调控双钙钛矿中高熵组分促进高温析氧反应

doi:10.3866/PKU.WHXB202306013

物理化学学报 >> 2024, Vol. 40 >> Issue (6): 2306013.doi: 10.3866/PKU.WHXB202306013

所属专题：电化学前沿

调控双钙钛矿中高熵组分促进高温析氧反应

冯炜程¹^,²^,†, 于景成¹^,²^,†, 杨溢澜³, 郭宜阁¹^,², 邹庚¹^,², 刘晓菊⁴, 陈洲⁵, 董坤⁶, 宋月锋¹^,*, 汪国雄¹^,*, 包信和¹

¹ 中国科学院大连化学物理研究所, 催化基础国家重点实验室, 洁净能源国家实验室, 辽宁大连 116023
² 中国科学院大学能源学院, 北京 100049
³ 大连交通大学环境与化学工程学院, 辽宁大连 116028
⁴ 榆林学院化学化工学院, 陕西榆林 719100
⁵ 厦门大学材料学院, 福建厦门 361005
⁶ 中国科学院过程工程研究所, 离子液体清洁过程北京市重点实验室, 多相复杂系统国家重点实验室, 北京 100190

收稿日期:2023-06-05 修回日期:2023-07-31 录用日期:2023-07-31 发布日期:2023-11-29
通讯作者: Email: songyf2014@dicp.ac.cn (宋月锋)wanggx@dicp.ac.cn; Tel.: +86-411-84379976 (汪国雄)
作者简介:
^†These authors contributed equally to this work.
基金资助:
国家重点研发计划(2021YFA1502400); 国家自然科学基金(22272176); 国家自然科学基金(22002166); 国家自然科学基金(22125205); 国家自然科学基金(22072146); 国家自然科学基金(22002158); 中国科学院洁净能源创新研究院合作基金(DNL202007); 榆林学院-中国科学院洁净能源创新研究院联合基金(YLU-DNL Fund 2022008); 中国科学院青年创新促进计划(Y201938)

Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction

Weicheng Feng¹^,², Jingcheng Yu¹^,², Yilan Yang³, Yige Guo¹^,², Geng Zou¹^,², Xiaoju Liu⁴, Zhou Chen⁵, Kun Dong⁶, Yuefeng Song¹^,*, Guoxiong Wang¹^,*, Xinhe Bao¹

¹ State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China
² College of Energy, University of Chinese Academy of Sciences, Beijing 100049, China
³ School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, China
⁴ School of Chemistry and Chemical Engineering, Yulin University, Yulin 719100, Shannxi Province, China
⁵ College of Materials, Xiamen University, Xiamen 361005, Fujian Province, China
⁶ Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2023-06-05 Revised:2023-07-31 Accepted:2023-07-31 Published:2023-11-29
Contact: Email: songyf2014@dicp.ac.cn (Yuefeng Song)wanggx@dicp.ac.cn; Tel.: +86-411-84379976 (Guoxiong Wang)
Supported by:
the National Key R & D Program of China(2021YFA1502400); the National Natural Science Foundation of China(22272176); the National Natural Science Foundation of China(22002166); the National Natural Science Foundation of China(22125205); the National Natural Science Foundation of China(22072146); the National Natural Science Foundation of China(22002158); the DNL Cooperation Fund, CAS(DNL202007); the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy(YLU-DNL Fund 2022008); the CAS Youth Innovation Promotion(Y201938)

1. 附件.pdf(2046KB)

摘要/Abstract

摘要：

固体氧化物电解池(SOEC)中阳极析氧反应动力学较为迟缓，限制了SOEC器件电催化转化能力，因此针对阳极材料的改性研究对于进一步提升SOEC电化学性能十分关键。高熵钙钛矿(HEP)在许多反应中表现出良好的催化活性，但在SOEC中的应用鲜有研究。本文通过在双钙钛矿的A位或Aʹ位分别掺杂不同的稀土金属、碱土金属或碱金属离子，合成了(Pr_0.2La_0.2Sm_0.2Nd_0.2Gd_0.2)BaCo₂O_6−δ (A-HEP)和Pr(Ba_0.2Sr_0.2Ca_0.2Na_0.2K_0.2)Co₂O_6−δ (Aʹ-HEP)两种高熵钙钛矿材料。由于掺杂离子平均半径和氧化态的差异，A-HEP保持四方双钙钛矿相结构而Aʹ-HEP则转变为正交单钙钛矿相。物理化学表征结果表明，A-HEP中Co平均价态更高，Co 2p-O 1s杂化更强，从而增加了电子转移路径并降低了转移能垒。同时，A-HEP中表面氧空位浓度更高，可为阳极析氧反应提供更多的活性位点。因此，在具有A-HEP阳极的SOEC中，与氧输运、电子传输和表界面反应过程相关的阳极极化电阻显著降低，并在800 ℃下实现最高1.76 A∙cm⁻²的电流密度和200 h的稳定性。本工作为高熵钙钛矿材料在SOEC阳极中的应用提供了新的策略。

