化学改性碳在锂硫电池中的研究进展

doi:10.3866/PKU.WHXB201609232

Abstract

Abstract:

Chemically modified carbon has attracted significant attention since our first report of its use in lithium/sulfur (Li/S) cells. Compared with traditional carbon materials, chemically modified carbon prevents the dissolution and diffusion of intermediate polysulfides. Therefore, it yields sulfur cathodes with long cycling stability, which has become the focus of current research in the field of Li/S batteries. This review summarizes the use of chemically modified carbon for highly efficient sulfur utilization and the synergistic chemical/physical trapping of sulfur species. The prospects of further developments of Li/S batteries using chemically modified carbon is also discussed.

Key words: Lithium/sulfur battery, Carbon, Chemical modification, Sulfur cathode, Shuttle effect

Wan-Fei LI,Mei-Nan LIU,Jian WANG,Yue-Gang ZHANG. Progress of Lithium/Sulfur Batteries Based on Chemically Modified Carbon[J]. Acta Phys. -Chim. Sin. 2017, 33(1), 165-182. doi: 10.3866/PKU.WHXB201609232

References

1	Goodenough J. B. Energy Environ. Sci 2014, 7, 14.
2	Larcher D. ; Tarascon J. M. Nat. Chem 2015, 7, 19.
3	Ellis B. L. ; Lee K. T. ; Nazar L. F. Chem. Mater 2010, 22, 691.
4	Goodenough J. B. ; Park K. S. J.Am. Chem. Soc 2013, 135, 1167.
5	Erickson E. M. ; Ghanty C. ; Aurbach D. J.Phys. Chem. Lett 2014, 5, 3313.
6	Croguennec L. ; Palacin M. R. J.Am. Chem. Soc 2015, 137, 3140.
7	Liu C. ; Li F. ; Ma L. P. ; Cheng H. M. Adv. Mater 2010, 22, E28.
8	Cheng F. Y. ; Liang J. ; Tao Z. L. ; Chen J. Adv. Mater 2011, 23, 1695.
9	Yang Y. ; Zheng G. Y. ; Cui Y. Chem. Soc. Rev 2013, 42, 3018.
10	Muldoon J. ; Bucur C. B. ; Gregory T. Chem. Rev 2014, 114, 11683.
11	Lin M. C. ; Gong M. ; Lu B. A. ; Wu Y. P. ; Wang D. Y. ; Guan M. Y. ; Angell M. ; Chen C. X. ; Yang J. ; Hwang B. J. ; Dai H.J. Nature 2015, 520, 325.
12	Yin Y. X. ; Xin S. ; Guo Y. G. ; Wan L. J. Angew. Chem. Int. Ed 2013, 52, 13186.
13	Manthiram A. ; Chung S. H. ; Zu C. X. Adv. Mater 2015, 27, 1980.
14	Li W. F. ; Cheng S. ; Wang J. ; Qiu Y. C. ; Zheng Z. Z. ; Lin H.Z. ; Nanda S. ; Ma Q. ; Xu Y. ; Ye F. M. ; Liu M. N. ; Zhou L.S. ; ZhangY.G. Angew. Chem. Int. Ed 2016, 55, 1.
15	Song M. K. ; Cairns E. J. ; Zhang Y. G. Nanoscale 2013, 5, 2186.
16	Bruce P. G. ; Freunberger S. A. ; Hardwick L. J. ; Tarascon J.M. Nat. Mater 2012, 11, 172.
