ; Nuckolls C. ; Hybertsen M. S. ; Steigerwald M. L. Nature 2006, 442, 904. doi: 10.1038/nature05037
21	Mao J. C. ; Peng L. L. ; Li W. Q. ; Chen F. ; Wang H. G. ; Shao Y. ; Zhou X. S. ; Zhao X. Q. ; Xie H. ; Niu Z. J. J. Phys. Chem. C 2017, 121 (3), 1472. doi: 10.1021/acs.jpcc.6b10925
22	Martin C. A. ; Ding D. ; Sorensen J. K. ; Bjornholm T. ; van Ruitenbeek J. M. ; van der Zant H. S. J. J. Am. Chem. Soc. 2008, 130 (40), 13198. doi: 10.1021/ja804699a
23	Smit R. H. M. ; Noat Y. ; Untiedt C. ; Lang N. D. ; van Hemert M. C. ; van Ruitenbeek J. M. Nature 2002, 419, 906. doi: 10.1038/nature01103
24	Kiguchi M. ; Miura S. ; Hara K. ; Sawamura M. ; Murakoshi K. Appl. Phys. Lett. 2007, 91 (5), 053110. doi: 10.1063/1.2757592
25	Yang Y. ; Liu J. ; Zheng J. ; Lu M. ; Shi J. ; Hong W. ; Yang F. ; Tian Z. Nano Res. 2017, 10 (10), 3314. doi: 10.1007/s12274-017-1544-0
26	Li Y. ; Demir F. ; Kaneko S. ; Fujii S. ; Nishino T. ; Saffarzadeh A. ; Kirczenow G. ; Kiguchi M. Phys. Chem. Chem. Phys. 2015, 17 (48), 32436. doi: 10.1039/c5cp05227k
27	Peng L. L. ; Chen F. ; Hong Z. W. ; Zheng J. F. ; Fillaud L. ; Yuan Y. ; Huang M. L. ; Shao Y. ; Zhou X. S. ; Chen J. Z. ; et al Nanoscale 2018, 10 (15), 7026. doi: 10.1039/c8nr00625c
28	Hong Z. W. ; Aissa M. A. B. ; Peng L. L. ; Xie H. ; Chen D. L. ; Zheng J. F. ; Shao Y. ; Zhou X. S. ; Raouafi N. ; Niu Z. J. Electrochem. Commun. 2016, 68, 86. doi: 10.1016/j.elecom.2016.05.002
29	Li H. X. ; Su T. A. ; Camarasa-Gomez M. ; Hernangomez-Perez D. ; Henn S. E. ; Pokorny V. ; Caniglia C. D. ; Inkpen M. S. ; Korytar R. ; Steigerwald M. L. ; et al Angew. Chem. Int. Ed. 2017, 56 (45), 14145. doi: 10.1002/anie.201708524
30	Wang Y. H. ; Hong Z. W. ; Sun Y. Y. ; Li D. F. ; Han D. ; Zheng J. F. ; Niu Z. J. ; Zhou X. S. J. Phys. Chem. C 2014, 118 (32), 18756. doi: 10.1021/jp505374v
31	Guo X. F. ; Gorodetsky A. A. ; Hone J. ; Barton J. K. ; Nuckolls C. Nat. Nanotechnol. 2008, 3 (3), 163. doi: 10.1038/nnano.2008.4
32	Zhou C. ; Li X. X. ; Gong Z. L. ; Jia C. C. ; Lin Y. W. ; Gu C. H. ; He G. ; Zhong Y. W. ; Yang J. L. ; Guo X. F. Nat. Commun. 2018, 9, 807. doi: 10.1038/s41467-018-03203-1
33	Moreland J. ; Ekin J. W. J. Appl. Phys. 1985, 58 (10), 3888. doi: 10.1063/1.335608
34	Xiang D. ; Jeong H. ; Lee T. ; Mayer D. Adv. Mater. 2013, 25 (35), 4845. doi: 10.1002/adma.201301589
35	Wang L. ; Wang L. ; Zhang L. ; Xiang D. Top. Current Chem. 2017, 375 (3), 61. doi: 10.1007/s41061-017-0149-0
36	Reichert J. ; Ochs R. ; Beckmann D. ; Weber H. B. ; Mayor M. ; Löhneysen H. V. Phys. Rev. Lett. 2002, 88 (17), 176804. doi: 10.1103/PhysRevLett.88.176804
37	Yang Y. ; Gantenbein M. ; Alqorashi A. ; Wei J. ; Sangtarash S. ; Hu D. ; Sadeghi H. ; Zhang R. ; Pi J. ; Chen L. ; et al J. Phys. Chem. C 2018, 122 (26), 14965. doi: 10.1021/acs.jpcc.8b03023