关键词: 固体氧化物电解池, 高熵钙钛矿, 析氧反应, 氧空位, 电子转移

Abstract:

Solid oxide electrolysis cells (SOECs) could convert CO₂ to CO powered by clean electricity with low overpotential, high Faradaic efficiency, and high current density. Since the performance of SOEC is affected by sluggish oxygen evolution reaction (OER) kinetics at the anodes, the modification of anode materials is crucial for the further application of SOEC. Perovskites with high configurational entropy exhibit high catalytic activity in many reactions, but are rarely reported in SOECs. Herein, two kinds of high entropy perovskites (HEPs), with formulas of (Pr_0.2La_0.2Sm_0.2Nd_0.2Gd_0.2)BaCo₂O_6−δ (A-HEP) and Pr(Ba_0.2Sr_0.2Ca_0.2Na_0.2K_0.2) Co₂O_6−δ (A′-HEP), are synthesized by doping different rare earth metal, and alkaline metal or alkaline earth metal ions into A-site and A′-site of the double perovskites. Rietveld refinement of X-ray diffraction patterns and elemental maps of scanning electron microscope images confirm the successful synthesis of the two samples. The tetragonal double perovskite structure of A-HEP and the transformation to orthorhombic structure of A′-HEP due to the difference in average atomic radii and oxidation states of the doped ions are also detected. Co 2p X-ray photoelectron spectroscopy (XPS) and O K-edge X-ray absorption spectroscopy reveal that the average oxidation state of Co is lifted from +3.23 in Aʹ-HEP to +3.39 in A-HEP, and the hybridization of Co 2p and O 1s orbitals is also enhanced in A-HEP, which increase the electron transfer pathway and reduce the transfer barrier. Therefore, the electrical conductivity of A-HEP at 800 ℃ is higher than that of Aʹ-HEP. Moreover, the increased absorption oxygen species concentration of A-HEP in O 1s XPS and O₂-temperature programmed desorption results indicates more surface oxygen vacancies, thus increasing active sites for the anodic OER. Consequently, the anodic polarization resistances related to oxygen transportation, electron transfer and surface reaction processes are decreased remarkably in A-HEP, resulting in a high current density of 1.76 A∙cm⁻² at 800 ℃ and a stability of 200 h. This work presents a new method for designing high-performance HEPs as SOEC anode materials.

Key words: Solid oxide electrolysis cell, High entropy perovskite, Oxygen evolution reaction, Oxygen vacancy, Electron transfer

冯炜程, 于景成, 杨溢澜, 郭宜阁, 邹庚, 刘晓菊, 陈洲, 董坤, 宋月锋, 汪国雄, 包信和. 调控双钙钛矿中高熵组分促进高温析氧反应[J]. 物理化学学报, 2024, 40(6), 2306013. doi: 10.3866/PKU.WHXB202306013

Weicheng Feng, Jingcheng Yu, Yilan Yang, Yige Guo, Geng Zou, Xiaoju Liu, Zhou Chen, Kun Dong, Yuefeng Song, Guoxiong Wang, Xinhe Bao. Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction[J]. Acta Phys. -Chim. Sin. 2024, 40(6), 2306013. doi: 10.3866/PKU.WHXB202306013

