物理化学学报 >> 1993, Vol. 9 >> Issue (04): 447-449.doi: 10.3866/PKU.WHXB19930404

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O(1D)+Si(CH3)3Cl反应生成振动激发的OH(ν≤3)

李红志; 王学斌; 孔繁敖; 朱起鹤   

  1. 中国科学院化学研究所，分子反应动力学国家重点实验室，北京 100080
  • 收稿日期:1993-03-29 修回日期:1993-04-05 发布日期:1993-08-15
  • 通讯作者:

Vibrational Excitation of OH(v≤3) from the reaction of O(1D)+Si(CH3)3Cl

Li Hong-Zhi; Wang Xue-Bin; Kong Fan-Ao; Zhu Qi-He   

  1. Institute of Chemistry, CAS, The State Key Laboratory of Malecular Reaction Dynamics, Beijing 100080
  • Received:1993-03-29 Revised:1993-04-05 Published:1993-08-15
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关键词: 能量传输, 重原子效应, 红外发射谱, 三甲基氯硅烷

Abstract: The vibrationally excited OH(v) from the reaction of O(~1D)+Si(CH_3)_3Cl was observed by UV laser photolysis/FTIR emission spectroscopy. The vibrational number was only up to 3 with a ratio of 1:0.8:0.1 for v=1:2:3. Comparing this result with the similar reaction of O(~1D)+Si(CH_3)_4 which OH(v) vibrational number was high up to 4 with a ratio of 1:1:1:0.3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of Cl for CH_3 affected the extent of heavy Si atom blocking the energy migration in a molecule. This results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer.

Key words: Intramolecular energy transfer, IR emission spectroscopy, Heavy atom effect, Chlorotrimethylsilane