物理化学学报 >> 1994, Vol. 10 >> Issue (08): 755-758.doi: 10.3866/PKU.WHXB19940818

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[CuCl3CPZ(O)H]络合物的合成及电化学行为的研究

李春光, 崔刚   

  1. 延边医学院药学系，延吉 133000
  • 收稿日期:1993-04-28 修回日期:1993-10-19 发布日期:1994-08-15
  • 通讯作者:

Synthese and Properties of Electrochemical of [CuCl3CPZ(O)H] Complex

Li Chun-Guang, Cui Gang   

  1. Department Pharmacy Yanji Medical College,Yanji 130000
  • Received:1993-04-28 Revised:1993-10-19 Published:1994-08-15
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关键词: 盐酸氯丙嗦, 循环伏安, 电导, 络合物

Abstract:

CPZ(O)HCl was synthesized by oxdation of 2-clilorcr-10-(3- dimethylaminopropyl) phenothiazime hydrochloride (CPZHCl) and reacted with CuCl2 to produce [CuCl3CPZ(O)H] complex. The properties of electrochemical of [CuCl3CPZ(O)H] were studies by cyclic voltammetry and conductivity method. The reaction of [CuCl3CPZ(O)H] complex on GC electrode shows single electron reaction and order of magnitude of k 10-4cm.s-1. Molal conductivities of [Cu(Ⅱ)Cl3CPZ(O)H] and CPZ(O)HCl are 220-122S.cm2 .mol-1 and 150-48S'cm2 .mol-1.

Key words: Chiorpromazine hydrochloride, Cyclic voltammetry, Electric conductance, Complex