物理化学学报 >> 1993, Vol. 9 >> Issue (05): 698-701.doi: 10.3866/PKU.WHXB19930524

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热动力学对比进度法II. 2-2型可逆反应

刘劲松; 曾宪诚; 邓郁   

  1. 四川大学化学系，成都 610064
  • 收稿日期:1992-03-11 修回日期:1992-08-10 发布日期:1993-10-15
  • 通讯作者: 刘劲松

Deduced Extent Method for Thermokinetics II. Thermokinetic Studies on 2-2 Type Reversible Reaction

Liu Jin-Song; Zeng Xian-Cheng; Deng Yu   

  1. Department of Chemistry, Sichuan University, Chengdu 610064
  • Received:1992-03-11 Revised:1992-08-10 Published:1993-10-15
  • Contact: Liu Jin-Song

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关键词: 热动力学, 对比进度法, 可逆反应, 量热

Abstract: Thermokinetics for a 2-2 reversible reaction system, 2-nitropropane with mor-pholion, have been studied at 25 and 30 ℃ in 40% (v/v) ethyl alcohol aqueous solution by the reduced extent method.
The rate constants、equilibrium constants、activation energies、activation free-energies、activation ethalpies and activation entropies of the reversible reaction have been calculated.
The concept of the reduced extent of thermokinetics and the experimetal results have been discussed in this paper.

Key words: Thermokinetics, Reduced extent method, Reversible reaction, Calorimetry