金属气凝胶：可控制备与应用展望

doi:10.3866/PKU.WHXB202212014

摘要/Abstract

摘要：

作为多孔材料家族的最新成员之一，金属气凝胶(Metal aerogels，MAs)是完全由纳米结构金属构筑而成的一类新型气凝胶。MAs兼有金属独特的物理化学性质与气凝胶的结构特征，同时拥有高速传质通道、高导电性三维网络、自支撑性与独特的光学特性，故在电催化、表面增强拉曼散射和生物传感等领域均表现出卓越性能。然而，MAs的研究历史较短，其可控制备、构效关系探索等研究存在众多挑战性问题，距离商业化应用尚有较长的道路。因此，系统梳理MAs的研究工作，从中汲取经验与总结设计原理是极为有益的。本文将对MAs的合成策略、应用研究进行系统评述，在此基础上对本领域的挑战与机遇进行总结展望。希望招徕更多科研工作者，共同探索MAs这一年轻而前景广阔的新材料领域。

关键词: 气凝胶, 金属, 溶胶-凝胶, 纳米结构, 电催化

Abstract:

Emerging as one of the youngest members in the family of porous materials, metal aerogels (MAs) are a new class of aerogels entirely built of nanostructured metals such as gold, silver, palladium, platinum, ruthenium, rhodium, osmium, copper, and nickel. They are typically fabricated via a sol-gel process coupled with special drying techniques (e.g., supercritical drying and freeze-drying). Combining the unique physicochemical properties of various nanostructured metals with the structural attributes of aerogels, MAs mark rapid mass transfer channels, highly conductive three-dimensional (3D) networks, and optical and magnetic properties. In this regard, MAs outperform conventional materials in various territories such as electrocatalysis, enzyme-like catalysis, surface-enhanced Raman scattering, diverse sensing, and actuators. Additionally, a substantial number of metal elements can offer vast opportunities for creating numerous MAs featuring desired properties, which is critical for a deep exploration and releases the full potential of aerogels. Consequently, MAs have received wide attention since their discovery in 2009.However, compared with conventional aerogels, MAs only appeared around a decade ago. A short research history challenges their fundamental studies, including controlled synthesis and structure-performance investigations, thereby retarding on-target materials design for practical applications. Currently, the majority of studies are restricted to MAs based on noble metals. This fact is ascribed to both their intrinsically high catalytic activity and simple fabrication due to the relatively high redox potential. In contrast, reports on low-cost non-noble metal aerogels are largely constrained, not to mention controlled synthesis as well as practical applications. As a result, the compositional and structural diversity of MAs is highly limited. Furthermore, the scope of the application of MAs is still constrained and is mostly restricted to electrocatalysis. Though certain remarkable MA-based electrocatalysts have been reported in the last few years, their limited composition and structure have retarded the systematic investigations into correlations between the material parameters and electrocatalytic properties. This discourages on-demand material design and performance optimization. Hence, fundamental studies and application attempts need to be strengthened to allow further development of this new material system. On this occasion, it is essential to thoroughly summarize the knowledge and design principles of MAs that have been presented in the past ten years. This study comprehensively introduces the state-of-the-art research progress in this field, which includes synthesis strategies, potential gelation mechanisms, and diverse applications of MAs. Additionally, the challenges and opportunities presented by MAs will be drawn from aspects of synthesis and applications. This review expects to attract widespread scientists from different fields (e.g., chemistry, physics, materials science, and life science) to join the area of MAs, thus jointly promoting the development of this young and promising field.

Key words: Aerogels, Metal, Sol-gel, Nanostructures, Electrocatalysis

王宁, 李一, 崔乾, 孙晓玥, 胡悦, 罗运军, 杜然. 金属气凝胶：可控制备与应用展望[J]. 物理化学学报, 2023, 39(9), 2212014. doi: 10.3866/PKU.WHXB202212014

Ning Wang, Yi Li, Qian Cui, Xiaoyue Sun, Yue Hu, Yunjun Luo, Ran Du. Metal Aerogels: Controlled Synthesis and Applications[J]. Acta Phys. -Chim. Sin. 2023, 39(9), 2212014. doi: 10.3866/PKU.WHXB202212014

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202212014

https://www.whxb.pku.edu.cn/CN/Y2023/V39/I9/2212014

图/表 21

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图9

表1

典型MAs的制备方法及产物参数"

