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Acta Phys. -Chim. Sin.
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中文
Current Issue
1992 Vol. 8, No. 06
Published online: 1992-12-15
Current column
Communication
ARTICLE
Note
Review
Communication
Al
±
n
Generated by Laser Ablation of Aln
Huang Rong-Bin; Liu Zhao-Yang; Zhang Peng; Zhao Jian-Hong; Zheng Lan-Sun
Both positive and negative aluminum cluster ions were generated by laser ablation of AIN sample. Their mass distribution...
Acta Phys. -Chim. Sin. 1992, 8 (06), 721-723.
DOI: 10.3866/PKU.WHXB19920601
5775
Abstract/Metrics
2796
PDF(1309KB)
The Topological Characteristics of the Structures in the Vicinity of Transition State of HCN→HNC Isomerization
Li Qing-Ming; Fu Xiao-Yuan; Zhang Jing-Chang; Cao Wei-Liang
In this paper,thermal isomerization of HCN to isocyanide HNC has been studied. The topological properties of the structu...
Acta Phys. -Chim. Sin. 1992, 8 (06), 724-727.
DOI: 10.3866/PKU.WHXB19920602
5654
Abstract/Metrics
2584
PDF(2349KB)
Temperature Dependence of Conductivity for Quasi-one Dimensional Organic Charge Transfer Crystal
Huang Yuan-He; Liu Ruo-Zhuang
One class of conducting molecular crystals is consisted of the charge transfer molecules crystallizing in segregated sta...
Acta Phys. -Chim. Sin. 1992, 8 (06), 728-731.
DOI: 10.3866/PKU.WHXB19920603
6325
Abstract/Metrics
2531
PDF(2838KB)
A Dynamic Investigation of the Dissociative Adsorption of Hcooh on Pt(100) Single Crystal Electrode
Sun Shi-Gang; Wang Jin-Jian; Mu Ji-Qian
Dissociative adsorption of small organic molecules on electrocatalyst is an important molecular process of surface, whic...
Acta Phys. -Chim. Sin. 1992, 8 (06), 732-735.
DOI: 10.3866/PKU.WHXB19920604
6278
Abstract/Metrics
2787
PDF(2025KB)
ARTICLE
Effects of Oxyethylene on Thermodynamic Function of the Micellization
Li Xue-Gang; Zhao Guo-Xi
The cmc's of C_8H_(17) (OC_2H_4)_nSO_4Na (C_8E_nS; n=0, 1, 3) under varied conditions have been measured by the drop-vol...
Acta Phys. -Chim. Sin. 1992, 8 (06), 736-741.
DOI: 10.3866/PKU.WHXB19920605
6061
Abstract/Metrics
2901
PDF(4526KB)
Viscosity of Amino Acids in Methanol-Water Mixtures
Liu Wen-Bin; Wang Jian-Ji; Wang Cai-Lan; Lu Jin-Suo
Viscosities and densities at 293.15 and 298.15 K are reported in this paper for glycine and DL-alanine in methanol-water...
Acta Phys. -Chim. Sin. 1992, 8 (06), 742-748.
DOI: 10.3866/PKU.WHXB19920606
7354
Abstract/Metrics
2544
PDF(3107KB)
Synthesis and Crystal Structure of Cluster (
μ
-SC
6
H
5
)(
μ
-P(SC
6
H
5
)
2
)Fe
2
(CO)
6
Wu Bing-Fang; Yan Xiu-Ying; Liu Qi-Wang; Liu Shu-Tang; Hu Xiang
The title compound was obtained by the reaction of Fe_3(CO)_(12) with phosphorotri-thious acid triphenyl ester P(SC_6H_5...
Acta Phys. -Chim. Sin. 1992, 8 (06), 749-752.
