高性能双金属氧化物负极的理性设计及储锂特性

doi:10.3866/PKU.WHXB202311005

物理化学学报 >> 2025, Vol. 41 >> Issue (3): 100021.doi: 10.3866/PKU.WHXB202311005

所属专题：能源化学

高性能双金属氧化物负极的理性设计及储锂特性

林学宇¹, 王瑞琦²^,*(), 董武杰³, 黄富强¹^,³^,⁴^,*()

¹ 北京大学化学与分子工程学院, 北京分子科学国家研究中心, 稀土材料化学与应用国家重点实验室, 北京 100871
² 中国科学院大学化学工程学院, 北京 101408
³ 中国科学院上海硅酸盐研究所, 高性能陶瓷和超微结构国家重点实验室, 上海 200050
⁴ 上海交通大学材料科学与工程学院, 金属基复合材料国家重点实验室, 上海 200240

收稿日期:2023-11-03 修回日期:2023-12-08 录用日期:2023-12-11 发布日期:2024-01-02
通讯作者: Email: wangruiqi@ucas.ac.cn (王瑞琦)huangfq@pku.edu.cn (黄富强)
基金资助:
国家自然科学基金(22005006)

Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage

Xueyu Lin¹, Ruiqi Wang²^,*(), Wujie Dong³, Fuqiang Huang¹^,³^,⁴^,*()

¹ College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, China
² School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 101408, China
³ State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
⁴ State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Received:2023-11-03 Revised:2023-12-08 Accepted:2023-12-11 Published:2024-01-02
Contact: Email: wangruiqi@ucas.ac.cn (Ruiqi Wang)huangfq@pku.edu.cn (Fuqiang Huang)
Supported by:
the National Natural Science Foundation of China(22005006)

摘要/Abstract

摘要：

高能量密度、高功率密度的“双高”锂离子电池(LIBs)的实现依赖于创新突破高容量、高倍率及长循环寿命电极材料。插入型负极，以d⁰过渡金属氧化物为代表，含有强金属-氧键，表现出高循环稳定性和高倍率性能。然而，由于金属离子变价较少，其比容量相对较低。转化-合金型负极，以p区金属氧化物为代表，具备高理论比容量，但嵌锂过程中的相团聚和体积膨胀易导致容量快速衰减和倍率性能不佳。通过引入插入型或转化型功能基元构建双金属氧化物负极，可以优化电极中的电子/离子传导，从而改善循环性能和倍率性能，有望实现负极材料高容量、高倍率及长循环的统一。本文通过对各类金属氧化物中的化学键及电子结构特征进行分析，并提出一种新的图示表达方式，将负极锂离子插脱嵌的电化学反应储能过程表达为态密度(DOS)图示。文章阐述了双金属氧化物负极的多步储锂机制，并结合近期相关研究进展，为发展高容量、高倍率及高稳定的双金属化合物负极提供理论参考和实践依据。

关键词: 锂离子电池, 负极材料, 双金属化合物, 储锂机制

Abstract:

The rapid advancement of scientific technology leads to a growing need for energy storage equipment in modern society. Lithium-ion batteries (LIBs) are extensively utilized in portable electronics, handy electric tools, medical electronics, and other industries due to their exceptional features such as high energy density, high power density, long lifespan, low self-discharge rate, wide operating temperature range and environmentally-friendly nature. However, the recent rapid development of mobile electronics and electric vehicles requires energy storage devices with even higher energy and power densities. To achieve this goal, it is essential to develop advanced electrode materials featuring high capacity, high rate capability, and long cycle life. The design of high-performance anode materials is an important aspect of constructing the ideal LIB devices. Besides the commercialized graphite, many metal oxides can also act as anode in the LIBs. In detail, the oxides that served as LIB anodes can be classified into intercalation-type, conversion-type and conversion-alloying-type anodes based on their Li⁺ storage mechanisms. Due to their robust metal-oxygen bonds, intercalation-type anodes, such as d⁰ metal oxides, exhibit stable cycling performance and high-rate capability. However, the limited valence change of intercalation-type metal ions often results in low theoretical capacities. In comparison, conversion-alloying type anodes, exemplified by p-block metal oxides, offer high theoretical capacities and low Li⁺ extraction potential, making them suitable for high-energy-density LIBs. Nevertheless, the Li⁺ intercalation process induces severe phase agglomeration and volume expansion, leading to rapid capacity decay and poor rate capability. Therefore, these drawbacks severely limit the wild utilization s of metal oxide anodes in commercialized LIBs. Recently, substantial efforts have been made to design novel bimetallic oxide anodes. Among these anodes, the incorporation of intercalation-type or conversion-type motifs into conversion-alloying-type metal oxides enables the creation of bimetallic oxide anodes with optimized electronic and ionic conductivities. This approach has the potential to combine the advantages of high capacity, high-rate capability, and long cycle life in a single system. To uncover the underlying Li⁺ storage mechanisms, this review analyzes the bond situations and electronic structures of various metal oxides. Additionally, it introduces a new graphic representation of the Li⁺-ion charge/discharge process using density-of-states (DOS) graphs. The multi-step lithium storage mechanisms in bimetallic oxide anodes are also discussed. Drawing on recent progress in the field, this review provides fundamental academic insights and practical perspectives for the development of high-capacity, high-rate, and robust bimetallic compound anodes.

