物理化学学报 >> 1987, Vol. 3 >> Issue (03): 286-291.doi: 10.3866/PKU.WHXB19870312

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用旋转园盘-园环电极研究碘酸盐阴极还原反应的机理

顾登平; 李海英   

  1. 河北师范大学化学系
  • 收稿日期:1985-12-02 修回日期:1986-07-19 发布日期:1987-06-15

THE STUDY OF ELECTROREDUCTIVE MECHANISM OF IODATE BY USING ROTATING RING-DISK ELECTRODE

Gu Dengping; Li Haiying   

  1. Department of Chemistry; Hebei Normal University; Shi jiazhuang
  • Received:1985-12-02 Revised:1986-07-19 Published:1987-06-15

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摘要： 本文研究了低浓度的碘酸盐在硫酸介质中, 在铂电报上的电化学还原。用旋转盘环电极检测到了碘酸盐阴极还原的中间产物I_2及最终产物I~-。测定了电化学反应的动力学参数。最后提出了磺酸盐阴极反应的机理。

Abstract: The electroreduction of low concentration iodate in H_2SO_4 was studied on the platinum electrode. The intermediate I_2 and the final product I~-, which are form- ed during the electroreduction of iodate, are detected by using the rotating ring-disk electrode. The kinetic parameters were measured. The mechanism of eletroreduction of iodate are proposed here.