DOI: 10.3866/PKU.WHXB19920607
6488
Abstract/Metrics
2757
PDF(2318KB)
Catalytic Activity of Vanadium Pentoxide for the Absorption of Carbon Dioxide by Potassium Carbonate Solution
Le Qing-Hua; Xu Jin-Lin; Shi Ya-Jun
The chemical mechanism that vanadium pentoxide, as an additive, enhances the absorption rate of carbon dioxide in aqueou...
Acta Phys. -Chim. Sin. 1992, 8 (06), 753-759.
DOI: 10.3866/PKU.WHXB19920608
7794
Abstract/Metrics
2961
PDF(5049KB)
A Study on Salting Effect in Partially Miscible Systems(I)
Tang Yi-Ping; Liu Yi; Li Zong-Cheng; Li Yi-Gui
The LLE data of eight ternary systems (n-butanol-water and butanone-water with NaCl, KCl, KBr) were determined experimen...
Acta Phys. -Chim. Sin. 1992, 8 (06), 760-766.
DOI: 10.3866/PKU.WHXB19920609
5795
Abstract/Metrics
2529
PDF(3217KB)
Activated Chemisorption of CH
4
On Ni Surface and La Film
Shao Shu-Min; Xi Guang-Kang; Wang Jun-Rong; Li Sheng-Lin; Yang Xue-Zhu; Wang Jin-He; Zhou Zhi-Qiang; He Tian-Xi; Yu Bao-Xia
The effect of translational kinetic energy E_k on the activated chemisorption of CH_4 on Ni (polycrystal) surface and La...
Acta Phys. -Chim. Sin. 1992, 8 (06), 767-771.
DOI: 10.3866/PKU.WHXB19920610
7332
Abstract/Metrics
2605
PDF(2580KB)
35
Cl NMR Study on Ion Pair and Ionic Solvation in Solution
Li Zhi-Fen; Jiang Jun-Ping; Sun Bin; Liu Rui-Lin
This research has recorded the linewidth of ~(35)Cl of Sr(ClO_4)_2 and Ba(ClO_4)_2 at 0.5 mol·L~(-1) in acetonitrile and...
Acta Phys. -Chim. Sin. 1992, 8 (06), 772-777.
DOI: 10.3866/PKU.WHXB19920611
5562
Abstract/Metrics
2725
PDF(2923KB)
Infrared Spectra and Crystal Structure of
BIS
-(Dimethoxylphosphato) Copper
Zeng Guang-Fu; Guo Xin; Wang Cui-Ying; Lin Yong-Hua; Li Han
The title complex has been synthesized by the reaction of CuCl_2 with trimethyl phosphate. Its Infrared spectra from 400...
Acta Phys. -Chim. Sin. 1992, 8 (06), 778-782.
DOI: 10.3866/PKU.WHXB19920612
6420
Abstract/Metrics
3021
PDF(3978KB)
Thermal Analysis nad Infrared Spectra of Dialkylammonium Tetrachlorocuprate
Guo Ning; Zeng Guang-Fu; Xi Shi-Quan
The thermal stability and the solid-solid phase transitions in the [n-C_nH_(2n+1)NH_3]_2CuCl_4 compounds with n=7-12 hav...
Acta Phys. -Chim. Sin. 1992, 8 (06), 783-788.
DOI: 10.3866/PKU.WHXB19920613
6613
Abstract/Metrics
2929
PDF(4927KB)
A Kinetic Model of the Hydrogenation of Oil and Fat
Ai Hong-Tao; Huang Dao-Hui; Zhang Yu-Jun; Wang Shui-Xing
A kinetic model of fat and oil hydrogenation is given in this paper. Hydrogen is adsorbed at the surface of catalyst M f...
Acta Phys. -Chim. Sin. 1992, 8 (06), 789-794.
DOI: 10.3866/PKU.WHXB19920614
6289
Abstract/Metrics
2654
PDF(4177KB)
Note
Study on
O
-Quinonoid Form Homologues by DSC
Huang Wei-Jun; Zhou Yan-Zhu; Tan Fu; Huang Xiu-Lan; Yang Bao-Jin
This paper presents the study on thermodynamic characteristics of phase transitions for tanshinone Ⅱ-A, tanshinone Ⅱ-B a...
