物理化学学报 >> 1998, Vol. 14 >> Issue (10): 865-868.doi: 10.3866/PKU.WHXB19981001

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CF自由基5pπE2Пr(ν’=1)←X2П(ν’’=0)带的转动分析

张群, 束继年, 周晓国, 戴静华, 李全新   

  1. 中国科技大学化学物理系，合肥 230026|中国科学院选键化学开放实验室
  • 收稿日期:1998-06-08 修回日期:1998-07-14 发布日期:1998-10-15
  • 通讯作者:

The Rotational Analysis for the 5pπE2Пr(ν’=1)←X2П(ν’’=0) Band of CF Radical

Zhang Qun, Shu Ji-Nian, Zhou Xiao-Guo, Dai Jing-Hua, Li Quan-Xin   

  1. Department of Chemical Physics,University of Science and Technology of China,Hefei 230026|Open Laboratory of Band-Selective Chemistry,Chinese Academy of Science
  • Received:1998-06-08 Revised:1998-07-14 Published:1998-10-15
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关键词: CF自由基, 共振增强多光子电离(REMPI), pπE2Пr态, 光谱常数

Abstract:

The two-photon resonance-enhanced multiphoton ionization spectrum between 285 and 288.5 nm of the 5pπE2Πr(v’=1)←X2Πr(v’’=0) band of CF radical is reported. The band is rotationally analyzed, and the spectroscopic constants of the state are first derived: σ0 = 69566.38±0.52 cm-1, A'v= 46.4±0.3 cm-1, B'v= 2.565±0.017 cm-1, D' v = (8.6±1.2)×10-6cm-1.

Key words: CF radical, REMPI, pπE2Пr state, Spectroscopic constants