二氧化锰@氮掺杂碳@镍铁氧体杂化材料的一锅法绿色合成及吸波性能研究

doi:10.1016/j.actphy.2026.100302

物理化学学报 >> 2026, Vol. 42 >> Issue (8): 100302.doi: 10.1016/j.actphy.2026.100302

二氧化锰@氮掺杂碳@镍铁氧体杂化材料的一锅法绿色合成及吸波性能研究

戴鑫鑫¹, 兰笛², 陈星亮¹^,⁴^,*(), 王行伟³^,*(), 姬广斌⁴^,*()

¹ 绍兴大学, 浙江省清洁染整技术研究重点实验室, 绍兴市高性能纤维制品重点实验室, 浙江绍兴 312000
² 湖北汽车工业学院材料科学与工程学院, 湖北十堰 442002
³ 中国科学院兰州化学物理研究所润滑材料国家重点实验室, 甘肃兰州 730000
⁴ 南京航空航天大学材料科学与技术学院, 江苏南京 210016

收稿日期:2026-02-14 修回日期:2026-04-06 录用日期:2026-04-08 发布日期:2026-06-11
通讯作者: Email: chenxlmoon@163.com (陈星亮)wangxingwei@licp.cas.cn (王行伟)gbji@nuaa.edu.cn (姬广斌)

One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids

Xinxin Dai¹, Di Lan², Xingliang Chen¹^,⁴^,*(), Xingwei Wang³^,*(), Guangbin Ji⁴^,*()

¹ Shaoxing Key Laboratory of High Performance Fibers & Products, Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing University, Shaoxing 312000, Zhejiang Province, China
² School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China
³ State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu Province, China
⁴ College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, Jiangsu Province, China

Received:2026-02-14 Revised:2026-04-06 Accepted:2026-04-08 Published:2026-06-11
Contact: Email: chenxlmoon@163.com (Xingliang Chen)wangxingwei@licp.cas.cn (Xingwei Wang)gbji@nuaa.edu.cn (Guangbin Ji)

摘要/Abstract

摘要：

技术革新与工业化的加速推进使电磁辐射的防护及重金属污染的治理成为当前的研究热点。本研究采用原创的一锅法绿色合成工艺，制备出了二氧化锰@氮掺杂碳@镍铁氧体复合杂化材料。通过系统性的表征，深入分析了合成产物的微观结构形貌、晶相组成、化学元素分布、电磁参数及吸波性能。反射损耗曲线结果表明：通过调控吡咯单体用量制备的优化样品表现出了理想的电磁波吸收性能，在3.2 mm匹配厚度下的最低反射损耗值可达到−48 dB，这主要可以归因于界面极化引发的共振效应、良好的阻抗匹配及其他协同因素。该一锅法合成策略所体现的绿色理念，对推动绿色合成技术的发展具有积极意义。

关键词: 氮掺杂碳, 绿色合成, 铁氧体, 二氧化锰, 电磁波吸收性能

Abstract:

The accelerating pace of technological advancement and industrialization has propelled electromagnetic radiation protection and heavy metal treatment to the forefront of current research. In this work, we adopted an original one pot green synthesis method, fabricated a set of novel manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids. The microstructures and morphologies, crystal forms, chemical compositions, electromagnetic parameters and electromagnetic wave absorption performances of as-synthesized hybrids were investigated in detail. Result of reflection loss curves indicated that the optimized sample obtained by adjusting the dosage of pyrrole monomer exhibited ideal electromagnetic wave absorption efficiency, with a minimum reflection loss value of −48 dB at the sample thickness of 3.2 mm, which can mainly be attributed to the resonance effect caused by interface polarization, reasonable impedance matching and some other factors. The synthesis concept involved in this one pot method is also beneficial for promoting the development of green synthesis.

Key words: Nitrogen doped carbon, Green synthesis, Ferrite, Manganese dioxide, EW absorption performance

戴鑫鑫, 兰笛, 陈星亮, 王行伟, 姬广斌. 二氧化锰@氮掺杂碳@镍铁氧体杂化材料的一锅法绿色合成及吸波性能研究[J]. 物理化学学报, 2026, 42(8), 100302. doi: 10.1016/j.actphy.2026.100302

Xinxin Dai, Di Lan, Xingliang Chen, Xingwei Wang, Guangbin Ji. One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids[J]. Acta Phys. -Chim. Sin. 2026, 42(8), 100302. doi: 10.1016/j.actphy.2026.100302

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2026.100302

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I8/100302

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二氧化锰@氮掺杂碳@镍铁氧体杂化材料的一锅法绿色合成及吸波性能研究

One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids

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二氧化锰@氮掺杂碳@镍铁氧体杂化材料的一锅法绿色合成及吸波性能研究

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One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids