物理化学学报 >> 1989, Vol. 5 >> Issue (03): 293-298.doi: 10.3866/PKU.WHXB19890309

研究论文 上一篇    下一篇

以快速预解离态为共振中间态的双色双共振多光子电离光谱

姜波; 解金春; 沙国河; 谢行滨; 张存浩   

  1. 中国科学院大连化学物理研究所
  • 收稿日期:1987-09-27 修回日期:1988-05-09 发布日期:1989-06-15
  • 通讯作者:

OODR-MPI SPECTROSCOPY OF AMMONIA INVOLVING A FAST PREDISSOCIATING INTERMEDIATE STATE

Jiang Bo*; Xie Jinchun; Sha Guohe; Xie Xinbing; Zhang Cunhao   

  1. Dalian Institute of Chemical Physica; Academic Sinica
  • Received:1987-09-27 Revised:1988-05-09 Published:1989-06-15
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摘要： NH_3Ã(~1Ã″_2)是个快速预解离态,寿命约10~(-13)s。本文研究了以这个态为中间共振态的2+1+1双色双共振多光子电离过程。我们首先获得了NH_2和ND_3两分子X→Ã→C′NH_3~+(或ND_3~+)+e跃迁的多光子电离光增, 求出了ND_3C′v_2=0, 1两能级的转动常数,然后通过合理的实验设计, 得到了NH_3分子X→Ã跃迁转动线的增益线型。

Abstract:

OOD-RMPI spectroscopy Of ammonia using the fast predissoeiating à state as the intermediate has proved to be a feasible approach to uncover hidden spectroscopic information on both the upper electronic states and the intermediate predissociating species. The rotationally resolved MPI spectra of NH_3 and ND_3 X→(2hν_1)Ã→(hν_2)C′transition and correspondingly the rotational constants of ND_3 C′ ~1A_1′(v_2=0,1) haStebeen obtained. We found that only Q branch lines of NH_3 X→à 2-photon transition appeared when linearly polarised pumping light was used. At a series of different v_1 frequences, we can always get 2v_1+v_2 resonant with a fixed X→C′rovibronic transition line by tunning v_2. The intensity envelope of the ion signal thus obtained represents the rotational line profile of à state. From the width of the profile predissociation life time of à is obtained.