物理化学学报 >> 2022, Vol. 38 >> Issue (12): 2208008.doi: 10.3866/PKU.WHXB202208008

所属专题： 纪念傅鹰先生诞辰120周年

综述 上一篇    

二次电池研究进展

黄俊达1,44, 朱宇辉2, 冯煜1, 韩叶虎4, 谷振一5, 刘日鑫6, 杨冬月7, 陈凯7, 张相禹8, 孙威1, 辛森2,*(), 余彦4, 尉海军9, 张旭9, 于乐8, 王华10, 刘新华11, 付永柱12, 李国杰13, 吴兴隆14, 马灿良15, 王飞16, 陈龙17, 周光敏18, 吴思思19, 卢周广19, 李秀婷20, 刘继磊21, 高鹏21, 梁宵22, 常智23, 叶华林24, 李彦光24, 周亮25, 尤雅25, 王鹏飞26, 杨超25, 刘金平25, 孙美玲27, 毛明磊28, 陈浩29, 张山青29, 黄岗7, 余丁山30, 徐建铁31, 熊胜林32, 张进涛32, 王莹33, 任玉荣34, 杨春鹏35, 徐韵涵35, 陈亚楠36, 许运华36, 陈子峰36, 杲祥文37, 浦圣达37, 郭少华6, 李强38, 曹晓雨39, 明军7, 皮欣朋40, 梁超凡40, 伽龙40, 王俊雄18, 焦淑红4, 姚雨4, 晏成林41, 周栋18, 李宝华18, 彭新文42, 陈冲43, 唐永炳43, 张桥保3, 刘奇45, 任金粲45, 贺艳兵18, 郝晓鸽46, 郗凯47, 陈立宝48, 马建民1,*()   

  1. 1 电子科技大学材料与能源学院, 成都 611731
    2 中国科学院化学研究所, 北京 100190
    3 厦门大学材料学院, 福建 厦门 361005
    4 中国科学技术大学材料科学与工程系, 合肥 230026
    5 东北师范大学物理学院, 长春 130024
    6 南京大学现代工程与应用科学学院, 南京 210046
    7 中国科学院长春应用化学研究所, 长春 130022
    8 北京化工大学有机无机复合材料国家重点实验室, 北京 100029
    9 北京工业大学材料与制造学部, 北京 100124
    10 北京航空航天大学化学学院, 北京 100191
    11 北京航空航天大学交通科学与工程学院, 北京 100191
    12 郑州大学化学学院, 郑州 450001
    13 郑州大学橡塑模具国家工程研究中心, 郑州 450002
    14 东北师范大学化学学院, 长春 130024
    15 山西大学分子科学研究所, 太原 030006
    16 复旦大学材料科学系, 上海 200433
    17 华东理工大学化工学院, 上海 200237
    18 清华大学深圳国际研究生院, 广东 深圳518055
    19 南方科技大学材料科学与工程系, 广东 深圳 518055
    20 深圳大学高等研究院, 广东 深圳 518060
    21 湖南大学材料科学与工程学院, 长沙 410082
    22 湖南大学化学化工学院, 长沙 410082
    23 中南大学材料科学与工程学院, 长沙 410083
    24 苏州大学功能纳米与软物质研究院, 江苏 苏州 215123
    25 武汉理工大学材料复合新技术国家重点实验室, 武汉 430070
    26 西安交通大学电气工程学院, 西安 710049
    27 武汉理工大学化学化工与生命科学学院, 武汉 430070
    28 华中科技大学光学与电子信息学院, 武汉 430074
    29 Centre for Catalysis and Clean Energy, School of Environment and Science, Griffith University, Gold Coast, QLD4214, Australia
    30 中山大学化学学院, 广州 510275
    31 华南理工大学环境与能源学院, 广州 510006
    32 山东大学化学与化工学院, 济南 250100
    33 香港中文大学化学系, 香港 999077
    34 常州大学材料科学与工程学院, 江苏 常州 213164
    35 天津大学化工学院, 天津 300350
    36 天津大学材料科学与工程学院, 天津 300350
    37 Department of Materials, University of Oxford, Oxford, OX1 3PH
    38 青岛大学新能源科学与工程系, 山东 青岛 266071
    39 河南工业大学化学化工学院, 郑州 450001
    40 华中科技大学材料科学与工程学院, 武汉 430074
    41 苏州大学能源学院, 江苏 苏州 215006
    42 华南理工大学轻工科学与工程学院, 广州 510641
    43 中国科学院深圳先进技术研究院, 广东 深圳 518055
    44 湖南大学物理与微电子科学学院, 长沙 410082
    45 香港城市大学物理系, 香港 999077
    46 Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9, Canada
    47 西安交通大学化学学院, 西安 710049
    48 中南大学粉末冶金国家重点实验室, 长沙 410083
  • 收稿日期:2022-08-04 录用日期:2022-09-19 发布日期:2022-10-08
  • 通讯作者: 辛森,马建民 E-mail:xinsen08@iccas.ac.cn;nanoelechem@uestc.edu.cn

Research Progress on Key Materials and Technologies for Secondary Batteries

Junda Huang1,44, Yuhui Zhu2, Yu Feng1, Yehu Han4, Zhenyi Gu5, Rixin Liu6, Dongyue Yang7, Kai Chen7, Xiangyu Zhang8, Wei Sun1, Sen Xin2,*(), Yan Yu4, Haijun Yu9, Xu Zhang9, Le Yu8, Hua Wang10, Xinhua Liu11, Yongzhu Fu12, Guojie Li13, Xinglong Wu14, Canliang Ma15, Fei Wang16, Long Chen17, Guangmin Zhou18, Sisi Wu19, Zhouguang Lu19, Xiuting Li20, Jilei Liu21, Peng Gao21, Xiao Liang22, Zhi Chang23, Hualin Ye24, Yanguang Li24, Liang Zhou25, Ya You25, Peng-Fei Wang26, Chao Yang25, Jinping Liu25, Meiling Sun27, Minglei Mao28, Hao Chen29, Shanqing Zhang29, Gang Huang7, Dingshan Yu30, Jiantie Xu31, Shenglin Xiong32, Jintao Zhang32, Ying Wang33, Yurong Ren34, Chunpeng Yang35, Yunhan Xu35, Yanan Chen36, Yunhua Xu36, Zifeng Chen36, Xiangwen Gao37, Shengda D. Pu37, Shaohua Guo6, Qiang Li38, Xiaoyu Cao39, Jun Ming7, Xinpeng Pi40, Chaofan Liang40, Long Qie40, Junxiong Wang18, Shuhong Jiao4, Yu Yao4, Chenglin Yan41, Dong Zhou18, Baohua Li18, Xinwen Peng42, Chong Chen43, Yongbing Tang43, Qiaobao Zhang3, Qi Liu45, Jincan Ren45, Yanbing He18, Xiaoge Hao46, Kai Xi47, Libao Chen48, Jianmin Ma1,*()   

  1. 1 School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China
    2 Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    3 College of Materials, Xiamen University, Xiamen 361005, Fujian Province, China
    4 Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    5 Department of Physics, Northeast Normal University, Changchun 130024, China
    6 College of Engineering and Applied Sciences, Nanjing University, Nanjing 210046, China
    7 Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
    8 State Key Lab of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
    9 Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China
    10 School of Chemistry, Beihang University, Beijing 100191, China
    11 School of Transportation Science and Engineering, Beihang University, Beijing 100191, China
    12 College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
    13 National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou 450002, China
    14 Department of Chemistry, Northeast Normal University, Changchun 130024, China
    15 Institute of Molecular Science, Shanxi University, Taiyuan 030006, China
    16 Department of Materials Science, Fudan University, Shanghai 200433, China
    17 School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    18 Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, Guangdong Province, China
    19 Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, Guangdong Province, China
    20 Institute for Advanced Study, Shenzhen University, Shenzhen 518060, Guangdong Province, China
    21 College of Materials Science and Engineering, Hunan University, Changsha 410082, China
    22 College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
    23 School of Materials Science and Engineering, Central South University, Changsha 420083, China
    24 Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, Jiangsu Province, China
    25 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
    26 School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, China
    27 School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China
    28 School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 China
    29 Centre for Catalysis and Clean Energy, School of Environment and Science, Griffith University, Gold Coast, QLD4214, Australia
    30 School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
    31 School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
    32 School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
    33 Department of Chemistry, The Chinese University of Hong Kong, Hong Kong 999077, China
    34 School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, China
    35 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
    36 School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China
    37 Department of Materials, University of Oxford, Oxford, OX1 3PH
    38 College of Physics Science, Qingdao University, Qingdao 266071, Shandong Province, China
    39 School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China
    40 School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
    41 College of Energy, Soochow University, Suzhou 215006, Jiangsu Province, China
    42 School of Light Industry Science and Engineering, South China University of Technology, Guangzhou 510641, China
    43 Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, Guangdong Province, China
    44 School of Physics & Electronics, Hunan University, Changsha 410082, China
    45 Department of Physics, City University of Hong Kong, Hong Kong 999077, China
    46 Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9, Canada
    47 School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China
    48 State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China
  • Received:2022-08-04 Accepted:2022-09-19 Published:2022-10-08
  • Contact: Sen Xin,Jianmin Ma E-mail:xinsen08@iccas.ac.cn;nanoelechem@uestc.edu.cn
  • About author:Email: nanoelechem@uestc.edu.cn (J.M)
    Email: xinsen08@iccas.ac.cn (X.S.)

