物理化学学报 >> 1992, Vol. 8 >> Issue (01): 8-9.doi: 10.3866/PKU.WHXB19920103

通讯 上一篇    下一篇

铌硫簇离子的激光产生与质谱分析

黄荣彬; 张鹏; 朱永宝; 郑兰荪   

  1. 厦门大学化学系，厦门 361005
  • 收稿日期:1991-09-04 修回日期:1991-10-21 发布日期:1992-02-15
  • 通讯作者: 郑兰荪

Mass Spectrometry of Niobium and Sulfur Mixed Cluster Ions Generated in Laser Plasma

Huang Rong-Bin; Zhang Peng; Zhu Yong-Bao; Zheng Lan-Sun   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Received:1991-09-04 Revised:1991-10-21 Published:1992-02-15
  • Contact: Zheng Lan-Sun

PDF

3057

赞

关键词: 激光等离子体反应, 类芳香性, 铌硫簇离子

Abstract: Cluster ions of niobium and sulfur were generated in laser plasma reactions on a self-built apparatus. Among all Nb_nS_m~+, the cluster cations with the compositions of n<4, m=n+1; n>3, m=n+2 have special high ion intensities in mass spectrum. The cluster anions of high intensities have four more sulfur atoms compared with the relative cations. By analogousing to [Mo_3S_4]~(4+) clusters, it is proposed that these cluster ions contain non-planar puckered rings with quasi-aromaticity.

Key words: laser plasma reaction, quasi-aromativitv mixed cluster ions of niobium and sulfur