17	Wild M. ; O'Neill L. ; Zhang T. ; Purkayastha R. ; Minton G. ; Marinescub M. ; Offer G. J. Energy Environ. Sci 2015, 8, 3477.
18	Pope M. A. ; Aksay I. A. Adv. Energy Mater 2015, 5, 1500124.
19	Zhang S. ; Ueno K. ; Dokko K. ; Watanabe M. Adv. Energy Mater 2015, 5, 1500117.
20	Huang J. Q. ; Zhang Q. ; Wei F. Energy Storage Mater 2015, 1, 127.
21	Song M. K. ; Zhang Y. G. ; Cairns E. J. Nano Lett 2013, 13, 5891.
22	Qiu Y. C. ; Li W. F. ; Zhao W. ; Li G. Z. ; Hou Y. ; Liu M. N. ; Zhou L. S. ; Ye F. M. ; Li H. F. ; Wei Z. H. ; Yang S. H. ; Duan W. H. ; Ye Y. F. ; Guo J. H. ; Zhang Y. G. Nano Lett 2014, 14, 4821.
23	Qiu Y. C. ; Rong G. L. ; Yang J. ; Li G. Z. ; Ma S. ; Wang X. L. ; Pan Z. H. ; Hou Y. ; Liu M. N. ; Ye F. M. ; Li W. F. ; Seh Z.W. ; Tao X. Y. ; Yao H. B. ; Liu N. ; Zhang R. F. ; Zhou G. M. ; Wang J. P. ; Fan S. S. ; Cui Y. ; Zhang Y. G. Adv. Energy Mater 2015, 5, 1501369.
24	Suo L. M. ; Hu Y. S. ; Li H. ; Armand M. ; Chen L. Q. Nat. Commun 2013, 4, 1481.
25	Zhou G. ; Li L. ; Wang D.W. ; Shan X. Y. ; Pei S. ; Li F. ; Cheng H. M. Adv. Mater 2015, 27, 641.
26	Huang J. Q. ; Zhuang T. Z. ; Zhang Q. ; Peng H. J. ; Chen C.M. ; Wei F. ACS Nano 2015, 9, 3002.
27	Wang W. K. ; Yu Z. B. ; Wang A. B. ; Yuan K. G. ; Yang Y. S. Research Progress and Thought in Lithium-Sulfur Batteries. The14th National Conference of Electrochemistry Yangzhou: YangzhouUniversity, 2007, 1058.
28	Ji X. L. ; Lee K. T. ; Nazar L. F. Nat. Mater 2009, 8, 500.
29	Li K.F. ; Wang B. ; Su D.W. ; Park J. ; Ahn H. ; Wang G. X. J. Power Sources 2012, 202, 389.
30	Li G. C. ; Hu J. J. ; Li G. R. ; Ye S. H. ; Gao X. P. J.Power Sources 2013, 240, 589.
31	Cheng J. J. ; Pan Y. ; Pan J. A. ; Song H. J. ; Ma Z. S. RSC Adv 2015, 5, 68.
32	Ji L.W. ; Rao M. M. ; Aloni S. ; Wang L. ; Cairns E. J. ; Zhang Y. G. Energy Environ. Sci 2011, 4, 5053.
33	Zheng G. Y. ; Yang Y. ; Cha J. J. ; Hong S. S. ; Cui Y. Nano Lett 2011, 11, 4462.
34	Guo J. C. ; Xu Y. H. ; Wang C. S. Nano Lett 2011, 11, 4288.
35	Wang L. N. ; Zhao Y. ; Thom M. L. ; Byon H. R. Adv. Funct. Mater 2014, 24, 2248.
36	Zhu L. ; Zhu W. C. ; Cheng X. B. ; Huang J. Q. ; Peng H. J. ; Yang S. H. ; Zhang Q. Carbon 2014, 75, 161.
37	Zhu J. X. ; Yang D. ; Yin Z. Y. ; Yan Q. Y. ; Zhang H. Small 2014, 10, 3480.
38	You Y. ; Zeng W. C. ; Yin Y. X. ; Zhang J. ; Yang C. P. ; Zhu Y.W. ; Guo Y. Y. J.Mater. Chem. A 2015, 3, 4799.