Composition	Initiating method or initiator	Gelation time	Density/(mg∙cm⁻³)	Ligament size/nm	Specific surface area/(m²∙g⁻¹)	Reference
Ag	evaporation concentration (313 K)	–	88	113	5.5	23
Au ^a	H₂O₂	~1 week	–	100–500	–	21
Ag ^a	H₂O₂	15 days	–	50–100	–	21
Pt ^a	ethanol	4 weeks	–	–	–	21
Ag ^a	C(NO₂)₄	4–12 h	37–41	5–11 ^b	43–160	45
Au-Ag-Pd ^a	C(NO₂)₄	16–24 h	20–60	4–6	76–269	47
Au-Ag	NaCl	1–28 days	70	15.4 ^b	42	58
Pd-Ag	NaCl	1–28 days	10	13.0 ^b	42	58
Pt-Ag	NaCl	1–28 days	180	13.6 ^b	32	58
Pd ^a	Ca²⁺	5 min–2 months	25–59	3–10	40–108	59
Au	NH₄F, NaCl, MgCl₂, KCl, NH₄NO₃, NH₄SCN, etc.	4–12 h	83.0–212.8	6.9–113.7	2.5–29.7	42
Ag	NH₄F	4–12 h	64.8	21.9	5.2	42
Pt	NH₄F	4–12 h	61.4	42	3.4	42
Pd	NH₄F	4–12 h	44.0–62.2	3.7	122.7	42
Au-M (M = Ag, Pd, Pt)	NH₄F	12 h		3.1–5.8	34.8–68.8	42
Pd-Pt	NH₄F	12 h		4.0	58.0	42
Au-Pd-Pt	NH₄F	12 h		3.8	95.8	42
Au	dopamine	6–72 h	40–43	5–6	50.1	48
Pd_xPt_y-Ni ^a	NaBH₄ (348 K)	＜6 h	35–50	4–8	67.7–95.4	68
Pd-Pt	NaBH₄	3–17 days	50–100	4–5	73–168	52
Au ^a	NaBH₄, DMAB, NaH₂PO₂	a few minutes	540	18–280	3.1	70
Pd ^a	NaBH₄, DMAB, NaH₂PO₂	a few minutes	65	12–65	15.4	70
Pt ^a	NaBH₄, DMAB, NaH₂PO₂	A few minutes	55	13–60	20.6	70
Pd ^a	CO (313 K)	5 h	11	50–100 ^c	–	73
Au	excessive NaBH₄	2–12 h	60.5–576.5	4.8–38.3	3.5–59.8	54
Ag, Pt, Os	excessive NaBH₄	4–6 h	157.2–250.6	48.2–226.7	2.1–13.2	54
Ru, Rh	excessive NaBH₄	4–6 h	–	3.9–2.5	1.2–3.8	54
Pd	excessive NaBH₄	4–6 h	51.8	5.6	69.1	54
Au-M (M = Ag, Pd, Pt, Ir)	excessive NaBH₄	4–6 h	46.7–169.8	4.3–7.6	42.6–72.9	54
Ni_xBi_y	excessive NaBH₄	8 h	–	30–36	12–44	34
Fe-Co-Ni	excessive NaBH₄	6 h	36	52.8	30.7	76
Pt ^a	N₂H₄ (hexane)	1–5 h	190–200	3–8	30–40	57
Cu NWs	N₂H₄ (323–358 K)	15 h	3.8–7.5	70–90	–	24
Ir_xCu	NaBH₄ (343 K)	2–3 h	–	3–7	41.7	77
Cu NWs	NaBH₄ (353 K)	~1 h	4.3–7.5	~130	–	75
Cu-Fe-Ni	DMAB (313K)	12 h	–	–	42	71
Pd	Na₂CO₃ (338 K)	~1 h	–	3–8	50.1	78
Au	freeze-casting	–	6–23	~7	–	79
Au ^a	freeze-casting	–	20–60	200–500	–	80
Ag ^a	freeze-casting	–		10–50	15	80
Pd ^a	freeze-casting	–		3–7	15	80
Pt ^a	freeze-casting	–		3–10	33	80
Cu NWs	freeze-casting	–	4.6–13.5	–	–	81
Au	freeze-thaw	12–24 h	164.4	35.0	–	82
Pd	freeze-thaw	12–24 h	–	4.5	–	82
Rh	freeze-thaw	12–24 h	–	4.8	–	82
Au-Pd	freeze-thaw	12–24 h	35.9 60.6	4.3	83.6 74.5	82
Au-Pt	freeze-thaw	12–24 h	35.9 60.6	4.7	83.6 74.5	82
Au	stirring	1–10 min	–	10.4–19.8	–	83
Ag	stirring	1–10 min	–	18.1	–	83
Rh	stirring	1–10 min	–	4.1	–	83
Pd	stirring	1–10 min	–	5.8	76.6	83
Au-M (M = Ag, Pd, Pt, Rh, Ir, Pd-Pt)	stirring	1–10 min	–	3.7–7.2	32.0–83.6	83
Ni NWs	N₂H₄ (353 K, magnetic field)	1 h	20–24	200–500	1.34–4.96	84
Pt-Ag_HCl	HCl (GRR)	8 h	–	7–10 ^b	24.7	85
Pt-Ag_NH4OH	NH₄OH (GRR)	8 h	–	7–10 ^b	83.4	85

表1

图10

图11

图12

图13

图14

表2

MAs应用于醇氧化反应的相关参数"

Composition	Electrolyte solution	Types of alcohol	I_f	Reference
AuPt₅	1 mol∙L⁻¹ H₂SO₄ + 1 mol∙L⁻¹ methanol	methanol	0.51 A∙mg_Pt⁻¹	87
Pt₄Ru₁Cu₅	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	2.1 A∙mg_Pt+Ru⁻¹	123
Ni₉₇Bi₃	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	1.8 A∙mg⁻¹	34
Pt-Cu	0.5 mol∙L⁻¹ H₂SO₄ + 1 mol∙L⁻¹ methanol	methanol	4.1 A∙mg_Pt⁻¹	74
Pt₁Cu₁Ir_0.04	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	4.7 A∙mg_Pt⁻¹	124
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	3.0 A∙mg_Pd⁻¹	98
Bi-decorated Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	8.0 A∙mg_Pt⁻¹	125
Au_0.166Ag_0.288Pt_0.546	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ methanol	methanol	2.0 A∙mg_Pt⁻¹	126
Pt₃Cu₁	0.5 mol∙L⁻¹ H₂SO₄ + 1 mol∙L⁻¹ methanol	methanol	3.8 A∙mg_Pt⁻¹	127
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	8.8 A∙mg_Pd⁻¹	98
Pd_β-CD	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	7.8 A∙mg_Pd⁻¹	51
Pd₈₃Ni₁₇	1 mol∙L⁻¹ NaOH + 1 mol∙L⁻¹ ethanol	ethanol	3.6 A∙mg_Pd⁻¹	63
Pd₆₈Cu₃₂	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	3.5 A∙mg_Pd⁻¹	25
Ni-Pd₆₀Pt₄₀	1 mol∙L⁻¹ NaOH + 1 mol∙L⁻¹ ethanol	ethanol	6.9 A∙mg_Pd+Pt⁻¹	68
Pd	1 mol∙L⁻¹ NaOH + 1 mol∙L⁻¹ ethanol	ethanol	~3.2 A∙mg_Pd⁻¹	72
Pd	1 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ ethanol	ethanol	4.7 A∙mg_Pd⁻¹	78
Au-Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	2.7 A∙mg_Pd+Pt⁻¹	42
Au-Pd-Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	4.8 A∙mg_Pd+Pt⁻¹	42
Pd-Ir	1 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ ethanol	ethanol	5.4 A∙mg_Pd⁻¹	121
Au-Pd (PVP)	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	9.8 A∙mg_Pd⁻¹	53
Au	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	0.27 A∙mg⁻¹	92
Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	0.99 A∙mg⁻¹	92
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	1.5 A∙mg⁻¹	92
Au₂Cu@Pd-₂	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	22.1 A∙mg_Pd⁻¹	96
Pd_89.3Au_10.7	1 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ ethanol	ethanol	6.3 A∙mg_Pd⁻¹	122
Au-Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	3.5 A∙mg_Pt⁻¹	82
Au-Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	8.4 A∙mg_Pd⁻¹	82
Au-Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	7.3 A∙mg_Pt⁻¹	83
Au-Pd-Pt	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	9.1 A∙mg_Pd+Pt⁻¹	83
Au-Pd-Pt with light	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ ethanol	ethanol	13.2 A∙mg_Pd+Pt⁻¹	83
Pd₃Pb₁@Pd	1 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ glycol	glycol	6.4 A∙mg_Pd⁻¹	69
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ glycol	glycol	~7.8 A∙mg_Pd⁻¹	98
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ isopropanol	isopropanol	~1.7 A∙mg_Pd⁻¹	98
Pd	1 mol∙L⁻¹ KOH + 1 mol∙L⁻¹ glycerol	glycerol	~3.5 A∙mg_Pd⁻¹	98

