Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (06): 742-748.doi: 10.3866/PKU.WHXB19920606

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Viscosity of Amino Acids in Methanol-Water Mixtures

Liu Wen-Bin; Wang Jian-Ji; Wang Cai-Lan; Lu Jin-Suo   

  1. Department of Chemistry, Henan Normal University, Xinxiang 453002
  • Received:1991-06-20 Revised:1991-12-16 Published:1992-12-15
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Abstract: Viscosities and densities at 293.15 and 298.15 K are reported in this paper for glycine and DL-alanine in methanol-water mixed solvent. The viscosity B coefficients and partial molar volumes at infinite dilution have been calculated. The experimental results show that B coefficients reach a minimum at about 15% for glycine and 25% for DL-alanine respectively. The effect of amino acids on solvent structure has been discussed. Also, the activation parameters for viscous flow for amino acids in methanol-water mixtures have been calculated.

Key words: Viscosity β coefficient, Solvation, Prtial molar volume, Activation parameter