新形金纳米片的简单制备与生长机制

doi:10.3866/PKU.WHXB201311053

物理化学学报 >> 2014, Vol. 30 >> Issue (1): 194-204.doi: 10.3866/PKU.WHXB201311053

材料物理化学上一篇

新形金纳米片的简单制备与生长机制

王长顺¹, 阚彩侠^1,2, 倪媛¹, 徐海英¹

1 南京航空航天大学理学院应用物理系, 南京 211106;
2 南京航空航天大学, 纳智能材料器件教育部重点实验室, 南京 211106

收稿日期:2013-08-23 修回日期:2013-11-04 发布日期:2014-01-01
通讯作者: 王长顺, 阚彩侠 E-mail:cxkan@nuaa.edu.cn，changshun@nuaa.edu.cn
基金资助:
南京航空航天大学基本科研项目(NZ2013204)资助

Facile Preparation and Growth Mechanism of New-Type Gold Nanoplates

WANG Chang-Shun¹, KAN Cai-Xia^1,2, NI Yuan¹, XU Hai-Ying¹

1 Department of Applied Physics, College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China;
2 Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China

Received:2013-08-23 Revised:2013-11-04 Published:2014-01-01
Contact: WANG Chang-Shun, KAN Cai-Xia E-mail:cxkan@nuaa.edu.cn，changshun@nuaa.edu.cn
Supported by:
The project was supported by the Nanjing University of Aeronautics and Astronautics Fundamental Research Funds, China (NZ2013204).

摘要/Abstract

摘要：

在室温(~30 ℃)条件下，氯金酸(HAuCl₄)均匀混合在粘稠的表面活性剂聚乙烯吡咯烷酮(PVP)胶体(水为溶剂)中，HAuCl₄可以被PVP还原，从而形成纳米片. 本工作中，通过调整晶体生长条件，成功合成了大量新形貌的单晶金纳米片(厚度数十纳米，尺寸为数个微米). 例如，在晶体生长初期阶段，通过引入温度变化(如降温10-20 ℃)，形成的金纳米片主要是六角星形，并伴有盾状、内凹外凸的三角状、截角的、三叉的及多台阶等新形纳米片. 结合理论计算，阐明了金纳米片的生长机制：在一定条件下，金(111)晶面不仅可以沿着<110>方向生长成为常规的三角或六角纳米片，还可以沿<211>、<321>等不同方向生长成含有更高指数侧面的新形金纳米片.

关键词: 金纳米片, 聚乙烯吡咯烷酮, 星形, 生长机制, 高指数面

Abstract:

When a sticky gel consisting of an aqueous HAuCl₄ solution mixed with poly-vinylpyrrolidone (PVP) surfactant is kept at room temperature (about 30 ℃), the HAuCl₄ is reduced by the PVP, resulting in the formation of nanostructures. In this study, gold nanoplates with new shapes, which were single crystalline, several micrometers wide, and tens of nanometers thick, were mass-synthesized by adjusting the crystal growth conditions. For example, through inducing temperature decrease (10-20 ℃) in the early stage of crystal growth, the product is dominated by star-like gold nanoplates, together with other new shapes such as shields, concave and convex triangles, corner snipped shapes, triple branched shapes, and shapes that are step-rich in the side plane. Based on theoretical calculations, we present the growth mechanism of these new gold nanoplates. Under certain growth conditions, the (111) plane of the gold crystal can grow not only along the <110> direction into regular triangular or hexagonal nanoplates, but also along other directions such as <211> and <321>, to give new nanoplates with high-index side facets.

Key words: Gold nanoplate, Poly-vinylpyrrolidone, Star-like shape, Growth mechanism, High-index facet

王长顺, 阚彩侠, 倪媛, 徐海英. 新形金纳米片的简单制备与生长机制[J]. 物理化学学报, 2014, 30(1): 194-204.

WANG Chang-Shun, KAN Cai-Xia, NI Yuan, XU Hai-Ying. Facile Preparation and Growth Mechanism of New-Type Gold Nanoplates[J]. Acta Phys. -Chim. Sin., 2014, 30(1): 194-204.

