物理化学学报 >> 1987, Vol. 3 >> Issue (03): 242-247.doi: 10.3866/PKU.WHXB19870305

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煤裂解反应红外光谱研究

王骊; 冯光瑛; 杨惠星   

  1. 北京大学化学系
  • 收稿日期:1985-12-03 修回日期:1986-05-10 发布日期:1987-06-15
  • 通讯作者:

IR STUDY ON COAL PYROLYSIS

Wang Li; Fen Guanging; Yang Huixing   

  1. Department of Chemistry; Peking University
  • Received:1985-12-03 Revised:1986-05-10 Published:1987-06-15
  • Contact:

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摘要： 本文用红外光谱检出了我国河北峰峰煤矿黄沙肥煤中的主要官能团, 定量地研究了该煤在裂解过程中主要官能团, OH、CH_2、C—O—C、芳香族稠环等的反应动力学。求出各种官的团在不同裂解温度下的反应速率常数、反应级数及表观活化能。

Abstract: The groups, OH, CH_2, CH_3, C—O—C etc. in fat coal from Feng-Feng in He-Bei province has been examined. The disappearance kinetics of these groups were also determined by IR method. The results showed that the disappearance reactions for these groups followed first-order reaction.The rate constants and corresponding activation energies to each reaction are:
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v/cm~(-1) group 10~2 k/s~(-1) E_a/kJ mol~(-1)
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500 ℃ 550 ℃ 600 ℃
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3690 OH 2.92 9.05 9.26 68.1
2920 CH 5.16 9.47 12.8 53.5
1600 Aromatic 1.85 2.03 6.22 71.9
C=C
1035 Asymmetric 2.05 4.21 8.31 81.1
Ar—O—C
1010 Symmetric 1.85 4.17 7.92 85.3
Ar—O—C
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