二极管特性简化模型在染料敏化太阳能电池电流-电压曲线拟合及在光电特性参数评估中的应用

doi:10.3866/PKU.WHXB201503192

Abstract

Abstract:

In the present work, we investigated the dynamics of charge collection and recombination in dyesensitized solar cells (DSSCs) spanning a large region of bias voltages using transient photoconductivity. The rate of charge collection was much faster than that of charge recombination at varied voltages, which was responsible for the nearly uniform charge collection efficiency. Based on this result, we simplified the diode characteristic model, which allowed us to directly fit the current-voltage (I-V) curve. A series of parameters related to the photo-to-electric processes in working DSSCs could be extracted from the proposed model, which could be used to evaluate the processes of charge generation, transport, and recombination in DSSCs, as well as the rectification of DSSC devices. We applied the fitting method to DSSCs with different 4-tert-butyl pyridine (TBP) concentrations of electrolyte. It was found that the rate of charge recombination significantly differed while that of charge collection was rather constant under different TBP concentrations, which was in good agreement with the results of I-V curve fitting. In addition, this research shows that the change of TBP concentration significantly affects the ideality factor (m) of DSSC devices.

Key words: Series resistance, Shunt resistance, I-V curve, 4-tert-butylpyridine, Ideality factor

ZHANG Ping, WANG Yi, FU Li-Min, AI Xi-Cheng, ZHANG Jian-Ping. Application of a Simplified Diode Characteristic Model in Current-Voltage Curve Fitting and Evaluation of Photoelectric Parameters within Dye-Sensitized Solar Cell[J]. Acta Phys. -Chim. Sin. 2015, 31(6), 1113-1117. doi: 10.3866/PKU.WHXB201503192

