物理化学学报 >> 1992, Vol. 8 >> Issue (03): 424-428.doi: 10.3866/PKU.WHXB19920327

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微电极的稳态可逆极化曲线

刘小平; 陆君涛; 查全性   

  1. 武汉大学化学系，武汉 430072
  • 收稿日期:1991-11-03 修回日期:1991-08-19 发布日期:1992-06-15
  • 通讯作者:

Steady State Reversible Voltammetric Waves of Microelectrodes

Liu Xiao-Ping; Lu Jun-Tao; Zha Quan-Xing   

  1. Department of Chemistry, Wuhan University, Wuhan 430072
  • Received:1991-11-03 Revised:1991-08-19 Published:1992-06-15
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关键词: 任意形状微电极, 稳态测量, 可逆伏安曲线

Abstract: In this work it is proved that the expression for steady state reversible voltammetric waves of a microelectrode is independent of the electrode geometry, provided that the migration of species O and R, the natural convection and the ohmic drop of the solution are neglected.

Key words: Microelectrodes, Steady state voltammetry, Reversible electrode reactions