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201311053

https://www.whxb.pku.edu.cn/CN/Y2014/V30/I1/194

参考文献

(1) Lal, S.; Link, S.; Halas, N. J. Nat. Photonics 2007, 1, 641.doi: 10.1038/nphoton.2007.223
(2) De, M.; Ghosh, P. S.; Rotello, V. M. Adv. Mater. 2008, 20,4225. doi: 10.1002/adma.v20:22
(3) Zijlstra, P.; Chon, J.W.; Gu, M. Nature 2009, 459, 410.doi: 10.1038/nature08053
(4) Vigderman, L.; Khanal, B. P.; Zubarev, E. R. Adv. Mater. 2012,24, 4811. doi: 10.1002/adma.201201690
(5) Liu, X.W.;Wang, D. S.; Li, Y. D. Nano Today 2012, 7, 448.doi: 10.1016/j.nantod.2012.08.003
(6) Gong, J. X.; Li, G. D.; Tang, Z. Y. Nano Today 2012, 7, 564.doi: 10.1016/j.nantod.2012.10.008
(7) Dykman, L.; Khlebtsov, N. Chem. Soc. Rev. 2012, 41, 2256.doi: 10.1039/c1cs15166e
(8) Rycenga, M.; Cobley, C. M.; Zeng, J.; Li,W. Y.; Moran, C. H.;Zhang, Q.; Qin, D.; Xia, Y. N. Chem. Rev. 2011, 111, 3669. doi: 10.1021/cr100275d
(9) Dreaden, E. C.; Alkilany, A. M.; Huang, X. H.; Murphy, C. J.;El-Sayed, M. A. Chem. Soc. Rev. 2012, 41, 2740. doi: 10.1039/c1cs15237h
(10) Li, Z.; Zhang, S.; Halas, N. J.; Nordlander, P.; Xu, H. Small2011, 7, 593. doi: 10.1002/smll.v7.5
(11) Auguie, B.; Barnes,W. L. Phys. Rev. Lett. 2008, 101, 143902.doi: 10.1103/PhysRevLett.101.143902
(12) Naumov, I. I.; Li, Z. Y.; Bratkovsky, A. M. Appl. Phys. Lett.2010, 96, 033105. doi: 10.1063/1.3273859
(13) Ray, P. C. Chem. Rev. 2010, 110, 5332. doi: 10.1021/cr900335q
(14) Ming, T.; Zhao, L.; Xiao, M. D.;Wang, J. F. Small 2010, 6,2514. doi: 10.1002/smll.201000920
(15) Yu, Y. Y.; Chang, S. S.; Lee, C. L.;Wang, C. R. C. J. Phys. Chem. B 1997, 101, 6661. doi: 10.1021/jp971656q
(16) Link, S.; Mohamed, M. B.; El-Sayed, M. A. J. Phys. Chem. B1999, 103, 3073.
(17) van der Zande, B. M. I.; Bohmer, M. R.; Fokkink, L. G. J.;Schonenberger, C. Langmuir 2000, 16, 451. doi: 10.1021/la9900425
(18) Jana, N. R.; Gearheart, L.; Murphy, C. J. J. Phys. Chem. B 2001,105, 4065.
(19) Busbee, B. D.; Obare, S. O.; Murphy, C. J. Adv. Mater. 2003, 15,414. doi: 10.1002/adma.200390095
(20) Sun, Y. G.; Xia, Y. N. Adv. Mater. 2002, 14, 833. doi: 10.1002/1521-4095(20020605)14:11<833::AID-ADMA833>3.0.CO;2-K
(21) Chen, S. H.; Carroll, D. L. Nano Lett. 2002, 2, 1003. doi: 10.1021/nl025674h
(22) Sun, Y. G.; Mayers, B.; Xia, Y. N. Nano Lett. 2003, 3, 675.doi: 10.1021/nl034140t
(23) Okada, N.; Hamanaka, Y.; Nakamura, A.; Pastoriza-Santos, I.;Liz-Marzan, L. M. J. Phys. Chem. B 2004, 108, 8751. doi: 10.1021/jp048193q
(24) Kan, C. X.; Zhu, X. G.;Wang, G. H. J. Phys. Chem. B 2006,110, 4651. doi: 10.1021/jp054800d
(25) Li, C. C.; Sato, R.; Kanehara, M.; Zeng, H. B.; Bando, Y.;Teranishi, T. Angew. Chem. Int. Edit. 2009, 48, 6883.doi: 10.1002/anie.v48:37
(26) Sau, T. K.; Rogach, A. L. Adv. Mater. 2010, 22, 1781. doi: 10.1002/adma.v22:16
(27) Chen, A. Q.; Deprince, A. E., III; Demortiere, A.; Joshi-Imre,A.; Shevchenko, E. V.; Gray, S. K.;Welp, U.; Vlasko-Vlasov, V.K. Small 2011, 7, 2365. doi: 10.1002/smll.v7.16
(28) Tao, A. R.; Habas, S.; Yang, P. D. Small 2008, 4, 310.
(29) Tian, N.; Zhou, Z. Y.; Sun, S. G.; Ding, Y.;Wang, Z. L. Science2007, 316, 732. doi: 10.1126/science.1140484