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202306013

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I6/2306013

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参考文献 55

1	Hauch A. ; Kungas R. ; Blennow P. ; Hansen A. B. ; Hansen J. B. ; Mathiesen B. V. ; Mogensen M. B. Science 2020, 370, eaba6118. doi: 10.1126/science.aba6118
2	Zheng Y. ; Wang J. C. ; Yu B. ; Zhang W. Q. ; Chen J. ; Qiao J. L. ; Zhang J. J. Chem. Soc. Rev. 2017, 46, 1427. doi: 10.1039/C6CS00403B
3	Ebbesen S. ; Jensen S. ; Hauch A. ; Mogensen M. Chem. Rev. 2014, 114, 10697. doi: 10.1021/cr5000865
4	Song Y. F. ; Zhang X. M. ; Xie K. ; Wang G. X. ; Bao X. H. Adv. Mater. 2019, 31, e1902033. doi: 10.1002/adma.201902033
5	Hwang J. ; Rao R. R. ; Giordano L. ; Katayama Y. ; Yu Y. ; Shao-Horn Y. Science 2017, 358, 751. doi: 10.1126/science.aam7092
6	Choi J. ; Park S. ; Han H. ; Kim M. ; Park M. ; Han J. ; Kim W. B. J. Mater. Chem. A 2021, 9, 8740. doi: 10.1039/d0ta11328j
7	Ai N. ; He S. ; Li N. ; Zhang Q. ; Rickard W. D. A. ; Chen K. F. ; Zhang T. ; Jiang S. P. J. Power Sources 2018, 384, 125. doi: 10.1016/j.jpowsour.2018.02.082
8	Shao Z. P. ; Haile S. M. Nature 2004, 431, 170. doi: 10.1038/nature02863
9	Jiang S. P. Solid State Ionics 2002, 146, 1. doi: 10.1016/S0167-2738(01)00997-3
10	Chen K. F. ; Ai N. ; Jiang S. P. Int. J. Hydrogen Energy 2014, 39, 0349. doi: 10.1016/j.ijhydene.2014.05.013
11	Woodward P. M. ; Suard E. ; Karen P. J. Am. Chem. Soc. 2003, 125, 8889. doi: 10.1021/ja034813+
12	Woodward P. M. ; Karen P. Inorg. Chem. 2003, 42, 1121. doi: 10.1021/ic026022z
13	King G. ; Woodward P. M. J. Mater. Chem. 2010, 20, 5785. doi: 10.1039/B926757C
14	Karen P. ; Woodward P. M. ; Lindén J. ; Vogt T. ; Studer A. ; Fischer P. Phys. Rev. B 2001, 64, 214405. doi: 10.1103/PhysRevB.64.214405
15	Karen P. M. ; Woodward P. J. Mater. Chem. 1999, 9, 789. doi: 10.1039/A809302D
16	Zhukov V. P. ; Chulkov E. V. ; Politov B. V. ; Suntsov A. Y. ; Kozhevnikov V. L. Phys. Chem. Chem. Phys. 2021, 23, 2313. doi: 10.1039/D0CP05497F
17	Taskin A. A. ; Lavrov A. N. ; Ando Y. Prog. Solid State Chem. 2007, 35, 481. doi: 10.1016/j.progsolidstchem.2007.01.014
18	Taskin A. A. ; Lavrov A. N. ; Ando Y. Appl. Phys. Lett. 2005, 86, 091910. doi: 10.1063/1.1864244
19	Shin T. H. ; Myung J.-H. ; Verbraeken M. ; Kim G. ; Irvine J. T. S. Faraday Discuss. 2015, 182, 227. doi: 10.1039/C5FD00025D
20	Seymour I. D. ; Tarancón A. ; Chroneos A. ; Parfitt D. ; Kilner J. A. ; Grimes R. W. Solid State Ionics 2012, 216, 41. doi: 10.1016/j.ssi.2011.09.002
21	Kim G. ; Wang S. ; Jacobson A. J. ; Reimus L. ; Brodersen P. ; Mims C. A. J. Mater. Chem. 2007, 17, 2500. doi: 10.1039/B618345J