表2

图15

图16

图17

图18

图19

参考文献 157

1	Li X. ; Lu L. ; Li J. ; Zhang X. ; Gao H. Nat. Rev. Mater. 2020, 5, 706. doi: 10.1038/s41578-020-0212-2
2	Hüsing N. ; Schubert U. Angew. Chem. Int. Ed. 1998, 37, 22. doi: 10.1002/(SICI)1521-3773(19980202)37:1/2<22::AID-ANIE22>3.0.CO;2-I
3	Guinness World Records. https://www.guinnessworldrecords.com/search?term=aerogel&page=1&type=record&max=20&partial=_Results&
4	Kistler S. S. Nature 1931, 127, 741. doi: 10.1038/127741a0
5	Teichner, S. J.; Nicolaon, G. A. Method of Preparing Inorganic Aerogels. US3672833A, 1972.
6	Tewari P. H. ; Hunt A. J. ; Lofftus K. D. Mater. Lett. 1985, 3, 363. doi: 10.1016/0167-577X(85)90077-1
7	Pekala R. W. J. Mater. Sci. 1989, 24, 3221. doi: 10.1007/BF01139044
8	Mayer S. T. ; Pekala R. W. ; Kaschmitter J. L. J. Electrochem. Soc. 1993, 140, 446. doi: 10.1149/1.2221066
9	Lu Y. ; He W. ; Cao T. ; Guo H. ; Zhang Y. ; Li Q. ; Shao Z. ; Cui Y. ; Zhang X. Sci. Rep. 2014, 4, 5792. doi: 10.1038/srep05792
10	Du R. ; Zhao Q. ; Zhang N. ; Zhang J. Small 2015, 11, 3263. doi: 10.1002/smll.201403170
11	Lohe M. R. ; Rose M. ; Kaskel S. Chem. Commun. 2009, 6056. doi: 10.1039/B910175F
12	Mohanan J. L. ; Arachchige I. U. ; Brock S. L. Science 2005, 307, 397. doi: 10.1126/science.1104226
13	Li G. Y. ; Wu X. H. ; He W. N. ; Fang J. H. ; Zhang X. T. Acta Phys. -Chim. Sin. 2016, 32, 2146.
	李广勇; 吴晓涵; 何伟娜; 方建慧; 张学同. 物理化学学报, 2016, 32, 2146. doi: 10.3866/PKU.WHXB201605243
14	Wang X. C. ; Li J. Z. ; Li G. Y. ; Wang J. ; Zhang X. T. ; Guo Q. Acta Phys. -Chim. Sin. 2017, 33, 2141.
	王叙春; 李金泽; 李广勇; 王锦; 张学同; 郭强. 物理化学学报, 2017, 33, 2141. doi: 10.3866/PKU.WHXB201705223
15	Lin Z. ; Zeng Z. ; Gui X. ; Tang Z. ; Zou M. ; Cao A. Adv. Energy Mater. 2016, 6, 1600554. doi: 10.1002/aenm.201600554
16	Rahmanian V. ; Pirzada T. ; Wang S. ; Khan S. A. Adv. Mater. 2021, 33, 2102892. doi: 10.1002/adma.202102892
17	Feng J. ; Su B.-L. ; Xia H. ; Zhao S. ; Gao C. ; Wang L. ; Ogbeide O. ; Feng J. ; Hasan T. Chem. Soc. Rev. 2021, 50, 3842. doi: 10.1039/C9CS00757A
18	Liu W. ; Herrmann A. K. ; Bigall N. C. ; Rodriguez P. ; Wen D. ; Oezaslan M. ; Schmidt T. J. ; Gaponik N. ; Eychmüller A. Acc. Chem. Res. 2015, 48, 154. doi: 10.1021/ar500237c
19	Du R. ; Fan X. ; Jin X. ; Hübner R. ; Hu Y. ; Eychmüller A. Matter 2019, 1, 39. doi: 10.1016/j.matt.2019.05.006
20	Qin G. W. ; Liu J. ; Balaji T. ; Xu X. ; Matsunaga H. ; Hakuta Y. ; Zuo L. ; Raveendran P. J. Phys. Chem. C 2008, 112, 10352. doi: 10.1021/jp800923h
21	Bigall N. C. ; Herrmann A. K. ; Vogel M. ; Rose M. ; Simon P. ; Carrillo-Cabrera W. ; Dorfs D. ; Kaskel S. ; Gaponik N. ; Eychmuller A. Angew. Chem. Int. Ed. 2009, 48, 9731. doi: 10.1002/anie.200902543
22	Leventis N. ; Chandrasekaran N. ; Sotiriou-Leventis C. ; Mumtaz A. J. Mater. Chem. 2009, 19, 63. doi: 10.1039/B815985H
23	Jung S. M. ; Jung H. Y. ; Dresselhaus M. S. ; Jung Y. J. ; Kong J. Sci. Rep. 2012, 2, 849. doi: 10.1038/srep00849
24	Jung S. M. ; Preston D. J. ; Jung H. Y. ; Deng Z. ; Wang E. N. ; Kong J. Adv. Mater. 2016, 28, 1413. doi: 10.1002/adma.201504774
25	Zhu C. ; Shi Q. ; Fu S. ; Song J. ; Xia H. ; Du D. ; Lin Y. Adv. Mater. 2016, 28, 8779. doi: 10.1002/adma.201602546
26	Pan Z. ; Wang Z.-Y. ; Wang M.-H. ; Yang L. ; Yu S.-H. Sci. China Mater. 2021, 64, 2868. doi: 10.1007/s40843-021-1677-3
27	Gao H.-L. ; Xu L. ; Long F. ; Pan Z. ; Du Y.-X. ; Lu Y. ; Ge J. ; Yu S.-H. Angew. Chem. Int. Ed. 2014, 53, 4561. doi: 10.1002/anie.201400457
28	Fang Q. ; Qin Y. ; Wang H. ; Xu W. ; Yan H. ; Jiao L. ; Wei X. ; Li J. ; Luo X. ; Liu M. ; Hu L. ; Gu W. ; Zhu C. Anal. Chem. 2022, 94, 11030. doi: 10.1021/acs.analchem.2c01836