Key words: Lithium-ion battery, Anode materials, Bimetallic compound, Li⁺ storage mechanism

林学宇, 王瑞琦, 董武杰, 黄富强. 高性能双金属氧化物负极的理性设计及储锂特性[J]. 物理化学学报, 2025, 41(3), 100021. doi: 10.3866/PKU.WHXB202311005

Xueyu Lin, Ruiqi Wang, Wujie Dong, Fuqiang Huang. Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage[J]. Acta Phys. -Chim. Sin. 2025, 41(3), 100021. doi: 10.3866/PKU.WHXB202311005

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202311005

https://www.whxb.pku.edu.cn/CN/Y2025/V41/I3/100021

图/表 12

图1

表1

图2

图3

图4

图5

图6

图7

图8

图9

图10

图11

参考文献 83

1	Xie L. ; Tang C. ; Bi Z. ; Song M. ; Fan Y. ; Yan C. ; Li X. ; Su F. ; Zhang Q. ; Chen C Adv. Energy Mater. 2021, 11, 2101650. doi: 10.1002/aenm.202101650
2	Ding X. ; Huang Q. ; Xiong X Acta Phys. -Chim. Sin. 2022, 38, 2204057. doi: 10.3866/PKU.WHXB202204057
	丁晓博; 黄倩晖; 熊训辉; 等. 物理化学学报, 2022, 38, 2204057. doi: 10.3866/PKU.WHXB202204057
3	Han C. ; He Y.-B. ; Wang S. ; Wang C. ; Du H. ; Qin X. ; Lin Z. ; Li B. ; Kang F ACS Appl. Mater. Interf. 2016, 8, 18788. doi: 10.1021/acsami.6b04239
4	Schmuch R. ; Wagner R. ; Hörpel G. ; Placke T. ; Winter M Nat. Energy 2018, 3, 267. doi: 10.1038/s41560-018-0107-2
5	Dong C. ; Dong W. ; Lin X. ; Zhao Y. ; Li R. ; Huang F EnergyChem 2020, 2, 100045. doi: 10.1016/j.enchem.2020.100045
6	Reddy M. V. ; Subba Rao G. ; Chowdari B Chem. Rev. 2013, 113, 5364. doi: 10.1021/cr3001884
7	Aravindan V. ; Lee Y. S. ; Madhavi S Adv. Energy Mater. 2015, 5, 1402225. doi: 10.1002/aenm.201402225
8	Ahmed B. ; Shahid M. ; Nagaraju D. H. ; Anjum D. H. ; Hedhili M. N. ; Alshareef H. N ACS Appl. Mater. Interf. 2015, 7, 13154. doi: 10.1021/acsami.5b03395
9	Chao D. ; Zhu C. ; Xia X. ; Liu J. ; Zhang X. ; Wang J. ; Liang P. ; Lin J. ; Zhang H. ; Shen Z. X Nano Lett. 2015, 15, 565. doi: 10.1021/nl504038s
10	Chen Z. ; Zhang C. ; Zhang Z. ; Li J Phys. Chem. Chem. Phys. 2014, 16, 13255. doi: 10.1039/c4cp00855c
11	Chernova N. A. ; Roppolo M. ; Dillon A. C. ; Whittingham M. S J. Mater. Chem. 2009, 19, 2526. doi: 10.1039/B819629J
12	Chiu H. C. ; Lu X. ; Zhou J. ; Gu L. ; Reid J. ; Gauvin R. ; Zaghib K. ; Demopoulos G. P Adv. Energy Mater. 2017, 7, 1601825. doi: 10.1002/aenm.201601825
13	Come J. ; Augustyn V. ; Kim J. W. ; Rozier P. ; Taberna P.-L. ; Gogotsi P. ; Long J. W. ; Dunn B. ; Simon P J. Electrochem. Soc. 2014, 161, A718. doi: 10.1149/2.040405jes
14	Ding J. ; Abbas S. A. ; Hanmandlu C. ; Lin L. ; Lai C.-S. ; Wang P.-C. ; Li L.-J. ; Chu C.-W. ; Chang C -C. J. Power Sources 2017, 348, 270. doi: 10.1016/j.jpowsour.2017.03.007
15	Hemalatha K. ; Prakash A. ; Guruprakash K. ; Jayakumar M J. Mater. Chem. A 2014, 2, 1757. doi: 10.1039/C3TA13352D
16	Hou C. ; Wang J. ; Du W. ; Wang J. ; Du Y. ; Liu C. ; Zhang J. ; Hou H. ; Dang F. ; Zhao L J. Mater. Chem. A 2019, 7, 13460. doi: 10.1039/C9TA03551F
