PEG和PVP改性溶胶-凝胶二氧化硅减反膜的对比

doi:10.3866/PKU.WHXB201202231

物理化学学报 >> 2012, Vol. 28 >> Issue (05): 1197-1205.doi: 10.3866/PKU.WHXB201202231

PEG和PVP改性溶胶-凝胶二氧化硅减反膜的对比

田红¹, 张磊², 徐耀¹, 吴东¹, 吴忠华³, 吕海兵⁴, 袁晓东⁴

1. 中国科学院山西煤炭化学研究所, 中国科学院炭材料重点实验室, 太原030001;
2. 河南理工大学理化学院, 河南焦作454000;
3. 中国科学院高能物理研究所, 同步辐射实验室, 北京100049;
4. 中国工程物理研究院激光聚变研究中心, 四川绵阳621900

收稿日期:2011-10-25 修回日期:2012-01-19 发布日期:2012-04-26
通讯作者: 徐耀 E-mail:xuyao@sxicc.ac.cn
基金资助:
国家自然科学基金(10835008)资助项目

Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP

TIAN Hong¹, ZHANG -Lei², XU Yao¹, WU Dong¹, WU Zhong-Hua³, LÜ Hai-Bing⁴, YUAN Xiao-Dong⁴

1. CAS Key Laboratory for Carbon, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
2. College of Science, Henan Polytechnic University, Jiaozuo 454003, Henan Province, P. R. China;
3. Laboratory of Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China;
4. Laer Fusion Research Center,Chinese Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China

Received:2011-10-25 Revised:2012-01-19 Published:2012-04-26
Contact: XU Yao E-mail:xuyao@sxicc.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (10835008).

摘要/Abstract

摘要： 聚乙二醇(PEG)和聚乙烯吡咯烷酮(PVP)对溶胶-凝胶二氧化硅减反膜的结构和激光损伤阈值有不同的影响. 动态光散射、透射电镜(TEM)以及小角X射线散射实验表明: PEG能够促进二氧化硅颗粒的生长并增加团簇生长的一致性. 然而,在PVP改性的溶胶中, Si―OH与PVP之间氢键作用制约了二氧化硅颗粒的生长. 此外, 多重分形谱(MFS)分析表明, PEG可以提高氧化硅薄膜的均匀性, PVP却降低了薄膜的均匀性, 因此, PEG改性的氧化硅薄膜的抗激光损伤性能增强, 而PVP改性的氧化硅薄膜的抗激光损伤性能被削弱. 固体²⁹Si 魔角旋转核磁共振(MAS NMR)结果表明, PEG能够提高Si―O四面体缩聚程度并改善薄膜的表面分形结构, PVP则相反, 导致了PEG改性的氧化硅薄膜与PVP改性的氧化硅薄膜具有不同的抗激光损伤性能.

关键词: 激光损伤阈值, 减反射, 光学膜, 表面分形

Abstract: The different effects of poly(ethylene glycol) (PEG) and poly(vinylpyrrolidone) (PVP) on the structure and laser-induced damage threshold of sol-gel silica anti-reflective films were investigated. The results of dynamic light-scattering, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS) showed that PEG could prompt silica particles to form uniform clusters, whereas in the PVP-modified sol, the growth of silica particles was restricted. This was a result of the strong hydrogen bonds between Si―OH groups and PVP molecules Multi-fractal spectrum (MFS) analysis suggested that PEG improved the uniformity of the silica film but PVP reduced it, therefore the laser-damage resistance of the PEG-modified silica film was enhanced, but that of the PVP-modified silica film was weakened. ²⁹Si magic-angle spinning nuclear magnetic responance (MAS NMR) showed that PEG improved the condensation of Si ―O tetrahedron, but PVP did not. This led to differences between the laser-damage resistances of PEG-modified silica films and PVP-modified silica films.

Key words: Laser-induced damage, Anti-reflection, Optical film, Surface fractal

田红, 张磊, 徐耀, 吴东, 吴忠华, 吕海兵, 袁晓东. PEG和PVP改性溶胶-凝胶二氧化硅减反膜的对比[J]. 物理化学学报, 2012, 28(05), 1197-1205. doi: 10.3866/PKU.WHXB201202231

TIAN Hong, ZHANG -Lei, XU Yao, WU Dong, WU Zhong-Hua, LÜ Hai-Bing, YUAN Xiao-Dong. Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP[J]. Acta Phys. -Chim. Sin. 2012, 28(05), 1197-1205. doi: 10.3866/PKU.WHXB201202231

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201202231

https://www.whxb.pku.edu.cn/CN/Y2012/V28/I05/1197

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PEG和PVP改性溶胶-凝胶二氧化硅减反膜的对比

Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP

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