(30) Xia, Y. N.; Xiong, Y. J.; Lim, B.; Skrabalak, S. E. Angew. Chem. Int. Edit. 2009, 48, 60. doi: 10.1002/anie.200802248
(31) Homan, K. A.; Chen, J.; Schiano, A.; Mohamed, M.;Willets, K.A.; Murugesan, S.; Stevenson, K. J.; Emelianov, S. Adv. Funct. Mater. 2011, 21, 1673. doi: 10.1002/adfm.201001556
(32) Kan, C. X.;Wang, C. S.; Li, H. C.; Qi, J. S.; Zhu, J. J.; Li, Z. S.;Shi, D. N. Small 2010, 6, 1768. doi: 10.1002/smll.201000600
(33) Xia, Y. N.; Xia, X. H.;Wang, Y.; Xie, S. F. MRS Bull. 2013, 38,335. doi: 10.1557/mrs.2013.84
(34) Morriss, R. H.; Bottoms,W. R.; Peacock, R. J. J. Appl. Phys.1968, 39, 3016. doi: 10.1063/1.1656724
(35) Kan, C. X.;Wang, C. S.; Zhu, J. J.; Li, H. C. J. Solid State Chem. 2010, 183, 858. doi: 10.1016/j.jssc.2010.01.021
(36) Washio, I.; Xiong, Y. J.; Yin, Y. D.; Xia, Y. N. Adv. Mater. 2006,18, 1745.
(37) Courty, A.; Henry, A. I.; Goubet, N.; Pileni, M. P. Nat. Mater.2007, 6, 900. doi: 10.1038/nmat2004
(38) Radha, B.; Kulkarni, G. U. Crystal Growth & Design 2011, 11,320. doi: 10.1021/cg1015548
(39) Jin, R. C.; Cao, Y. C.; Hao, E.; Metraux, G. S.; Schatz, G. C.;Mirkin, C. A. Nature 2003, 425, 487. doi: 10.1038/nature02020
(40) Li, C. C.; Cai,W. P.; Cao, B. Q.; Sun, F. Q.; Li, Y.; Kan, C. X.;Zhang, L. D. Adv. Funct. Mater. 2006, 16, 83.
(41) Yao, L. Z. Foundation of Crystal Growth; University of Scienceand Technology of China Press: Hefei, 1995; pp 258-310, 409-429. [姚连增. 晶体生长基础. 合肥: 中国科学技术大学出版社, 1995: 258-310; 409-429.]
(42) Kan, C. X.; Cai,W. P.; Li, C. C.; Zhang, L. D. J. Mater. Res.2004, 20, 320.
(43) Kamat, P. V. J. Phys. Chem. B 2002, 106, 7729. doi: 10.1021/jp0209289
(44) Wiley, B.; Sun, Y. G.; Chen, J. Y.; Cang, H.; Li, Z. Y.; Li, X. D.;Xia, Y. N. MRS Bull. 2005, 30, 356. doi: 10.1557/mrs2005.98
(45) Germain, V.; Li, J.; Ingert, D.;Wang, Z. L.; Pileni, M. P. J. Phys. Chem. B 2003, 107, 8717. doi: 10.1021/jp0303826
(46) Aherne, D.; Ledwith, D. M.; Gara, M.; Kelly, J. M. Adv. Funct. Mater. 2008, 18, 2005. doi: 10.1002/adfm.v18:14
(47) Duan, J. Y.; Zhang, Q. X.;Wang, Y. L.; Guan, J. G. Acta Phys. - Chim. Sin. 2009, 25, 1405. [段君元, 章桥新, 王一龙, 官建国.物理化学学报, 2009, 25, 1405.] doi: 10.3866/PKU.WHXB20090731
(48) Wang, Z. L. J. Phys. Chem. B 2000, 104, 1153. doi: 10.1021/jp993593c
(49) Xue, C.; Metraux, G. S.; Millstone, J. E.; Mirkin, C. A. J. Am. Chem. Soc. 2008, 130, 8337. doi: 10.1021/ja8005258
(50) Xiong, Y. J.;Washio, I.; Chen, J. Y.; Cai, H. G.; Li, Z. Y.; Xia, Y.N. Langmuir 2006, 22, 8563. doi: 10.1021/la061323x
(51) Nam, H. S.; Hwang, N. M.; Yu, B. D.; Yoon, J. K. Phys. Rev. Lett. 2002, 89, 275502. doi: 10.1103/PhysRevLett.89.275502
(52) Cao, Y. L.; Ding, X. L.; Li, H. C.; Yi, Z. G.;Wang, X. F.; Zhu, J.J.; Kan, C. X. Acta Phys. -Chim. Sin. 2011, 27, 1273. [曹艳丽,丁孝龙, 李红臣, 伊兆广, 王祥夫, 朱杰君, 阚彩侠. 物理化学学报, 2011, 27, 1273.] doi: 10.3866/PKU.WHXB20110604
(53) Hoppe, C. E.; Lazzari, M.; Pardinas-Blanco, I.; Lopez-Quintela,M. A. Langmuir 2006, 22, 7027. doi: 10.1021/la060885d
(54) Wang, C. S.; Kan, C. X.; Zhu, J. J.; Zeng, X. L.;Wang, X. F.; Li,H. C.; Shi, D. N. Journal of Nanomaterials 2010, 969030.
(55) Delley, B. J. Chem. Phys. 2000, 113, 7756. doi: 10.1063/1.1316015