38	Sun Y. Y. ; Peng Z. L. ; Hou R. ; Liang J. H. ; Zheng J. F. ; Zhou X. Y. ; Zhou X. S. ; Jin S. ; Niu Z. J. ; Mao B. W. Phys. Chem. Chem. Phys. 2014, 16 (6), 2260. doi: 10.1039/c3cp53269k
39	Wen H. M. ; Yang Y. ; Zhou X. S. ; Liu J. Y. ; Zhang D. B. ; Chen Z. B. ; Wang J. Y. ; Chen Z. N. ; Tian Z. Q. Chem. Sci. 2013, 4 (6), 2471. doi: 10.1039/C3SC50312G
40	Liu J. ; Zhao X. ; Al-Galiby Q. ; Huang X. ; Zheng J. ; Li R. ; Huang C. ; Yang Y. ; Shi J. ; Manrique D. Z. ; et al Angew. Chem. Int. Ed. 2017, 56 (42), 13061. doi: 10.1002/anie.201707710
41	Yang G. ; Sangtarash S. ; Liu Z. ; Li X. ; Sadeghi H. ; Tan Z. ; Li R. ; Zheng J. ; Dong X. ; Liu J. ; et al Chem. Sci. 2017, 8 (11), 7505. doi: 10.1039/C7SC01014A
42	Perrin M. L. ; Verzijl C. J. O. ; Martin C. A. ; Shaikh A. J. ; Eelkema R. ; van Esch J. H. ; van Ruitenbeek J. M. ; Thijssen J. M. ; van der Zant H. S. J. ; Dulić D. Nat. Nanotechnol. 2013, 8, 282. doi: 10.1038/nnano.2013.26
43	Song H. ; Kim Y. ; Jang Y. H. ; Jeong H. ; Reed M. A. ; Lee T. Nature 2009, 462 (7276), 1039. doi: 10.1038/nature08639
44	Xiang D. ; Jeong H. ; Kim D. ; Lee T. ; Cheng Y. ; Wang Q. ; Mayer D. Nano Lett. 2013, 13 (6), 2809. doi: 10.1021/nl401067x
45	Aragonès A. C. ; Haworth N. L. ; Darwish N. ; Ciampi S. ; Bloomfield N. J. ; Wallace G. G. ; Diez-Perez I. ; Coote M. L. Nature 2016, 531, 88. doi: 10.1038/nature16989
46	Zhang L. ; Laborda E. ; Darwish N. ; Noble B. B. ; Tyrell J. H. ; Pluczyk S. ; Le Brun A. P. ; Wallace G. G. ; Gonzalez J. ; Coote M. L. ; et al J. Am. Chem. Soc. 2018, 140 (2), 766. doi: 10.1021/jacs.7b11628
47	Xiao X. Y. ; Xu B. Q. ; Tao N. J. Nano Lett. 2004, 4 (2), 267. doi: 10.1021/nl035000m
48	Darwish N. ; Díez-Pérez I. ; Da Silva P. ; Tao N. ; Gooding J. J. ; Paddon-Row M. N. Angew. Chem. Int. Ed. 2012, 51 (13), 3203. doi: 10.1002/anie.201107765
49	Baghernejad M. ; Zhao X. ; Baruël Ørnsø K. ; Füeg M. ; Moreno-García P. ; Rudnev A. V. ; Kaliginedi V. ; Vesztergom S. ; Huang C. ; Hong W. ; et al J. Am. Chem. Soc. 2014, 136 (52), 17922. doi: 10.1021/ja510335z
50	Li Y. ; Baghernejad M. ; Qusiy A. G. ; Zsolt Manrique D. ; Zhang G. ; Hamill J. ; Fu Y. ; Broekmann P. ; Hong W. ; Wandlowski T. ; et al Angew. Chem. Int. Ed. 2015, 54 (46), 13586. doi: 10.1002/anie.201506458
51	Xiang L. ; Palma J. L. ; Li Y. ; Mujica V. ; Ratner M. A. ; Tao N. Nat. Commun. 2017, 8, 14471. doi: 10.1038/ncomms14471
52	Yang Y. ; Liu J. Y. ; Chen Z. B. ; Tian J. H. ; Jin X. ; Liu B. ; Li X. ; Luo Z. Z. ; Lu M. ; Yang F. Z. ; et al Nanotechnology 2011, 22 (27), 275313. doi: 10.1088/0957-4484/22/27/275313
53	Venkataraman L. ; Klare J. E. ; Tam I. W. ; Nuckolls C. ; Hybertsen M. S. ; Steigerwald M. L. Nano Lett. 2006, 6 (3), 458. doi: 10.1021/nl052373+