29	Jiao L. ; Xu W. ; Yan H. ; Wu Y. ; Gu W. ; Li H. ; Du D. ; Lin Y. ; Zhu C. Chem. Commun. 2019, 55, 9865. doi: 10.1039/c9cc04436a
30	Duan W. ; Zhang P. ; Xiahou Y. ; Song Y. ; Bi C. ; Zhan J. ; Du W. ; Huang L. ; Möhwald H. ; Xia H. ACS Appl. Mater. Interfaces 2018, 10, 23081. doi: 10.1021/acsami.8b04823
31	Wang C. ; Duan W. ; Xing L. ; Xiahou Y. ; Du W. ; Xia H. J. Mater. Chem. B 2019, 7, 7588. doi: 10.1039/c9tb01653h
32	Xu J. ; Sun F. ; Li Q. ; Yuan H. ; Ma F. ; Wen D. ; Shang L. Small 2022, 18, 2200525. doi: 10.1002/smll.202200525
33	Gao W. ; Lei M. ; Li L. ; Wen D. Chem. Commun. 2020, 56, 15446. doi: 10.1039/D0CC06337A
34	Dubale A. A. ; Zheng Y. ; Wang H. ; Hubner R. ; Li Y. ; Yang J. ; Zhang J. ; Sethi N. K. ; He L. ; Zheng Z. ; et al Angew. Chem. Int. Ed. 2020, 59, 13891. doi: 10.1002/anie.202004314
35	Zheng Y. ; Yang J. ; Lu X. ; Wang H. ; Dubale A. A. ; Li Y. ; Jin Z. ; Lou D. ; Sethi N. K. ; Ye Y. ; et al Adv. Energy Mater. 2021, 11, 2002276. doi: 10.1002/aenm.202002276
36	Du R. ; Jin W. ; Wu H. ; Hübner R. ; Zhou L. ; Xue G. ; Hu Y. ; Eychmüller A. J. Mater. Chem. A 2021, 9, 17189. doi: 10.1039/d1ta03103a
37	Jiang X. ; Du R. ; Hübner R. ; Hu Y. ; Eychmüller A. Matter 2021, 4, 54. doi: 10.1016/j.matt.2020.10.001
38	Wen D. ; Eychmüller A. Chem. Commun. 2017, 53, 12608. doi: 10.1039/C7CC03862C
39	Hench L. L. ; West J. K. Chem. Rev. 1990, 90, 33. doi: 10.1021/cr00099a003
40	dos Santos D. I. ; Aegerter M. A. ; Craievich A. F. ; Lours T. ; Zarzycki J. J. Non-Cryst. Solids 1987, 95–96, 1143. doi: 10.1016/S0022-3093(87)80727-5
41	Zhang H. ; Wang D. Angew. Chem. Int. Ed. 2008, 47, 3984. doi: 10.1002/anie.200705537
42	Du R. ; Hu Y. ; Hübner R. ; Joswig J.-O. ; Fan X. ; Schneider K. ; Eychmüller A. Sci. Adv. 2019, 5, eaaw4590. doi: 10.1126/sciadv.aaw4590
43	Sun H. ; Xu Z. ; Gao C. Adv. Mater. 2013, 25, 2554. doi: 10.1002/adma.201204576
44	Schneider K. ; Melnyk I. ; Hiekel K. ; Fery A. ; Auernhammer G. K. ; Eychmüller A. J. Phys. Chem. C 2019, 123, 27651. doi: 10.1021/acs.jpcc.9b08607
45	Gao X. ; Esteves R. J. ; Luong T. T. ; Jaini R. ; Arachchige I. U. J. Am. Chem. Soc. 2014, 136, 7993. doi: 10.1021/ja5020037
46	Gao X. ; Esteves R. J. ; Nahar L. ; Nowaczyk J. ; Arachchige I. U. ACS Appl. Mater. Interfaces 2016, 8, 13076. doi: 10.1021/acsami.5b11582
47	Nahar L. ; Farghaly A. A. ; Esteves R. J. A. ; Arachchige I. U. Chem. Mater. 2017, 29, 7704. doi: 10.1021/acs.chemmater.7b01731
48	Wen D. ; Liu W. ; Haubold D. ; Zhu C. ; Oschatz M. ; Holzschuh M. ; Wolf A. ; Simon F. ; Kaskel S. ; Eychmuller A. ACS Nano 2016, 10, 2559. doi: 10.1021/acsnano.5b07505
49	Benkovičová M. ; Wen D. ; Plutnar J. ; Čížková M. ; Eychmüller A. ; Michl J. J. Phys. Chem. Lett. 2017, 8, 2339. doi: 10.1021/acs.jpclett.7b00296
50	Wu Y. ; Jiao L. ; Xu W. ; Gu W. ; Zhu C. ; Du D. ; Lin Y. Small 2019, 15, e1900632. doi: 10.1002/smll.201900632
51	Liu W. ; Herrmann A. K. ; Geiger D. ; Borchardt L. ; Simon F. ; Kaskel S. ; Gaponik N. ; Eychmuller A. Angew. Chem. Int. Ed. 2012, 51, 5743. doi: 10.1002/anie.201108575
52	Liu W. ; Rodriguez P. ; Borchardt L. ; Foelske A. ; Yuan J. ; Herrmann A. K. ; Geiger D. ; Zheng Z. ; Kaskel S. ; Gaponik N. ; et al Angew. Chem. Int. Ed. 2013, 52, 9849. doi: 10.1002/anie.201303109
53	Fan X. ; Zerebecki S. ; Du R. ; Hubner R. ; Marzum G. ; Jiang G. ; Hu Y. ; Barcikowki S. ; Reichenberger S. ; Eychmuller A. Angew. Chem. Int. Ed. 2020, 59, 5706. doi: 10.1002/anie.201913079
54	Du R. ; Wang J. ; Wang Y. ; Hubner R. ; Fan X. ; Senkovska I. ; Hu Y. ; Kaskel S. ; Eychmuller A. Nat. Commun. 2020, 11, 1590. doi: 10.1038/s41467-020-15391-w