22	Dong F. ; Ni M. ; Chen Y. ; Chen D. ; Tadé M. O. ; Shao Z. J. Mater. Chem. A 2014, 2, 20520. doi: 10.1039/C4TA04372C
23	Akande S. O. ; Boulfrad S. ; Schwingenschlö gl U. J. Mater. Chem. A 2016, 4, 3560. doi: 10.1039/C5TA06858D
24	Rost C. M. ; Sachet E. ; Borman T. ; Moballegh A. ; Dickey E. C. ; Hou D. ; Jones J. L. ; Curtarolo S. ; Maria J.-P. Nat. Commun. 2015, 6, 8485. doi: 10.1038/ncomms9485
25	Wright A. J. ; Wang Q. Y. ; Huang C. Y. ; Nieto A. ; Chen R. K. ; Luo J. J. Eur. Ceram. Soc. 2020, 40, 2120. doi: 10.1016/j.jeurceramsoc.2020.01.015
26	Jiang S. Y. ; Sun D. ; Zhang Y. Q. ; Wang S. B. ; Zhao C. Z. J. Mater. Sci. 2017, 52, 3199. doi: 10.1007/s10853-016-0609-x
27	Xu H. D. ; Zhang Z. H. ; Liu J. X. ; Do-Thanh C.-L. ; Chen H. ; Xu S. H. ; Lin Q. J. ; Jiao Y. ; Wang J. L. ; Wang Y. ; et al Nat. Commun. 2020, 11, 3908. doi: 10.1038/s41467-020-17738-9
28	Chen H. ; Fu J. ; Zhang P. F. ; Peng H. G. ; Abney C. W. ; Jie K. C. ; Liu X. M. ; Chi M. F. ; Dai S. J. Mater. Chem. A 2018, 6, 11129. doi: 10.1039/C8TA01772G
29	Sarkar A. ; Wang Q. ; Schiele A. ; Chellali M. R. ; Bhattacharya S. S. ; Wang D. ; Brezesinski T. ; Hahn H. ; Velasco L. ; Breitung B. Adv. Mater. 2019, 31, e1806236. doi: 10.1002/adma.201806236
30	Shi Y. C. ; Ni N. ; Ding Q. ; Zhao X. F. J. Mater. Chem. A 2022, 10, 2256. doi: 10.1039/d1ta07275g
31	Yang Q. ; Wang G. Q. ; Wu H. D. ; Beshiwork B. A. ; Tian D. ; Zhu S. Y. ; Yang Y. ; Lu X. Y. ; Ding Y. Z. ; Ling Y. H. ; et al J. Alloy. Compd. 2021, 872, 159633. doi: 10.1016/j.jallcom.2021.159633
32	He F. ; Zhou Y. ; Hu T. ; Xu Y. ; Hou M. ; Zhu F. ; Liu D. ; Zhang H. ; Xu K. ; Liu M. ; Chen Y. Adv. Mater. 2023, 35, e2209469. doi: 10.1002/adma.202209469
33	Garcı́a-Muñoz J. L. ; Frontera C. ; Llobet A. ; Carrillo A. E. ; Caneiro A. ; Aranda M. A. G. ; Ritter C. ; Dooryee E. Phys. B 2004, 350, e277. doi: 10.1016/j.physb.2004.03.069
34	Brinks H. W. ; Fjellvåg H. ; Kjekshus A. ; Hauback B. C. J. Solid State Chem. 1999, 147, 464. doi: 10.1006/jssc.1999.8384
35	Guo D. ; Zhang M. ; Chen Z. ; Liu X.-X. RSC Adv. 2018, 8, 33374. doi: 10.1039/C8RA07032F
36	Xin W.-L. ; Lu K.-K. ; Zhu D.-R. ; Zeng H.-B. ; Zhang X.-J. ; Marks R.-S. ; Shan D. Electrochim. Acta 2019, 307, 375. doi: 10.1016/j.electacta.2019.03.196
37	Zhao K. ; Shen Y. ; Huang Z. ; He F. ; Wei G. Q. ; Zheng A. Q. ; Li H. B. ; Zhao Z. L. J. Energy Chem. 2017, 26, 501. doi: 10.1016/j.jechem.2016.11.016
38	Sunarso J. ; Hashim S. S. ; Zhu N. ; Zhou W. Prog. Energy Combust. Sci. 2017, 61, 57. doi: 10.1016/j.pecs.2017.03.003
39	Suntivich J. ; Hong W. T. ; Lee Y.-L. ; Rondinelli J. M. ; Yang W. ; Goodenough J. B. ; Dabrowski B. ; Freeland J. W. ; Shao-Horn Y. J. Phys. Chem. C 2014, 118, 1856. doi: 10.1021/jp410644j