References

(1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
(2) Lenzmann, F. O.; Kroon, J. M. Advances in OptoElectronics 2007, 2007, 65073. doi: 10.1155/2007/65073
(3) Kuciauskas, D.; Monat, J. E.; Villahermosa, R.; Gray, H. B.; Lewis, N. S.; McCusker, J. K. J. Phys. Chem. B 2002, 106, 9347. doi: 10.1021/jp014589f
(4) Luo, J.; Xu, M. F.; Li, R. Z.; Huang, K.W.; Jiang, C. Y.; Qi, Q. B.; Zeng, W. D.; Zhang, J.; Chi, C. Y.; Wang, P.; Wu, J. S. J. Am. Chem. Soc. 2014, 136, 265. doi:10.1021/ja409291g
(5) (a) Xie, Y.; Joshi, P.; Darling, S. B.; Chen, P. L.; Zhang, T.; Galipeau, D.; Qiao, Q. Q. J. Phys. Chem. C 2010, 114, 17880. doi: 10.1021/jp106302m
(b) Zhang, R. K.; Sun, Z.; Xie, H. H.; Liang, M.; Xue, S. Acta Phys. -Chim. Sin. 2012, 28, 1139. [张仁开, 孙喆, 谢焕焕, 梁茂, 薛松. 物理化学学报, 2012, 28, 1139.] doi: 10.3866/PKU.WHXB201202233
(6) (a) Zhu, F.; Wu, D. P.; Li, Q.; Dong, H.; Li, J. M.; Jiang, K.; Xu, D. S. RSC Adv. 2012, 2, 11629. doi: 10.1039/c2ra22043a
(b) Gao, S.W.; Lan, Z.; Wu, W. X.; Que, L. F.; Wu, J. H. Acta Phys. -Chim. Sin. 2014, 30, 446. [高素雯, 兰章, 吴晚霞, 阕兰芳, 吴季怀. 物理化学学报, 2014, 30, 446.] doi: 10.3866/PKU.WHXB201401022
(7) Ishibashi, K.; Kimura, Y.; Niwano, M. J. Appl. Phys. 2008, 103, 094507. doi: 10.1063/1.2895396
(8) Zhang, C. F.; Zhang, J. C.; Hao, Y.; Lin, Z. H.; Zhu, C. X. J. Appl. Phys. 2011, 110, 064504. doi:10.1063/1.3632971
(9) Sarker, S.; Seo, H.W.; Kim, D. M. J. Power Sources 2014, 248, 739. doi:10.1016/j.jpowsour.2013.09.101
(10) Han, L. Y.; Koide, N.; Chiba, Y.; Mitate, T. Appl. Phys. Lett. 2004, 84, 13. doi: 10.1063/1.1690495
(11) Fisher, A. C.; Peter, L. M.; Ponomarev, E. A.; Walker, A. B.; Wijayantha, K. G. U. J. Phys. Chem. B 2000, 104, 949. doi: 10.1021/jp993220b
(12) Dloczik, L.; Ileperuma, O.; Lauermann, I.; Peter, L. M.; Ponomarev, E. A.; Redmond, G.; Shaw, N. J.; Uhlendorf, I. J. Phys. Chem. B 1997, 101, 10281. doi:10.1021/jp972466i
(13) Bisquert, J. J. Phys. Chem. C 2007, 111, 17163. doi:10.1021/jp077419x
(14) Duffy, N.W.; Peter, L. M.; Rajapakse, R. M. G.; Wijayantha, K. G. U. Electrochem. Commun. 2000, 2, 658. doi: 10.1016/S1388-2481(00)00097-7
(15) Jennings, J. R.; Ghicov, A.; Peter, L. M.; Schmuki, P.; Walker, A. B. J. Am. Chem. Soc. 2008, 130, 13364. doi:10.1021/ja804852z
(16) Katoh, R.; Kasuya, M.; Kodate, S.; Furube, A.; Fuke, N.; Koide, N. J. Phys. Chem. C 2009, 113, 20738. doi: 10.1021/jp906190a
(17) Shi, C.W.; Dai, S. Y.; Wang, K. J.; Pang, X.; Kong, F. T.; Hu, L. H. Vibrational Spectroscopy 2005, 39, 99. doi: 10.1016/j.vibspec.2005.01.002
(18) O'Regan, B.; Bakker, K.; Kroeze, J.; Smit, H.; Sommeling, P.; Durrant, J. R. J. Phys. Chem. B 2006, 110, 17155. doi: 10.1021/jp062761f
(19) Sauvage, F.; Chen, D. H.; Comte, P.; Huang, F. Z.; Heiniger, L. P.; Cheng, Y. B.; Caruso, R. A.; Grätzel, M. ACS Nano 2010, 4, 4420. doi: 10.1021/nn1010396
(20) Nakade, S.; Kanzaki, T.; Kubo, W.; Kitamura, T.; Wada, Y.; Yanagida, S. J. Phys. Chem. B 2005, 109, 3480. doi: 10.1021/jp0460036
(21) Hara, K.; Dan-oh, Y.; Kasada, C.; Ohga, Y.; Shinpo, A.; Suga, S.; Sayama, K.; Arakawa, H. Langmuir 2004, 20, 4205. doi: 10.1021/la0357615
(22) Zhang, P. P.; Zhu, F.; Ai, X. C.; Fu, L. M.; Xu, D. S.; Zhang, J. P. Chem. J. Chin. Univ. 2013, 34, 418. [张盼盼, 朱枫, 艾希成, 付立民, 徐东升, 张建平. 高等学校化学学报, 2013, 34, 418.] doi: 10.7503/cjcu20120159
(23) Ma, T. L.; Yun, S. N. Dye Sensitized Solar Cell——from Theoretic Foundation to Technical Application; Chemical Industry Press: Beijing, 2013; pp 24-27. [马庭丽, 云斯宁. 染料敏化太阳能电池——从理论基础到技术应用. 北京: 化学工业出版社, 2013: 24-27.]

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Application of a Simplified Diode Characteristic Model in Current-Voltage Curve Fitting and Evaluation of Photoelectric Parameters within Dye-Sensitized Solar Cell

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