55	Lin Z. ; Liu S. ; Liu Y. ; Liu Z. ; Zhang S. ; Zhang X. ; Tian Y. ; Tang Z. J. Power Sources 2021, 514, 230600. doi: 10.1016/j.jpowsour.2021.230600
56	Yan S. ; Mahyoub S. A. ; Lin J. ; Zhang C. ; Hu Q. ; Chen C. ; Zhang F. ; Cheng Z. Nanotechnology 2022, 33, 125705. doi: 10.1088/1361-6528/ac4287
57	Naskar S. ; Freytag A. ; Deutsch J. ; Wendt N. ; Behrens P. ; Köckritz A. ; Bigall N. C. Chem. Mater. 2017, 29, 9208. doi: 10.1021/acs.chemmater.7b03088
58	Ranmohotti K. G. S. ; Gao X. ; Arachchige I. U. Chem. Mater. 2013, 25, 3528. doi: 10.1021/cm401968j
59	Wen D. ; Herrmann A. K. ; Borchardt L. ; Simon F. ; Liu W. ; Kaskel S. ; Eychmuller A. J. Am. Chem. Soc. 2014, 136, 2727. doi: 10.1021/ja412062e
60	Wu Z. ; Wu H. ; Cai W. ; Wen Z. ; Jia B. ; Wang L. ; Jin W. ; Ma T. Angew. Chem. Int. Ed. 2021, 60, 12554. doi: 10.1002/anie.202102832
61	Du R. ; Jin W. ; Hübner R. ; Zhou L. ; Hu Y. ; Eychmüller A. Adv. Energy Mater. 2020, 10, 1903857. doi: 10.1002/aenm.201903857
62	López-León T. ; Santander-Ortega M. J. ; Ortega-Vinuesa J. L. ; Bastos-González D. J. Phys. Chem. C 2008, 112, 16060. doi: 10.1021/jp803796a
63	Cai B. ; Wen D. ; Liu W. ; Herrmann A. K. ; Benad A. ; Eychmuller A. Angew. Chem. Int. Ed. 2015, 54, 13101. doi: 10.1002/anie.201505307
64	Zheng Y. ; Li N. ; Mukherjee S. ; Yang Y. ; Yan J. ; Liu J. ; Fang Y. ACS Appl. Nano Mater. 2019, 2, 3012. doi: 10.1021/acsanm.9b00401
65	Fan X. ; Cai B. ; Du R. ; Hübner R. ; Georgi M. ; Jiang G. ; Li L. ; Samadi Khoshkhoo M. ; Sun H. ; Eychmüller A. Chem. Mater. 2019, 31, 10094. doi: 10.1021/acs.chemmater.9b03121
66	Heuer-Jungemann A. ; Feliu N. ; Bakaimi I. ; Hamaly M. ; Alkilany A. ; Chakraborty I. ; Masood A. ; Casula M. F. ; Kostopoulou A. ; Oh E. ; et al Chem. Rev. 2019, 119, 4819. doi: 10.1021/acs.chemrev.8b00733
67	Tang S. ; Vongehr S. ; Wang Y. ; Juan C. S. ; Xiangyu W. ; Meng X. J. Mater. Chem. A 2014, 2, 3648. doi: 10.1039/c3ta14541g
68	Cai B. ; Dianat A. ; Hubner R. ; Liu W. ; Wen D. ; Benad A. ; Sonntag L. ; Gemming T. ; Cuniberti G. ; Eychmuller A. Adv. Mater. 2017, 29, 1605254. doi: 10.1002/adma.201605254
69	Zhu C. ; Shi Q. ; Fu S. ; Song J. ; Du D. ; Su D. ; Engelhard M. H. ; Lin Y. J. Mater. Chem. A 2018, 6, 7517. doi: 10.1039/c7ta11233e
70	Burpo F. J. ; Nagelli E. A. ; Morris L. A. ; McClure J. P. ; Ryu M. Y. ; Palmer J. L. J. Mater. Res. 2017, 32, 4153. doi: 10.1557/jmr.2017.412
71	Jiang B. ; Wan Z. ; Kang Y. ; Guo Y. ; Henzie J. ; Na J. ; Li H. ; Wang S. ; Bando Y. ; Sakka Y. ; Yamauchi Y. Nano Energy 2021, 81, 105644. doi: 10.1016/j.nanoen.2020.105644
72	Yazdan-Abad M. Z. ; Noroozifar M. ; Modaresi Alam A. R. ; Saravani H. J. Mater. Chem. A 2017, 5, 10244. doi: 10.1039/c7ta03208k
73	Yazdan-Abad M. Z. ; Noroozifar M. ; Douk A. S. ; Modarresi-Alam A. R. ; Saravani H. Appl. Catal. B-Environ. 2019, 250, 242. doi: 10.1016/j.apcatb.2019.02.064
74	Song T. ; Xue H. ; Sun J. ; Guo N. ; Sun J. ; Wang Q. Chem. Commun. 2021, 57, 7140. doi: 10.1039/d1cc02038b
75	Xu X. ; Wang R. ; Nie P. ; Cheng Y. ; Lu X. ; Shi L. ; Sun J. ACS Appl. Mater. Interfaces 2017, 9, 14273. doi: 10.1021/acsami.7b02087
76	Yan S. ; Zhong M. ; Wang C. ; Lu X. Chem. Eng. J. 2022, 430, 132955. doi: 10.1016/j.cej.2021.132955
77	Shi Q. ; Zhu C. ; Zhong H. ; Su D. ; Li N. ; Engelhard M. H. ; Xia H. ; Zhang Q. ; Feng S. ; Beckman S. P. ; et al ACS Energy Lett. 2018, 3, 2038. doi: 10.1021/acsenergylett.8b01338
78	Shafaei Douk A. ; Saravani H. ; Noroozifar M. Electrochim. Acta 2018, 275, 182. doi: 10.1016/j.electacta.2018.04.073
79	Qian F. ; Troksa A. ; Fears T. M. ; Nielsen M. H. ; Nelson A. J. ; Baumann T. F. ; Kucheyev S. O. ; Han T. Y. ; Bagge-Hansen M. Nano Lett. 2020, 20, 131. doi: 10.1021/acs.nanolett.9b03445
