物理化学学报 >> 2001, Vol. 17 >> Issue (08): 696-701.doi: 10.3866/PKU.WHXB20010806

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亚硝胺在沸石上催化分解的研究

薛军;朱建华;沈彬;马丽丽   

  1. 南京大学化学化工学院化学系，南京　210093
  • 收稿日期:2001-01-02 修回日期:2001-03-23 发布日期:2001-08-15
  • 通讯作者: 朱建华 E-mail:jhzhu@nju.edu.cn

Investigation on Catalytic Decomposition of N-nitrosamines over Zeolites

Xue Jun;Zhu Jian-Hua;Shen Bin;Ma Li-Li   

  1. Department of Chemistry, Chemistry ＆Chemical Engineering College, Nanjing University, Nanjing　210093
  • Received:2001-01-02 Revised:2001-03-23 Published:2001-08-15
  • Contact: Zhu Jian-Hua E-mail:jhzhu@nju.edu.cn

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摘要： 采用气相色谱质谱（GCMSD）、程序升温表面反应（TPSR）和红外光谱（IR）技术研究吡咯烷亚硝胺（NPYR）和二甲基亚硝胺（NDMA）等亚硝胺在NaY、HY、NaZSM5、HZSM5等沸石上的催化分解，并剖析其产物分布,发现亚硝胺在Na＋型沸石上的裂解产物近似于热裂解,而在H＋型沸石上则发生了质子参与的催化裂解反应.

关键词: 沸石催化材料, 亚硝胺分解反应, 气相色谱-质谱, 程序升温表面反应

Abstract: Decomposition of Nnitrosodimethylamine (NDMA) and Nnitrosopyrrolidine (NPYR) on zeolite Y and ZSM5 was investigated by means of temperature programmed surface reaction(TPSR) combined with GCMSD and IR techniques. Degradation of Nnitrosamine strongly depended on the activity of zeolite and was accelerated by acid sites. Products of Nnitrosamines degradation were changed by zeolite catalysis, cyano derivative appeared as the main product on NaZSM5 and NaY zeolites similar to that in pyrolysis while dimethylamine became the dominant one on HZSM5 and HY. Different reactions are thus proposed: on the latter the Bronsted acid sites probably play the role of main catalytic sites, hence Nnitrosamines degrades to amines while on the former Nnitrosamines may decompose through radical reaction process, similar to the process of pyrolysis. Protonation of zeolite NaY or NaZSM5 is proved not to be necessary for decomposition of Nnitrosamines. Zeolites are proved to be the novel materials for removing Nnitrosamines pollutants from environment.

Key words: Zeolite catalytic materials, Decomposition of N-nitrosamines, 　Gas chromatograph-mass spectroscopy, Temperature programmed surface reaction