54	Huang C. ; Jevric M. ; Borges A. ; Olsen S. T. ; Hamill J. M. ; Zheng J. ; Yang Y. ; Rudnev A. ; Baghernejad M. ; Broekmann P. ; et al Nat. Commun. 2017, 8, 15436. doi: 10.1038/ncomms15436
55	Halbritter A. ; Makk P. ; Mackowiak S. ; Csonka S. ; Wawrzyniak M. ; Martinek J. Phys. Rev. Lett. 2010, 105 (26) doi: 10.1103/PhysRevLett.105.266805
56	Guan J. ; Jia C. ; Li Y. ; Liu Z. ; Wang J. ; Yang Z. ; Gu C. ; Su D. ; Houk K. N. ; Zhang D. Sci. Adv. 2018, 4 (2), 2177. doi: 10.1126/sciadv.aar2177
57	Gu C. ; Hu C. ; Wei Y. ; Lin D. ; Jia C. ; Li M. ; Su D. ; Guan J. ; Xia A. ; Xie L. Nano Lett. 2018, 18 (7), 4156. doi: 10.1021/acs.nanolett.8b00949
58	Wang H. Y. ; Quan S. G. Acta Phys. -Chim. Sin. 2018, 34 (1), 22. doi: 10.3866/PKU.WHXB201706302
	王海燕; 石高全. 物理化学学报, 2018, 34 (1), 22. doi: 10.3866/PKU.WHXB201706302
59	Jun L. Y. ; Li Y. L. Acta Phys. -Chim. Sin. 2018, 34 (9), 992. doi: 10.3866/PKU.WHXB201801302
	李勇军; 李玉良. 物理化学学报, 2018, 34 (9), 992. doi: 10.3866/PKU.WHXB201801302
60	Tian J. H. ; Liu B. ; Li X. ; Yang Z. L. ; Ren B. ; Wu S. T. ; Tao N. ; Tian Z. Q. J. Am. Chem. Soc. 2006, 128 (46), 14748. doi: 10.1021/ja0648615
61	Tian, J. H.; Liu, B.; Jin, S.; Dai, K.; Chen, Z. B.; Li, X.; Ke, H.; Wu, S. T.; Yang, Y.; Ren, B.; et al. A Combined SERS and MCBJ Study on Molecular Junctions on Silicon Chips. In 7th IEEE NANO, Proceedings of the 7th IEEE International, Hong Kong, China, Aug 2−5, 2007; IEEE: Hong Kong, 2008. doi: 10.1109/NANO.2007.4601421
62	Konishi T. ; Kiguchi M. ; Takase M. ; Nagasawa F. ; Nabika H. ; Ikeda K. ; Uosaki K. ; Ueno K. ; Misawa H. ; Murakoshi K. J. Am. Chem. Soc. 2013, 135 (3), 1009. doi: 10.1021/ja307821u
63	Yang Y. ; Chen Z. ; Liu J. ; Lu M. ; Yang D. ; Yang F. ; Tian Z. Nano Res. 2011, 4 (12), 1199. doi: 10.1007/s12274-011-0170-5
64	Pontes R. B. ; Rocha A. R. ; Sanvito S. ; Fazzio A. ; da Silva A. J. R. ACS Nano 2011, 5 (2), 795. doi: 10.1021/nn101628w
65	Martin C. A. ; Ding D. ; van der Zant H. S. J. ; van Ruitenbeek J. M. New J. Phys. 2008, 10, 065008. doi: 10.1088/1367-2630/10/6/065008
66	Zheng J. T. ; Yan R. W. ; Tian J. H. ; Liu J. Y. ; Pei L. Q. ; Wu D. Y. ; Dai K. ; Yang Y. ; Jin S. ; Hong W. ; et al Electrochim. Acta 2016, 200, 268. doi: 10.1016/j.electacta.2016.03.129
67	Yang Y. ; Liu J. ; Feng S. ; Wen H. ; Tian J. ; Zheng J. ; Schöllhorn B. ; Amatore C. ; Chen Z. ; Tian Z. Nano Res. 2016, 9 (2), 560. doi: 10.1007/s12274-015-0937-1
68	Wang L. ; Li S. Y. ; Yuan J. H. ; Gu J. Y. ; Wang D. ; Wan L. J. Chem. Asian J. 2014, 9 (8), 2077. doi: 10.1002/asia.201402196
69	Zheng J. ; Liu J. ; Zhuo Y. ; Li R. ; Jin X. ; Yang Y. ; Chen Z. ; Shi J. ; Xiao Z. ; Hong W. ; et al Chem. Sci. 2018, 9 (22), 5033. doi: 10.1039/C8SC00727F

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Recent Progress of Break Junction Technique in Single-Molecule Reaction Chemistry

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