80	Freytag A. ; Sánchez-Paradinas S. ; Naskar S. ; Wendt N. ; Colombo M. ; Pugliese G. ; Poppe J. ; Demirci C. ; Kretschmer I. ; Bahnemann D. W. ; et al Angew. Chem. Int. Ed. 2016, 55, 1200. doi: 10.1002/anie.201508972
81	Tang Y. ; Yeo K. L. ; Chen Y. ; Yap L. W. ; Xiong W. ; Cheng W. J. Mater. Chem. A 2013, 1, 6723. doi: 10.1039/C3TA10969K
82	Du R. ; Joswig J. O. ; Hubner R. ; Zhou L. ; Wei W. ; Hu Y. ; Eychmuller A. Angew. Chem. Int. Ed. 2020, 59, 8293. doi: 10.1002/anie.201916484
83	Du R. ; Joswig J. O. ; Fan X. ; Hubner R. ; Spittel D. ; Hu Y. ; Eychmuller A. Matter 2020, 2, 908. doi: 10.1016/j.matt.2020.01.002
84	Pan W. ; Liang C. ; Sui Y. ; Wang J. ; Liu P. ; Zou P. ; Guo Z. ; Wang F. ; Ren X. ; Yang C. Adv. Funct. Mater. 2022, 32, 2204166. doi: 10.1002/adfm.202204166
85	Liu W. ; Haubold D. ; Rutkowski B. ; Oschatz M. ; Hübner R. ; Werheid M. ; Ziegler C. ; Sonntag L. ; Liu S. ; Zheng Z. ; et al Chem. Mater. 2016, 28, 6477. doi: 10.1021/acs.chemmater.6b01394
86	Herrmann A.-K. ; Formanek P. ; Borchardt L. ; Klose M. ; Giebeler L. ; Eckert J. ; Kaskel S. ; Gaponik N. ; Eychmüller A. Chem. Mater. 2014, 26, 1074. doi: 10.1021/cm4033258
87	Shi Q. ; Zhu C. ; Du D. ; Bi C. ; Xia H. ; Feng S. ; Engelhard M. H. ; Lin Y. J. Mater. Chem. A 2017, 5, 19626. doi: 10.1039/c7ta06375j
88	Gilbert D. A. ; Burks E. C. ; Ushakov S. V. ; Abellan P. ; Arslan I. ; Felter T. E. ; Navrotsky A. ; Liu K. Chem. Mater. 2017, 29, 9814. doi: 10.1021/acs.chemmater.7b03978
89	Qian F. ; Lan P. C. ; Freyman M. C. ; Chen W. ; Kou T. ; Olson T. Y. ; Zhu C. ; Worsley M. A. ; Duoss E. B. ; Spadaccini C. M. ; Baumann T. ; Han T. Y. Nano Lett. 2017, 17, 7171. doi: 10.1021/acs.nanolett.7b02790
90	Fears T. M. ; Hammons J. A. ; Sain J. D. ; Nielsen M. H. ; Braun T. ; Kucheyev S. O. APL Mater. 2018, 6, 091103. doi: 10.1063/1.5039521
91	Müller D. ; Klepzig L. F. ; Schlosser A. ; Dorfs D. ; Bigall N. C. Langmuir 2021, 37, 5109. doi: 10.1021/acs.langmuir.0c03619
92	Müller D. ; Zámbó D. ; Dorfs D. ; Bigall N. C. Small 2021, 17, 2007908. doi: 10.1002/smll.202007908
93	Liang C. ; Pan W. ; Zou P. ; Liu P. ; Liu K. ; Zhao G. ; Fan H. J. ; Yang C. Small 2022, 18, e2203663. doi: 10.1002/smll.202203663
94	Zhao H. ; Yuan Y. ; Zhang D. ; Qin Y. ; Han Y. ; Li H. ; Wang Z. ; Li S.-X. ; Lai J. ; Wang L. ACS Appl. Nano Mater. 2021, 4, 11221. doi: 10.1021/acsanm.1c02746
95	Cai B. ; Hübner R. ; Sasaki K. ; Zhang Y. ; Su D. ; Ziegler C. ; Vukmirovic M. B. ; Rellinghaus B. ; Adzic R. R. ; Eychmüller A. Angew. Chem. Int. Ed. 2018, 57, 2963. doi: 10.1002/anie.201710997
96	Shi Q. ; Zhu C. ; Tian M. ; Su D. ; Fu M. ; Engelhard M. H. ; Chowdhury I. ; Feng S. ; Du D. ; Lin Y. Nano Energy 2018, 53, 206. doi: 10.1016/j.nanoen.2018.08.047
97	Wang J. ; Chen F. ; Jin Y. ; Guo L. ; Gong X. ; Wang X. ; Johnston R. L. Nanoscale 2019, 11, 14174. doi: 10.1039/c9nr03266e
98	Wang C. ; Gao W. ; Wan X. ; Yao B. ; Mu W. ; Gao J. ; Fu Q. ; Wen D. Chem. Sci. 2022, 13, 13956. doi: 10.1039/D2SC05425F
99	Sosnick, B. Process for Making Foamlike Mass of Metal. US2434775A, 1948.
100	Forty A. J. Nature 1979, 282, 597. doi: 10.1038/282597a0
101	Takale B. S. ; Feng X. ; Lu Y.-M. ; Bao M. ; Jin T. ; Minato T. ; Yamamoto Y. J. Am. Chem. Soc. 2016, 138, 10356. doi: 10.1021/jacs.6b06569
102	Cattarin S. ; Kramer D. ; Lui A. ; Musiani M. M. J. Phys. Chem. C 2007, 111, 12643. doi: 10.1021/jp072405c
103	Xu C. ; Su J. ; Xu X. ; Liu P. ; Zhao H. ; Tian F. ; Ding Y. J. Am. Chem. Soc. 2007, 129, 42. doi: 10.1021/ja0675503
104	Wang C. ; Chen Q. Chem. Mater. 2018, 30, 3894. doi: 10.1021/acs.chemmater.8b01431