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摘要：

能源的存储和利用是当今科学和技术发展中的重大课题之一，尤其是作为高效的电能/化学能转化装置的二次电池相关技术一直是科学家研究的热点领域。在此背景下，本文较为系统地介绍目前二次电池的重要研究进展，将从二次电池的发展历史引入，再到其相关的基础理论知识的介绍。随后较为详细地讨论当前不同体系的二次电池及相关应的关键材料的研究进展，涉及到锂离子电池、钠离子电池、钾离子电池、镁离子电池、锌离子电池、钙离子电池、铝离子电池、氟离子电池、氯离子电池、双离子电池、锂-硫(硒)电池、钠-硫(硒)电池、钾-硫(硒)电池、多价金属-硫基电池、锂-氧电池、钠-氧电池、钾-氧电池、多价金属-氧气电池、锂-溴(碘)电池、水系金属离子电池、光辅助电池、柔性电池、有机电池、金属-二氧化碳电池等。此外，也介绍了电池研究中常见的电极反应过程表征技术，包括冷冻电镜、透射电镜、同步辐射、原位谱学表征、磁性表征等。本文将有助于研究人员对二次电池进行全面系统的了解与把握，并为之后二次电池的研究提供很好的指导作用。

关键词: 二次电池, 电池体系, 电池材料, 电化学知识, 表征技术

Abstract:

The storage and utilization of energy is one of the important topics in the development of science and technology, especially regarding secondary batteries, which are efficient electrical-/chemical-energy-converting devices. This review systematically introduces the important research progress made in the context of secondary batteries, starting from their development and leading to the introduction of related basic theoretical knowledge. The current research on secondary batteries that are based on different systems and related key materials is discussed in detail, and includes lithium-ion batteries, sodium-ion batteries, potassium-ion batteries, magnesium-ion batteries, zinc-ion batteries, calcium-ion batteries, aluminum-ion batteries, fluorine-ion batteries, chloride-ion batteries, dual-ion batteries, lithium-sulfur (Se) batteries, sodium-sulfur (Se) batteries, potassium-sulfur (Se) batteries, polyvalent metal-sulfur-based batteries, lithium-oxygen batteries, sodium-oxygen batteries, potassium-oxygen batteries, aqueous metal-ion batteries, polyvalent metal-oxygen batteries, lithium-bromine (or lithium-iodine) batteries, photo-assisted batteries, flexible batteries, organic batteries, and metal-carbon dioxide batteries. Additionally, the common characterization techniques for electrode reaction processes in battery research are also introduced, including cryo-electron microscopy, transmission electron microscopy, synchrotron radiation, in situ spectroscopic techniques, and magnetic characterization. This paper will help researchers to systematically understand secondary battery technology and provide good guidance for future research on secondary batteries.

Key words: Secondary battery, Battery system, Battery material, Electrochemical knowledge, Characterization technique