Acta Phys. -Chim. Sin. 1992, 8 (06), 795-798.
DOI: 10.3866/PKU.WHXB19920615
5241
Abstract/Metrics
2468
PDF(1945KB)
The Structural Character of Musk Odor Molecules and Its Model of Olfaction
Liu Jing-Jiang; Tang Ji-Wei; Zhu Neng-Chui; Zhu Min-Hui; Fan Xiao-Ling
Molecular interaction model of olfaction for musk odorants are proposed on the basis of grometric optimization by molecu...
Acta Phys. -Chim. Sin. 1992, 8 (06), 799-803.
DOI: 10.3866/PKU.WHXB19920616
6077
Abstract/Metrics
2813
PDF(2161KB)
The Isothermal Compressibility of Binary Systems
Wen Xiao-Lin; He Jia-Jun
The molar volumes were determined for the binary mixtures such as benzene-cy-clohexane and benzene-n-hexane at 288.15, 2...
Acta Phys. -Chim. Sin. 1992, 8 (06), 804-808.
DOI: 10.3866/PKU.WHXB19920617
6728
Abstract/Metrics
2521
PDF(2282KB)
An Example of Lone Pair Orbital and Their Interaction——Gas Phase Ultravlolet Photoelctron Spectroscople Study of some Nitrogen Heterocyclle Compounds
Wang Dian-Xun; Wang Dong; Zhao Heng-Qi; Tang Qing; Xu Guang-Zhi
Ione pair orbital and their interaction in some nitrogen heterocyclic compound series have been interpreted in terms of ...
Acta Phys. -Chim. Sin. 1992, 8 (06), 809-813.
DOI: 10.3866/PKU.WHXB19920618
5952
Abstract/Metrics
2591
PDF(2346KB)
Mechanism of the Formation of Uniform Spherical Colloidal Hematite
Zhang Yu-Ting; Yu Ming
The formation of uniform spherical hematite particles, obtained by hydrolysis of ferric chloride at elevated temperature...
Acta Phys. -Chim. Sin. 1992, 8 (06), 814-818.
DOI: 10.3866/PKU.WHXB19920619
5185
Abstract/Metrics
2564
PDF(2494KB)
Isopiestic Osmotic Coefficient and Activity Coefficient of some Naphthyldisulfonates
Zhao Ji-Hong; Wu Ding-Quan; Qu Song-Sheng
The osmotic coefficients and activity coefficients for aqueous solution of naphtha-lene-1,5-disulfonic acid disodium and...
Acta Phys. -Chim. Sin. 1992, 8 (06), 819-823.
DOI: 10.3866/PKU.WHXB19920620
5256
Abstract/Metrics
2577
PDF(3349KB)
The Oscillation of Chemical Affinity and Entropy Production of the Brusselator
Gao Zhi-Di; Li Ming-Cheng; Liu Jun-Li
The time variation of chemical affinities A_p and entropy production ? of an open Brusselator system has been studied. I...
Acta Phys. -Chim. Sin. 1992, 8 (06), 824-828.
DOI: 10.3866/PKU.WHXB19920621
5442
Abstract/Metrics
2549
PDF(2051KB)
Study of Phase Equilibrium on CO(NH
2
)
2
-H
3
BO
3
-H
2
O System At 25 ℃ and 35 ℃
Guo Zhi-Qin; Jiang Cheng-Fa; Su Yu-Guang
The phase equilibrium data of CO(NH_2)_2-H_3BO_3-H_2O system at 25 ℃ and 35 ℃ have been presented and the phase diagrams...
Acta Phys. -Chim. Sin. 1992, 8 (06), 829-833.
DOI: 10.3866/PKU.WHXB19920622
5821
Abstract/Metrics
2515
PDF(2024KB)