17	Li T. ; Nam G. ; Liu K. ; Wang J.-H. ; Zhao B. ; Ding Y. ; Soule L. ; Avdeev M. ; Luo Z. ; Zhang W Energy Environ. Sci. 2022, 15, 254. doi: 10.1039/D1EE02664J
18	Liu H. ; Wang G. ; Liu J. ; Qiao S. ; Ahn H J. Mater. Chem. 2011, 21, 3046. doi: 10.1039/C0JM03132A
19	Lou S. ; Cheng X. ; Wang L. ; Gao J. ; Li Q. ; Ma Y. ; Gao Y. ; Zuo P. ; Du C. ; Yin G J. Power Sources 2017, 361, 80. doi: 10.1016/j.jpowsour.2017.06.023
20	Lu J. ; Chen Z. ; Pan F. ; Cui Y. ; Amine K Electrochem. Energy Rev. 2018, 1, 35. doi: 10.1007/s41918-018-0001-4
21	Ren H. ; Yu R. ; Qi J. ; Zhang L. ; Jin Q. ; Wang D Adv. Mater. 2019, 31, 1805754. doi: 10.1002/adma.201805754
22	Sun Y. ; Wang J. ; Zhao B. ; Cai R. ; Ran R. ; Shao Z J. Mater. Chem. A 2013, 1, 4736. doi: 10.1039/C3TA01285A
23	Wang J. ; Liu Z. ; Yang W. ; Han L. ; Wei M Chem. Commun. 2018, 54, 7346. doi: 10.1039/C8CC03875A
24	Wang L. ; Zhang Y. ; Guo H. ; Li J. ; Stach E. A. ; Tong X. ; Takeuchi E. S. ; Takeuchi K. J. ; Liu P. ; Marschilok A. C Chem. Mater. 2018, 30, 671. doi: 10.1021/acs.chemmater.7b03847
25	Wu F. ; Maier J. ; Yu Y Chem. Soc. Rev. 2020, 49, 1569. doi: 10.1039/c7cs00863e
26	Wu L. ; Zheng J. ; Wang L. ; Xiong X. ; Shao Y. ; Wang G. ; Wang J. H. ; Zhong S. ; Wu M Angew. Chem. 2019, 131, 821. doi: 10.1002/ange.201811784
27	Yan B. ; Li X. ; Bai Z. ; Li M. ; Dong L. ; Xiong D. ; Li D J. Alloys Compd. 2015, 634, 50. doi: 10.1016/j.jallcom.2015.01.292
28	Yang L. ; Liu L. ; Zhu Y. ; Wang X. ; Wu Y J. Mater. Chem. 2012, 22, 13148. doi: 10.1039/C2JM31364B
29	Yao Z. ; Xia X. ; Xie D. ; Wang Y. ; Zhou C. A. ; Liu S. ; Deng S. ; Wang X. ; Tu J Adv. Funct. Mater. 2018, 28, 1802756. doi: 10.1002/adfm.201802756
30	Yuan T. ; Yu X. ; Cai R. ; Zhou Y. ; Shao Z J. Power Sources 2010, 195, 4997. doi: 10.1016/j.jpowsour.2010.02.020
31	Zhou J. ; Lin N. ; Wang L. ; Zhang K. ; Zhu Y. ; Qian Y J. Mater. Chem. A 2015, 3, 7463. doi: 10.1039/C5TA00516G
32	Zhu K. ; Wang X. ; Liu J. ; Li S. ; Wang H. ; Yang L. ; Liu S. ; Xie T ACS Sustain. Chem. Eng. 2017, 5, 8025. doi: 10.1021/acssuschemeng.7b01595
33	Lu Y. ; Yu L. ; Lou X. W. D Chem 2018, 4, 972. doi: 10.1016/j.chempr.2018.01.003
34	Choi J. W. ; Aurbach D Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13
35	Heligman B. T. ; Manthiram A ACS Energy Lett. 2021, 6, 2666. doi: 10.1021/acsenergylett.1c01145
36	Park C.-M. ; Kim J.-H. ; Kim H. ; Sohn H -J. Chem. Soc. Rev. 2010, 39, 3115. doi: 10.1039/b919877f
37	Song K. ; Liu C. ; Mi L. ; Chou S. ; Chen W. ; Shen C Small 2021, 17, 1903194. doi: 10.1002/smll.201903194
38	Yu S.-H. ; Feng X. ; Zhang N. ; Seok J. ; Abruña H. D Acc. Chem. Res. 2018, 51, 273. doi: 10.1021/acs.accounts.7b00487
39	Li H. ; Balaya P. ; Maier J J. Electrochem. Soc. 2004, 151, : A1878. doi: 10.1149/1.1801451
40	Luo Y. -R. Comprehensive Handbook of Chemical Bond Energies Boca Raton, FL, USA: CRC Press, 2007.
41	Kim M.-S. ; Lee B.-H. ; Park J.-H. ; Lee H. S. ; Hooch Antink W. ; Jung E. ; