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Acta Phys. -Chim. Sin.
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中文
Current Issue
1989 Vol. 5, No. 02
Published online: 1989-04-15
Current column
Communication
ARTICLE
Note
Communication
PREPARATION AND STRUCTURAL STUDY OF 110 K SUPERCONDUCTING PHASE IN Bi (Pb)-Sr-Ca-Cu-O SYSTEM
Lu Weijing; Zhang Yufen; Zheng Xiangmiao; Wei Chengqian; Wei Zhaoqing; He Jun
The stable superconducting phase with T_c 110 K has been prepared in samples of nominal composition (Bi_(2-x)Pb_x)Sr_2Ca...
Acta Phys. -Chim. Sin. 1989, 5 (02), 129-134.
DOI: 10.3866/PKU.WHXB19890201
4780
Abstract/Metrics
2415
PDF(2163KB)
ARTICLE
ESR STUDY ON THE FREE RADICAL INTERMEDIATES FORMED DURING THE PHOTOLYSIS OF METHYL PHENYLDIAZONIUM SALTS AND THEIR CROWN ETHER COMPLEXES
Liu Yang; Xu Guangzhi; Zhao Yaoxing; Sun Xiangyu
Active free radicals formed by the photolysis of methyl substitute phenyldiazonium and their crown ether complexes have ...
Acta Phys. -Chim. Sin. 1989, 5 (02), 135-140.
DOI: 10.3866/PKU.WHXB19890202
4716
Abstract/Metrics
2305
PDF(1937KB)
THE STRUCTURAL EFFECT OF POLYPHENOXY BENZNE COMPOUNDS——THE CRYSTAL STRUCTRE OF 1,4-BIPHENOXYBENZENE AND 1,4-BIS (4-METHOXYPHENOXY) BENZENE
Liu Yuming; Guo Fang; Dai Cuichen; Chen Zhendong; Hong Shunian
The Crystal structure of 1,4-Biphenoxybenzene (Ⅰ) and 1,4-Bis (4-Methoxyphenoxy) benzene (Ⅱ) have been determined by X-r...
Acta Phys. -Chim. Sin. 1989, 5 (02), 141-144.
DOI: 10.3866/PKU.WHXB19890203
5258
Abstract/Metrics
2093
PDF(1481KB)
SORPTION AND DIFFUSION OF XYLENES IN ZSM-5 ZEOLITES
Zeng Zhaohuai; Pan Guisheng
The equilibrium isotherms have been determined gravimetrically for xylenes in HZSM-5 and MgHZSM-5 zeolites at the temper...
Acta Phys. -Chim. Sin. 1989, 5 (02), 145-150.
DOI: 10.3866/PKU.WHXB19890204
5666
Abstract/Metrics
2387
PDF(2236KB)
HE PHASE TRANSFER OF CO(Ⅱ) CATALYZED BY 2,2′-BIPYRIDINE AT THE WATER/NITROBENZENE INTERFACE
Liu Yuqing; Wang Erkang
The chemical reactions coupled with the phase transfer of Co(Ⅱ) catalyzed by 2,2′ -bipyridine across the water/nitrobenz...
Acta Phys. -Chim. Sin. 1989, 5 (02), 151-155.
DOI: 10.3866/PKU.WHXB19890205
4572
Abstract/Metrics
2414
PDF(1666KB)
THERMODYNAMIC ANALYSIS OF BINARY PHASE DIAGRAM INVOLVING AN INTERMEDiATE COMPOUND
Li Ruiqing; Zhou Guozhi
In a binary system involving an intermediate compound,if the liquidus has been measured, if the entropy or enthalpy of f...
Acta Phys. -Chim. Sin. 1989, 5 (02), 156-162.
DOI: 10.3866/PKU.WHXB19890206
5576
Abstract/Metrics
2321
PDF(1941KB)
INFINITZ DILUTE THERMODYNAMIC QUANTITIES OF ALCOHOLS IN INERT SOLVENTS BY GAS-IQUID CHROMATOGRAPHY
Qiu Liyan; Zheng Guokang; Zhou Xiaoxian
The infinite dilution activity coefficients γ_i, partial molar excess enthalpies H_i~E and entropies S_i~E of C_1—C_4 al...
Acta Phys. -Chim. Sin. 1989, 5 (02), 163-167.
DOI: 10.3866/PKU.WHXB19890207
5007
Abstract/Metrics
2131
PDF(1878KB)
THERMODYNAMICS OF ASSOCIATED SOLUTIONS OF ALCOHOLS IN INERT SOLVENTS
Zheng Guokang; Qiu Liyan; Zhou Xiaoxian
Under the condition of infinite dilution, the activity coefficients previously obtained have been treated by Kretschmer-...
Acta Phys. -Chim. Sin. 1989, 5 (02), 168-172.
DOI: 10.3866/PKU.WHXB19890208
5514
Abstract/Metrics
2188
PDF(1769KB)
AN INVESTIGATION ON PHASE DIAGRAM OF TERNARY SYSTEM PrCl
3
-BaCl
2
-LiCl
Zheng Chaogui; Jin Jun; Qiao Zhiyu; Ye Yupu
The phase diagram of ternary system PrCl_3-BaCl_2-LiCl has been investigated by means of DTA and X-ray diffraction analy...
Acta Phys. -Chim. Sin. 1989, 5 (02), 173-177.
DOI: 10.3866/PKU.WHXB19890209
4856
Abstract/Metrics
2295
PDF(1569KB)
ATALYTIC PERFORMANCE OF PILLARED INTERLAYERED CLAY MOLECULAR SIEVE WITH HIGH THERMAL STABILITY
Gao Zi; Jiao Jinbao
The surface acidity of a kind of pillared interlayered clay molecular sieve with high thermal and hydrothermal stabiliti...
Acta Phys. -Chim. Sin. 1989, 5 (02), 178-184.
DOI: 10.3866/PKU.WHXB19890210
4444
Abstract/Metrics
2182
PDF(2332KB)
ADSORPTION OF POLYETHYLENE GLYCOLS, POLYPROPYLENE GLYCOL AND POLYOXYETHYLENE-POLYOXYPROPYLENE BLOCK COPOLYMERS ON SOLID/LIQUID INTERFACES Ⅰ .ACTIVE CARBON/WATER INTERFACE
Zhao Zhenguo; Gu Tiren
The adsorption isotherms of polyethylene glycols(PEG,molecular weights of 400,1000, 3350, 6000 and 20000), one polypropy...
Acta Phys. -Chim. Sin. 1989, 5 (02), 185-190.
DOI: 10.3866/PKU.WHXB19890211
6055
Abstract/Metrics
2171
PDF(1945KB)
DETERMINING BIFURCATION OF BRUSSELATOR AND OREGONATOR BY LYAPUNOV EXPONENT
Liu Junli; Gai Feng; Han Degang; Lin Qiuzhu; Gao Zhidi
The variation of Lyapunov exponent of Brusselator and Oregonator with controlling parameters of systems has been calcula...
Acta Phys. -Chim. Sin. 1989, 5 (02), 191-195.
DOI: 10.3866/PKU.WHXB19890212
5303
Abstract/Metrics
2159
PDF(1630KB)
ACTIVE PHASE AND ROLE OF POTASSIUM IN POTASSIUM-PROMOTED IRON OXIDE CATALYST FOR DEHYDROGENATION OF ETHYLBENZENE
Zhu Yixiang; Lin Rencun; He Danyun; Yan Jian
Fe_2O_3-K_2O binary catalysts prepared by high temperature calcination of the relevant mixtures and by KOH solution impr...
Acta Phys. -Chim. Sin. 1989, 5 (02), 196-201.
DOI: 10.3866/PKU.WHXB19890213
5699
Abstract/Metrics
2199
PDF(2226KB)
ESR STUDIES OF CuTAPP SUPPORTED ON ACTIVE CARBON (Ⅱ)
Lu Juntao; Liu Xiaoping; Zha Quansin
ESR studies were carried out in detail to investigate the changes of CuTAPP (cppper tetra-(p-trimethylanmoniumphyenl) po...
Acta Phys. -Chim. Sin. 1989, 5 (02), 202-205.
DOI: 10.3866/PKU.WHXB19890214
4650
Abstract/Metrics
2277
PDF(1840KB)
INVESTIGATION OF DISPERSION OF NICKEL OXIDE ONTO THE SURFACE OF
γ
-ALUMINA BY EXAFS
Jin Xianglin; Cai Xiaohai; Ge Zhihong; Xie Youchang; Tang Youqi
Zhao Yaqin; Lu Kunquan
EXAFS spectroscopy has been used to investigate the dispersion of NiO onto the surface of γ-Al_2O_3. The comparison of t...
Acta Phys. -Chim. Sin. 1989, 5 (02), 206-209.
DOI: 10.3866/PKU.WHXB19890215
4667
Abstract/Metrics
2365
PDF(1611KB)
Note
GROUP REACTIVITIES IN THE GAS PHASE REACTIONS OF HYDROXYL RADICALS WITH ETHERS
Liu Renzhang*; Wallington; Timothy J. Dagaut; Philippe Kurylo; Michael J.
Acta Phys. -Chim. Sin. 1989, 5 (02), 210-213.
DOI: 10.3866/PKU.WHXB19890216
5097
Abstract/Metrics
2360
PDF(1468KB)
THE PREOSCILLATORY TIME AND PERIOD OF PHENOL-BrO
3
-H
2
SO
4
SYSTEM
Gao Zhidi; Yu Baoqing; Liu Junli; Lin Qiuzhu
The variation of preoscillatory time and period with initial concentration of every substance in the phenol-BrO_3~--H_2S...
Acta Phys. -Chim. Sin. 1989, 5 (02), 214-217.
DOI: 10.3866/PKU.WHXB19890217
4360
Abstract/Metrics
2128
PDF(1348KB)
INVESTIGATION OF Ba
2
CdMoO
6
AND A NEW COMPOUND Sr
2
CdMoO
6
CRYSTAL STRUCTURES
Fu Zhengmin*; Ma Fengzhe; Mu Jianping
The crystal structure of Ba_2CdMoO_6 have been investigated by means of X-ray powder method, precise measurement of latt...
Acta Phys. -Chim. Sin. 1989, 5 (02), 218-223.
DOI: 10.3866/PKU.WHXB19890218
4261
Abstract/Metrics
2162
PDF(1890KB)
PREDICTION OF EXCESS VOLUME AND EXCESS ENTHALPY FROM PROPERTIES OF PURE COMPONENTS——PROPOSAL OF A NEW EQUATION OF CORRELATION
Zhang Jianhou*; Hou Huaiwen
On the basis of a general functional relation representing the actual PVT properties of liquids, an equation of state of...
Acta Phys. -Chim. Sin. 1989, 5 (02), 224-227.
DOI: 10.3866/PKU.WHXB19890219
4875
Abstract/Metrics
2270
PDF(1357KB)
MODIFICATION OF THE EMPIRICAL POTENTIAL ENERGY FUNCTIONS
Xu Zongrong; Tian Zhiyue*
A general method to modify the empirical potential energy functions is proposed V(r)=W(r)V′(r) with correction function ...
Acta Phys. -Chim. Sin. 1989, 5 (02), 228-231.
DOI: 10.3866/PKU.WHXB19890220
3981
Abstract/Metrics
2255
PDF(1308KB)
A THEORITICAL STUDY ON THE INTERACTIONS OF FORMALDEHYDE AND ACETONE WITH TERPOLYMER OF FORMALDEHYDE AND ITS DERIVATIVES
Cai Guoqiang*; Jing Fuqiang
We have studied the interaction of acetone and formaldehyde with terpolymer of formaldehyde and its methyl-,nitrile-and ...
Acta Phys. -Chim. Sin. 1989, 5 (02), 232-235.
DOI: 10.3866/PKU.WHXB19890221
4392
Abstract/Metrics
2053
PDF(1430KB)
THE STUDY OF ATOMIC STRUCTURE OF THE Ti(0001)SURFACE BY LOW-ENERGY-ELECTRON-DIFFRACTION
Lan Tian*; Xu Feiyue
The present paper presents the results of a structural study of the clean Ti(0001) surface carried out by analysis of Lo...
Acta Phys. -Chim. Sin. 1989, 5 (02), 236-238.
DOI: 10.3866/PKU.WHXB19890222
4562
Abstract/Metrics
2104
PDF(1132KB)
STUDIES ON THERMOCHEMISTRY OF PORPHYRINS——Ⅳ.A PRECISION ROTATING-BOMB COMBUSTION CALORIMETER AND IT'S CALIBRATION
Zhang Faming; Xu Guiduan*; Qu Songsheng
A precision rotating-bomb combustion calorimeter in which thermistors were used as elements of temperature control and t...
Acta Phys. -Chim. Sin. 1989, 5 (02), 239-242.
DOI: 10.3866/PKU.WHXB19890223
3838
Abstract/Metrics
2289
PDF(1386KB)
THE TAFEL PLOT OF THIONYL CHLORIDE REDUCTION
Li Changming*; Zha Quanxin
The electrochemical behaviors of thionyl chloride reduction in 0.11 mol dm~(-3) SOCl_2+ 0.1 mol dm~(-3) LiA1CI_4/DMF sol...
Acta Phys. -Chim. Sin. 1989, 5 (02), 243-245.
DOI: 10.3866/PKU.WHXB19890224
4626
Abstract/Metrics
2291
PDF(1105KB)
RESEARCH ON BELOUSV-ZHABOTINSKII REACTION WITH GALLIC ACID AS SUBSTRATES
Zhang Tianxi; Zhang Dingheng; Liu Zhiding*
In perfect mixture of CSTR, oscillation behavior of B-Z reaction system with gallic acid as organic substrates have been...
Acta Phys. -Chim. Sin. 1989, 5 (02), 246-249.
DOI: 10.3866/PKU.WHXB19890225
3976
Abstract/Metrics
2394
PDF(1480KB)
THE EFFECTS OF ENVIRONMENTS ON THE FLUORESCENCE SPECTRUM OF HYPOCRELLIN A
Diwu Zhenjun; Jiang Lijin*; Zhang Manhua
In this paper, the effects of the concentration of Hypocrellin A, solvents, acid, bases, dispersing agents and temperatu...
Acta Phys. -Chim. Sin. 1989, 5 (02), 250-253.
DOI: 10.3866/PKU.WHXB19890226
4528
Abstract/Metrics
2129
PDF(1535KB)