40	Miao X. ; Wu L. ; Lin Y. ; Yuan X. ; Zhao J. ; Yan W. ; Zhou S. ; Shi L. Chem. Commun. 2019, 55, 1442. doi: 10.1039/c8cc08817a
41	Luo Q. X. ; Lin D. ; Zhan W. Q. ; Zhang W. Q. ; Tang L. L. ; Luo J. J. ; Gao Z. ; Jiang P. ; Wang M. ; Hao L. Y. ; et al ACS Appl. Energy Mater. 2020, 3, 7149. doi: 10.1021/acsaem.0c01192
42	Grimaud A. ; Diaz-Morales O. ; Han B. ; Hong W. T. ; Lee Y. L. ; Giordano L. ; Stoerzinger K. A. ; Koper M. T. M. ; Shao-Horn Y. Nat. Chem. 2017, 9, 457. doi: 10.1038/nchem.2695
43	Xi X. ; Liu J. W. ; Luo W. Z. ; Fan Y. ; Zhang J. J. ; Luo J. L. ; Fu X. Z. Adv. Energy Mater. 2021, 11, 2102845. doi: 10.1002/aenm.202102845
44	Li J. W. ; Fu Z. M. ; Wei B. ; Su C. X. ; Yue X. ; Lü Z. J. Mater. Chem. A 2020, 8, 18778. doi: 10.1039/d0ta04857g
45	Guan F. ; Zhang X. M. ; Song Y. F. ; Zhou Y. J. ; Bao X. H. Chin. J. Catal. 2018, 39, 1484. doi: 10.1016/S1872-2067(18)63118-3
46	Zhang X. M. ; Song Y. F. ; Guan F. ; Zhou Y. J. ; Lv H. F. ; Wang G. X. ; Bao X. H. J. Catal. 2018, 359, 8. doi: 10.1016/j.jcat.2017.12.027
47	Li Q. ; Wu J. B. ; Wu T. ; Jin H. R. ; Zhang N. ; Li J. ; Liang W. X. ; Liu M. L. ; Huang L. ; Zhou J. Adv. Funct. Mater. 2021, 31, 2102002. doi: 10.1002/adfm.202102002
48	Song Y. F. ; Zhou Z. W. ; Zhang X. M. ; Zhou Y. J. ; Gong H. M. ; Lv H. F. ; Liu Q. X. ; Wang G. X. ; Bao X. H. Angew. Chem. Int. Ed. 2019, 58, 4617. doi: 10.1002/anie.201814612
49	Wang W. H. ; Yang Y. ; Huan D. M. ; Wang L. K. ; Shi N. ; Xie Y. ; Xia C. R. ; Peng R. R. ; Lu Y. L. J. Mater. Chem. A 2019, 7, 12538. doi: 10.1039/c9ta03099a
50	Ciucci F. ; Chen C. Electrochim. Acta 2015, 167, 439. doi: 10.1016/j.electacta.2015.03.123
51	Saccoccio M. ; Wan T. H. ; Chen C. ; Ciucci F. Electrochim. Acta 2014, 147, 470. doi: 10.1016/j.electacta.2014.09.058
52	Li Y. H. ; Li Y. ; Wan Y. H. ; Xie Y. ; Zhu J. F. ; Pan H. B. ; Zheng X. S. ; Xia C. R. Adv. Energy Mater. 2019, 9, 1803156. doi: 10.1002/aenm.201803156
53	Lv H. F. ; Lin L. ; Zhang X. M. ; Song Y. F. ; Matsumoto H. ; Zeng C. B. ; Ta N. ; Liu W. ; Gao D. F. ; Wang G. X. ; et al Adv. Mater. 2020, 32, e1906193. doi: 10.1002/adma.201906193
54	Song Y. F. ; Zhang X. M. ; Zhou Y. J. ; Lv H. F. ; Liu Q. X. ; Feng W. F. ; Wang G. X. ; Bao X. H. J. Energy Chem. 2019, 35, 181. doi: 10.1016/j.jechem.2019.03.013
55	Zhang X. M. ; Song Y. F. ; Guan F. ; Zhou Y. J. ; Lv H. F. ; Liu Q. X. ; Wang G. X. ; Bao X. H. J. Power Sources 2018, 400, 104. doi: 10.1016/j.jpowsour.2018.08.017

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调控双钙钛矿中高熵组分促进高温析氧反应

Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction

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