基于非手性邻苯酚胺衍生物的半醌Fe(III)络合物的镜面对称性破缺及其绝对构型关联

doi:10.3866/PKU.WHXB201304122

Abstract

Abstract:

A pair of chiral o-iminobenzosemiquinonato Fe(III) complexes, Λ-mer- [Fe(L^ISQ)₃] and Δ-mer-[Fe(L^ISQ)₃] (L^ISQ: 2-phenylimino-4, 6-di-tert-butylphenol, mer: meridian configuration), were synthesized from 2-anilino-4,6-di-tert-butylphenol (H₂L) and FeCl₂·4H₂O. Their absolute configurations were determined by single crystal X-ray diffraction (XRD) and solid-state circular dichroism (CD) spectra (the same single crystal for XRD was dispersed in KCl). Correlations between the absolute configurations of the chiral-atmetal o-iminobenzosemiquinonato M(III) complexes [M(L^ISQ)₃] (M=Cr, Fe, Co) and their solid-state CD spectra were also established. Comparison between solid-state CD spectra of the bulk samples from 10 different syntheses and their single crystals were thoroughly analyzed. The solid-state CD spectra of the powdered samples from 10 different crystallizations of one product were characterized. These studies indicated that mirror symmetry breaking (MSB) occurred during the crystallization process of the Fe(III) complexes and their enantiomeric excess (ee) values were between 15% and 100%.

Key words: Semiquinone Fe(III) complexes, Mirror symmetry breaking, Absolute configuration, Solid-state CD spectroscopy, Single crystal X-ray diffraction

ZHAO Lei, WAN Shi-Gang, CHEN Cheng-Dong, LIN Yi-Ji, FANG Xue-Ming, ZHANG Hui. Mirror Symmetry Breaking and Absolute Configuration Correlations of Fe(III) Complexes with Achiral Substituted o-Iminobenzosemiquinonato Ligands[J].Acta Phys. -Chim. Sin., 2013, 29(06): 1183-1191.

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Mirror Symmetry Breaking and Absolute Configuration Correlations of Fe(III) Complexes with Achiral Substituted o-Iminobenzosemiquinonato Ligands

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