105	Ron R. ; Gachet D. ; Rechav K. ; Salomon A. Adv. Mater. 2017, 29, 1604018. doi: 10.1002/adma.201604018
106	Khan F. ; Eswaramoorthy M. ; Rao C. N. R. Solid State Sci. 2007, 9, 27. doi: 10.1016/j.solidstatesciences.2006.11.002
107	Nyce G. W. ; Hayes J. R. ; Hamza A. V. ; Satcher J. H. Chem. Mater. 2007, 19, 344. doi: 10.1021/CM062569Q
108	Walsh D. ; Arcelli L. ; Ikoma T. ; Tanaka J. ; Mann S. Nat. Mater. 2003, 2, 386. doi: 10.1038/nmat903
109	Jiang B. ; Yang X. ; Niu W. ; He C. ; Shi C. ; Zhao N. Scr. Mater. 2016, 117, 68. doi: 10.1016/j.scriptamat.2016.02.024
110	Leventis N. ; Chandrasekaran N. ; Sadekar A. G. ; Mulik S. ; Sotiriou-Leventis C. J. Mater. Chem. 2010, 20, 7456. doi: 10.1039/C0JM00856G
111	Leventis N. ; Donthula S. ; Mandal C. ; Ding M. S. ; Sotiriou-Leventis C. Chem. Mater. 2015, 27, 8126. doi: 10.1021/acs.chemmater.5b03898
112	Chen K. ; Bao Z. ; Shen J. ; Wu G. ; Zhou B. ; Sandhage K. H. J. Mater. Chem. 2012, 22, 16196. doi: 10.1039/C2JM31662E
113	Chen K. ; Xu W. ; Du A. ; Shen J. ; Wu G. ; Bao Z. ; Zhou B. Mater. Lett. 2014, 116, 31. doi: 10.1016/j.matlet.2013.10.079
114	Xu W. ; Du A. ; Xiong J. ; Zhang Z. ; Shen J. ; Zhou B. Mater. Des. 2016, 97, 93. doi: 10.1016/j.matdes.2016.02.070
115	Tappan B. C. ; Steiner Iii S. A. ; Luther E. P. Angew. Chem. Int. Ed. 2010, 49, 4544. doi: 10.1002/anie.200902994
116	Yan P. ; Brown E. ; Su Q. ; Li J. ; Wang J. ; Xu C. ; Zhou C. ; Lin D. Small 2017, 13, 1701756. doi: 10.1002/smll.201701756
117	Zhu C. ; Qi Z. ; Beck V. A. ; Luneau M. ; Lattimer J. ; Chen W. ; Worsley M. A. ; Ye J. ; Duoss E. B. ; Spadaccini C. M. ; et al Sci. Adv. 2018, 4, eaas9459. doi: 10.1126/sciadv.aas9459
118	Tappan B. C. ; Huynh M. H. ; Hiskey M. A. ; Chavez D. E. ; Luther E. P. ; Mang J. T. ; Son S. F. J. Am. Chem. Soc. 2006, 128, 6589. doi: 10.1021/ja056550k
119	Gao D. ; Yang G. ; Zhu Z. ; Zhang J. ; Yang Z. ; Zhang Z. ; Xue D. J. Mater. Chem. 2012, 22, 9462. doi: 10.1039/C2JM30548H
120	Tappan B. C. ; Steiner Iii S. A. ; Dervishi E. ; Mueller A. H. ; Scott B. L. ; Sheehan C. ; Luther E. P. ; Lichthardt J. P. ; Dirmyer M. R. ACS Appl. Mater. Interfaces 2021, 13, 1204. doi: 10.1021/acsami.0c17624
121	Shafaei Douk A. ; Saravani H. ACS Omega 2020, 5, 22031. doi: 10.1021/acsomega.0c01661
122	Shafaei Douk A. ; Saravani H. ; Yazdan Abad M. Z. ; Noroozifar M. ACS Appl. Energy Mater. 2020, 3, 7527. doi: 10.1021/acsaem.0c00928
123	Wang H. ; Wu Y. ; Luo X. ; Jiao L. ; Wei X. ; Gu W. ; Du D. ; Lin Y. ; Zhu C. Nanoscale 2019, 11, 10575. doi: 10.1039/c9nr02712b
124	Fang Q. ; Wang H. ; Lv X. ; Wei X. ; Luo X. ; Huang J. ; Jiao L. ; Gu W. ; Song W. ; Zhu C. ACS Sustain. Chem. Eng. 2021, 9, 13039. doi: 10.1021/acssuschemeng.1c04765
125	Zhu L. ; Zhang R. ; Liu X. ; Zhu J. ; Guo Z. ; Zhao Y. Appl. Surf. Sci. 2022, 592, 153219. doi: 10.1016/j.apsusc.2022.153219
126	Sarkar R. ; Farghaly A. A. ; Arachchige I. U. Chem. Mater. 2022, 34, 5874. doi: 10.1021/acs.chemmater.2c00717
127	Tie X. ; Sun X. ; Li Q. ; Min Y. ; Xu Q. J. Electrochem. Soc. 2022, 169, 026517. doi: 10.1149/1945-7111/ac519c
128	Yang N. ; Chen D. ; Cui P. ; Lu T. ; Liu H. ; Hu C. ; Xu L. ; Yang J. SmartMat 2021, 2, 234. doi: 10.1002/smm2.1032
129	Jin Y. ; Chen F. ; Wang J. ; Guo L. ; Jin T. ; Liu H. J. Power Sources 2019, 435, 226798. doi: 10.1016/j.jpowsour.2019.226798
130	Douk A. S. ; Farsadrooh M. ; Damanigol F. ; Moghaddam A. A. ; Saravani H. ; Noroozifar M. RSC Adv. 2018, 8, 23539. doi: 10.1039/c8ra03718c
131	Douk A. S. ; Saravani H. ; Yazdan Abad M. Z. ; Noroozifar M. Compos. Part B-Eng. 2019, 172, 309. doi: 10.1016/j.compositesb.2019.05.021