39	Li H. F. ; Yang X.W. ; Wang X. M. ; Liu M. N. ; Ye F. M. ; Wang J. ; Qiu Y. C. ; Li W. F. ; Zhang Y. G. Nano Energy 2015, 12, 468.
40	Zhou G. M. ; Pei S. F. ; Li L. ; Wang D.W. ; Wang S. G. ; Huang K. ; Yin L. C. ; Li F. ; Cheng H. M. Adv. Mater 2014, 26, 625.
41	Zheng S. Y. ; Yi F. ; Li Z. P. ; Zhu Y. J. ; Xu Y. H. ; Luo C. ; Yang J. H. ; Wang C. S. Adv. Funct. Mater 2014, 24, 4156.
42	Li Z. ; Yuan L. X. ; Yi Z. Q. ; Sun Y. M. ; Liu Y. ; Jiang Y. ; Shen Y. ; Xin Y. ; Zhang Z. L. ; Huang Y. H. Adv. Energy Mater 2014, 4, 1301473.
43	Zhang K. ; Zhao Q. ; Tao Z. L. ; Chen J. Nano Res 2013, 6, 38.
44	Peng H. J. ; Huang J. Q. ; Zhao M. Q. ; Zhang Q. ; Cheng X.B. ; Liu X. Y. ; Qian W. Q. ; Wei F. Adv. Func. Mater 2014, 19, 2772.
45	Liu S. K. ; Xie K. ; Li Y. J. ; Chen Z. X. ; Hong X. B. ; Zhou L.J. ; Yuan J. F. ; Zheng C. M. RSC Adv 2015, 5, 5516.
46	Zhu L. ; Peng H. J. ; Liang J. Y. ; Huang J. Q. ; Chen C. M. ; Guo X. F. ; Zhu W. C. ; Li P. ; Zhang Q. Nano Energy 2015, 11, 746.
47	Sun L. ; Kong W. B. ; Jiang Y. ; Wu H. C. ; Jiang K. L. ; Wang J. P. ; Fan S. S. J.Mater. Chem. A 2015, 3, 5305.
48	Yang X. ; Zhang L. ; Zhang F. ; Huang Y. ; Chen Y. S. ACS Nano 2014, 8, 5208.
49	Seh Z.W. ; Li W. Y. ; Cha J. J. ; Zheng G. Y. ; Yang Y. ; McDowell M. T. ; Hsu P. C. ; Cui Y. Nat. Commun 2013, 4, 1331.
50	Yao H. B. ; Zheng G. Y. ; Hsu P. C. ; Kong D. S. ; Cha J. J. ; Li W. Y. ; Seh Z.W. ; McDowell M. T. ; Yan K. ; Liang Z. ; Narasimhan V. K. ; Cui Y. Nat. Commun 2014, 5, 3943.
51	Tao X. Y. ; Wang J. G. ; Ying Z. G. ; Cai Q. X. ; Zheng G. Y. ; Gan Y. P. ; Huang H. ; Xia Y. ; Liang C. ; Zhang W. K. ; Cui Y. Nano Lett 2014, 14, 5288.
52	Pang Q. ; Kundu D. ; Cuisinier M. ; Naza L. F. Nat. Commun 2015, 5, 4759.
53	Song M. S. ; Han S. C. ; Kim H. S. ; Kim J. H. ; Kim K. T. ; Kang Y. M. ; Ahn H. J. ; Dou S. X. ; Lee J. Y. J.Electrochem. Soc 2004, 151, A791.
54	Zhang Y. G. ; Zhao Y. ; Yermukhambetova A. ; Bakenov Z. ; Chen P. J. J.Mater. Chem. A 2013, 1, 295.
55	Choi Y. J. ; Jung B. S. ; Lee D. J. ; Kim K.W. ; Ahn H. J. ; Cho K. K. ; Gu H. B. Phys. Scr 2007, T129, 62.
56	Ji X. L. ; Evers S. ; Black R. ; Nazar L. F. Nat. Commun 2011, 2, 325.
57	Liang Z. ; Zheng G. Y. ; Li W. Y. ; Seh Z.W. ; Yao H. B. ; Yan K. ; Kong D. S. ; Cui Y. ACS Nano 2014, 8, 5249.
58	Sun F. G. ; Wang J. T. ; Long D. H. ; Qiao W. M. ; Ling L. C. ; Lv C. X. ; Cai R. J.Mater. Chem. A 2013, 1, 13283.
