物理化学学报 >> 1994, Vol. 10 >> Issue (07): 662-665.doi: 10.3866/PKU.WHXB19940717

研究简报 上一篇    下一篇

对甲苯磺酰胺电还原过程的电化学-ESR研究

黄树坤, 陈林生, 谢乃贤, 汪凤珍, 刘国根   

  1. 湖南大学化学化工系，长沙 410082|中南工业大学测试中心，长沙 410083
  • 收稿日期:1993-01-08 修回日期:1993-10-08 发布日期:1994-07-15
  • 通讯作者: 黄树坤

Electrochemical-ESR Study of Electroreduction Process of p-toluene Sulfonamide

Huang Shu-Kun, Chen Lin-Sheng, Xie Nai-Xian, Wang Feng-Zhen, Liu Guo-Gen   

  1. Department of Chemistry and Chemical Engineering, Hunan University, Changsha 410082|Centre Laboratory, Centre South University of Technology, Changsha 410083
  • Received:1993-01-08 Revised:1993-10-08 Published:1994-07-15
  • Contact: Huang Shu-Kun

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关键词: 对甲苯磺酰胺, 电还原机理, 自旋捕捉技术, 对甲苯基/苄基自由基

Abstract:

Electron spin resonance trapping technique with phenyl t-butyl nitrone (PBN) have been used to study the process of electroreduction of p-toluene sulfonamide at mercury electrode. The results showed that the reaction is a free radical one. p-toluene/benzyl radicals formed yia a stage of detaching sulfonamide group have been identified by the hyperfine spectrum of the radical adducts.

Key words: p-toluene sulfonamide, Electroreduction mechanism, Spin trapping technique, p-toluene/Benzyl radicals