四氯合锌酸正九烷铵的晶体结构及热化学性质

doi:10.3866/PKU.WHXB20110526

Abstract

Abstract:

We synthesized crystalline bis(n-nonylammonium) tetrachlorozincate (C₉H₁₉NH₃)₂ZnCl₄(s) (C₉Zn(s)). X-ray single crystal diffraction, chemical analysis, and elemental analysis were used to determine the crystal structure and composition of the complex. The lattice potential energy U_POT was calculated to be 952.94 kJ·mol^-1 from crystallographic data. The molar enthalpies of C₉Zn(s) dissolution using various molalities were measured in double-distilled water by an isoperibol solution-reaction calorimeter at 298.15 K. According to Pitzer's electrolyte solution theory the molar enthalpy of dissolution of C₉Zn(s) at infinite dilution (Δ_sΗ_m^∞ )] was calculated to be 20.09 kJ·mol^-1 and the sums of Pitzer's parameters (4β_{C₉H₁₉NH₃,Cl}^(0)L+2β_Zn,Cl^(0)L+θ_{C₉H₁₉NH₃,Zn}^L) and (2β_{C₉H₁₉NH₃,Cl}^(1)L+β_Zn,Cl^(1)L) were obtained.

Key words: Bis(n-nonylammonium) tetrachlorozincate, Lattice potential energy, Molar enthalpy of dissolution at infinite dilution, Pitzer’s parameter, Pitzer’s theory

LU Dong-Fei, DI You-Ying, HE Dong-Hua. Crystal Structure and Thermochemical Properties of Bis(n-Nonylammonium) Tetrachlorozincate[J]. Acta Phys. -Chim. Sin. 2011, 27(06), 1319-1324. doi: 10.3866/PKU.WHXB20110526

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Crystal Structure and Thermochemical Properties of Bis(n-Nonylammonium) Tetrachlorozincate

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