59	Qu Q. T. ; Gao T. ; Zheng H. Y. ; Wang Y. ; Li X. Y. ; Li X. X. ; Chen J. M. ; Han Y. Y. ; Shao J. ; Zheng H. Z. Adv. Mater. Interfaces 2015, 2, 1500048.
60	Liang X. ; Garsuch A. ; Nazar L. F. Angew. Chem. Int. Ed 2015, 54, 3907.
61	Zhang Q. F. ; Wang Y. F. ; Seh Z.W. ; Fu Z. H. ; Zhang R. F. ; Cui Y. Nano Lett 2015, 15, 3780.
62	Ji L. ; Rao M. ; Zheng H. ; Zhang L. ; Li Y. ; Duan W. ; Guo J. ; Cairns E. J. ; Zhang Y. J. Am. Chem. Soc 2011, 133, 18522.
63	Zhang S. S. Inorg. Chem. Front 2015, 2, 1059.
64	Zhang L. ; Ji L. ; Glans P. A. ; Zhang Y. ; Zhu J. ; Guo J. Phys. Chem. Chem. Phys 2012, 14, 13670.
65	Qiu Y. C. ; Li W. F. ; Li G. Z. ; Hou Y. ; Zhou L. S. ; Li H. F. ; Liu M. N. ; Ye F. M. ; Yang X.W. ; Zhang Y. G. Nano Res 2014, 7, 1355.
66	Ye F. M. ; Liu M. N. ; Zhang X. Y. ; Li W. F. ; Pan Z. H. ; Li H.F. ; Zhang S. ; Zhang Y. G. Small 2016, 12, 4966.
67	Liu M. N. ; Ye F. M. ; Li W. F. ; Li H. F. ; Zhang Y. G. Nano Res 2016, 9, 94.
68	Wang C. ; Su K. ; Wan W. ; Guo H. ; Zhou H. H. ; Chen J. T. ; Zhang X. X. ; Huang Y. H. J.Mater. Chem. A 2014, 2, 5018.
69	Zhang S. ; Liu M. N. ; Ma F. ; Ye F. M. ; Li H. F. ; Zhang X. Y. ; Hou Y. ; Qiu Y. C. ; Li W. F. ; Wang J. ; Wang J. ; Zhang Y. G. J. Mater. Chem. A 2015, 3, 18913.
70	Liu J. H. ; Zhang T. K. ; Wang Z. C. ; Dawson G. ; Chen W. J. Mater. Chem 2011, 21, 14398.
71	Zhang Y.W. ; Liu J. H. ; Wu G. ; Chen W. Nanoscale 2012, 4, 5300.
72	Liu J. ; Liu Y. ; Liu N. Y. ; Han Y. Z. ; Zhang X. ; Huang H. ; Lifshitz Y. ; Lee S. T. ; Zhong J. ; Kang Z. H. Science 2015, 347, 970.
73	Liu J. H. ; Li W. F. ; Duan L. M. ; Li X. ; Ji L. ; Geng Z. B. ; Huang K. K. ; Lu L. H. ; Zhou L. S. ; Liu Z. R. ; Chen W. ; Liu L.W. ; Feng S. H. ; Zhang Y. G. Nano Lett 2015, 15, 5137.
74	Pang Q. ; Nazar L. F. ACS Nano 2016, 10, 4111.
75	Wang J. ; Cheng S. ; Li W.F. ; Zhang S. ; Li H. F. ; Zheng Z.Z. ; Li F. J. ; Shi L. Y. ; Lin H. Z. ; Zhang Y. G. J.Power Sources 2016, 321, 193.
76	Zhou G. ; Paek E. ; Hwang G. S. ; Manthiram A. Nat. Commun 2015, 6, 7760.
77	Pang Q. ; Tang J. ; Huang H. ; Liang X. ; Hart C. ; Tam K. C. ; Nazar L. F. Adv. Mater 2015, 27, 6021.

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Progress of Lithium/Sulfur Batteries Based on Chemically Modified Carbon

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