132	Zhang R. ; Zhu L. ; Liu X. ; Zhu J. ; Zhao Y. ACS Sustain. Chem. Eng. 2021, 9, 7837. doi: 10.1021/acssuschemeng.1c01498
133	Wen D. ; Liu W. ; Herrmann A. K. ; Eychmuller A. Chemistry 2014, 20, 4380. doi: 10.1002/chem.201304635
134	Wang J. ; Chen F. ; Jin Y. ; Johnston R. L. ChemSusChem 2018, 11, 1354. doi: 10.1002/cssc.201800052
135	Wang Y.-J. ; Long W. ; Wang L. ; Yuan R. ; Ignaszak A. ; Fang B. ; Wilkinson D. P. J. E. ; Science E. Energy Environ. Sci. 2018, 11, 258. doi: 10.1039/C7EE02444D
136	Wang Y. ; Wang D. ; Li Y. SmartMat 2021, 2, 56. doi: 10.1002/smm2.1023
137	Henning S. ; Kühn L. ; Herranz J. ; Durst J. ; Binninger T. ; Nachtegaal M. ; Werheid M. ; Liu W. ; Adam M. ; Kaskel S. ; et al J. J. Electrochem. Soc. 2016, 163, F998. doi: 10.1149/2.0251609jes
138	Henning S. ; Ishikawa H. ; Kuhn L. ; Herranz J. ; Muller E. ; Eychmuller A. ; Schmidt T. J. Angew. Chem. Int. Ed. 2017, 56, 10707. doi: 10.1002/anie.201704253
139	Shi Q. ; Zhu C. ; Li Y. ; Xia H. ; Engelhard M. H. ; Fu S. ; Du D. ; Lin Y. Chem. Mater. 2016, 28, 7928. doi: 10.1021/acs.chemmater.6b03549
140	Gao W. ; Fan H. ; Li L. ; Lei M. ; Wen D. Appl. Surf. Sci. 2023, 611, 155639. doi: 10.1016/j.apsusc.2022.155639
141	Li Y. ; Peng C. K. ; Hu H. ; Chen S. Y. ; Choi J. H. ; Lin Y. G. ; Lee J. M. Nat. Commun. 2022, 13, 1143. doi: 10.1038/s41467-022-28805-8
142	Lu L. ; Sun X. ; Ma J. ; Yang D. ; Wu H. ; Zhang B. ; Zhang J. ; Han B. Angew. Chem. Int. Ed. 2018, 57, 14149. doi: 10.1002/anie.201808964
143	Zhong D. ; Zhang L. ; Zhao Q. ; Cheng D. ; Deng W. ; Liu B. ; Zhang G. ; Dong H. ; Yuan X. ; Zhao Z. ; Li J. ; Gong J. J. Chem. Phys. 2020, 152, 204703. doi: 10.1063/5.0007207
144	Wang W. ; Gong S. ; Liu J. ; Ge Y. ; Wang J. ; Lv X. J. Colloid Interface Sci. 2021, 595, 159. doi: 10.1016/j.jcis.2021.03.120
145	Chauhan P. ; Hiekel K. ; Diercks J. S. ; Herranz J. ; Saveleva V. A. ; Khavlyuk P. ; Eychmuller A. ; Schmidt T. J. ACS Mater. Au 2022, 2, 278. doi: 10.1021/acsmaterialsau.1c00067
146	Xu Y. ; Ren K. ; Ren T. ; Wang M. ; Liu M. ; Wang Z. ; Li X. ; Wang L. ; Wang H. Chem. Commun. 2021, 57, 7525. doi: 10.1039/d1cc02105b
147	Wang N. ; Miao R. K. ; Lee G. ; Vomiero A. ; Sinton D. ; Ip A. H. ; Liang H. ; Sargent E. H. SmartMat 2021, 2, 12. doi: 10.1002/smm2.1018
148	Zeng Y. ; Li Y. ; Tan X. ; Gong J. ; Wang Z. ; An Y. ; Wang Z. ; Li H. ACS Appl. Mater. Interfaces 2021, 13, 36816. doi: 10.1021/acsami.1c07987
149	Tan X. ; Yang Q. ; Sun X. ; Sun P. ; Li H. ACS Appl. Mater. Interfaces 2022, 14, 10047. doi: 10.1021/acsami.1c22625
150	Yang Y. ; Zhang H. ; Wang J. ; Yang S. ; Liu T. ; Tao K. ; Chang H. J. Mater. Chem. A 2019, 7, 11497. doi: 10.1039/c9ta01963d
151	Guan S. ; Xu B. ; Yang Y. ; Zhu X. ; Chen R. ; Ye D. ; Liao Q. ACS Appl. Nano Mater. 2022, 5, 11091. doi: 10.1021/acsanm.2c02272
152	Li G. ; Hao J. ; Li W. ; Ma F. ; Ma T. ; Gao W. ; Yu Y. ; Wen D. Anal. Chem. 2021, 93, 14068. doi: 10.1021/acs.analchem.1c01581
153	Gao W. ; Wen D. VIEW. 2021, 2, 20200124. doi: 10.1002/VIW.20200124
154	Xiao Y. ; Wang C. ; Liu K. ; Wei L. ; Luo Z. ; Zeng M. ; Yi Y. J. Solgel Sci. Technol. 2021, 99, 614. doi: 10.1007/s10971-021-05597-9
155	Zhou L. ; Peng Y. ; Zhang N. ; Du R. ; Hübner R. ; Wen X. ; Li D. ; Hu Y. ; Eychmüller A. Adv. Optical. Mater. 2021, 9, 2100352. doi: 10.1002/adom.202100352
156	Phattharasupakun N. ; Wutthiprom J. ; Duangdangchote S. ; Sawangphruk M. Chem. Commun. 2019, 55, 5689. doi: 10.1039/C9CC01528K
157	Zhang L. ; An L. ; Wang Y. ; Lee A. ; Schuman Y. ; Ural A. ; Fleischer A. S. ; Feng G. Chem. Eng. J. 2019, 373, 857. doi: 10.1016/j.cej.2019.05.10

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