物理化学学报 >> 1991, Vol. 7 >> Issue (03): 289-293.doi: 10.3866/PKU.WHXB19910306

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荧光光谱和吸收光谱研究脂肪醇与β-环糊精的相互作用

江云宝; 黄贤智; 陈国珍   

  1. 厦门大学化学系，厦门 361005
  • 收稿日期:1990-02-25 修回日期:1990-09-13 发布日期:1991-06-15
  • 通讯作者:

A Study of the Interaction of Aliphatic Alcohol with β-Cyclodextrin by Fluorescence and Absorption Spectroscopies

Jiang Yun-Bao; Huang Xian-Zhi; Chen Guo-Zhen   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Received:1990-02-25 Revised:1990-09-13 Published:1991-06-15
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摘要： 选择芘作为光谱探针, 用荧光光谱和吸收光谱法研究了一些水溶性脂肪醇与β-环糊精(β-CD)间的相互作用。结果表明, 一元醇使得β-CD空腔极性减小, 芘-β-CD包络物的形成常数增大; 而多元醇具有相反的效应, 指出醇与β-CD端羟基间的氢键作用是导致这些效应的本质原因。

关键词: 脂肪醇, β-环糊精, 荧光和吸收光谱

Abstract: Pyrene was used as a spectral probe in studying the interaction of some watersoluble aliphatic alcohols with β-cyclodextrin (β-CD) by fluorescence and absorption spectroseopies. Results showed that monobasic alcohol can decrease the micropolarity of β-CD cavity, but the formation constant of pyrene-β-CD inclusion complex is being larger, and polybasie alcohol had the opposite effects. The hydrogen-bonding interaction between alcohols and β-CD was proposed to explain the results.

Key words: Aliphatic alcohols, β-Cyelodextrin, Fluorescence and Absorption Spectroscopies