[1]	刘为燕,李亚东,刘甜,干林. 单分散铁氧体纳米颗粒的生长机制与成分偏聚的透射电子显微研究[J]. 物理化学学报, 2017, 33(10): 2106 -2112 .
[2]	徐海英, 阚彩侠, 王长顺, 倪媛, 刘津升, 徐伟, 柯军华. 一步湿化学法合成超细金纳米线[J]. 物理化学学报, 2015, 31(6): 1186 -1190 .
[3]	徐丽红, 阚彩侠, 王长顺, 从博, 倪媛, 施大宁. 聚乙烯吡咯烷酮辅助的水热法合成形貌可控的银纳米结构[J]. 物理化学学报, 2014, 30(3): 569 -575 .
[4]	莫博, 阚彩侠, 柯善林, 从博, 徐丽红. 银纳米片的研究进展[J]. 物理化学学报, 2012, 28(11): 2511 -2524 .
[5]	曹艳丽, 丁孝龙, 李红臣, 伊兆广, 王祥夫, 朱杰君, 阚彩侠. 形貌可控贵金属纳米颗粒的合成、光学性质及生长机制[J]. 物理化学学报, 2011, 27(06): 1273 -1286 .
[6]	任月萍, 徐程程, 方云. 聚乙烯吡咯烷酮碱性水溶液中金纳米花的简易合成[J]. 物理化学学报, 2011, 27(05): 1244 -1248 .
[7]	傅婧, 乔锦丽, 马建新. 高稳定性化学交联聚乙烯醇/聚乙烯吡咯烷酮碱性固体电解质膜[J]. 物理化学学报, 2010, 26(11): 2975 -2981 .
[8]	王杰, 庄惠照, 薛成山, 李俊林, 徐鹏. Sn 掺杂ZnO 纳米针的结构及其生长机制[J]. 物理化学学报, 2010, 26(10): 2840 -2844 .
[9]	傅婧, 林瑞, 吕洪, 王晓蕾, 马建新, 乔锦丽. 聚乙烯醇/聚乙烯吡咯烷酮碱性复合膜的制备及其性能[J]. 物理化学学报, 2010, 26(10): 2653 -2658 .
[10]	代克化, 毛景, 翟玉春. 凝胶燃烧法合成5 V级正极材料LiNi_0.5Mn_1.5O₄及其高倍率放电性能[J]. 物理化学学报, 2010, 26(08): 2130 -2134 .
[11]	郭元元, 汪明, 毛晓波, 蒋月秀, 王琛, 杨延莲. 阳极氧化铝模板法可控制备金属纳米线和纳米管阵列的生长机制[J]. 物理化学学报, 2010, 26(07): 2037 -2043 .
[12]	杨新伟, 张贵荣, 李永绣, 徐柏庆. 单分散纳米金尺寸的分步晶种生长控制[J]. 物理化学学报, 2009, 25(12): 2565 -2569 .
[13]	段君元, 章桥新, 王一龙, 官建国. 边长为微米级的银纳米片的简易合成与形成机理[J]. 物理化学学报, 2009, 25(07): 1405 -1408 .
[14]	吕勇, 陆文聪, 张良苗, 岳宝华, 尚兴付, 倪纪朋. 核壳结构AlOOH的制备、表征及其生长机制[J]. 物理化学学报, 2009, 25(07): 1391 -1396 .
[15]	阮小云;方云;樊晔. SDS-PVP水溶液中超细镍粉的制备[J]. 物理化学学报, 2008, 24(08): 1513 -1518 .

新形金纳米片的简单制备与生长机制

Facile Preparation and Growth Mechanism of New-Type Gold Nanoplates

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0