Pb1-xTbxTi1-xMnxO3 (0≤x≤0.10)固溶体的合成、结构与表征

doi:10.3866/PKU.WHXB20110428

Acta Phys. -Chim. Sin. ›› 2011, Vol. 27 ›› Issue (04): 990-994.doi: 10.3866/PKU.WHXB20110428

• PHYSICAL CHEMISTRY OF MATERIALS • Previous Articles

Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions

FAN Min², LI Guo-Bao¹, WANG Dong-Wei³, JIN Tou-Nan², LIAO Fu-Hui¹, LIN Jian-Hua¹

1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. College of Material Science and Engineering, Beijing University of Technology, Beijing 100022, P. R. China;
3. National Center for Nanoscience and Technolgy, Beijing 100190, P. R. China

Received:2010-12-27 Revised:2011-02-15 Published:2011-03-29
Contact: LI Guo-Bao, JIN Tou-Nan, LIN Jian-Hua E-mail:liguobao@pku.edu.cn; tnjinkim@bjut.edu.cn; jhlin@pku.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20771008), Scientific Research Key Program of Beijing Municipal Commission of Education, China (KM201010005019), and National Key Basic Research Project of China (2010CB833103).

Abstract

Abstract:

Solid solutions of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) were synthesized by a traditional solid state reaction and characterized by powder X-ray diffraction. The solutions crystallize in the P4mm space group at room temperature. Differential scanning calorimetry (DSC) measurements were performed to obtain phase transition temperatures (T_c) for the samples, and these were found to decrease with an increase in the amount of doped Tb and Mn. The temperature dependent dielectric constant shows a peak close to the T_c, indicating that the corresponding phase transition is a ferroelectric phase transition. Magnetic measurements indicate that a paramagnetic to antiferromagnetic phase transition occurs at 25 and 29 K for Pb_1-xTb_xTi_1-xMn_xO₃ with x=0.08 and x=0.10, respectively.

Key words: Solid-state reaction, PbTiO₃, Phase transition, Ferroelectrics, TbMnO₃

FAN Min, LI Guo-Bao, WANG Dong-Wei, JIN Tou-Nan, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions[J]. Acta Phys. -Chim. Sin. 2011, 27(04), 990-994. doi: 10.3866/PKU.WHXB20110428

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Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions

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Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions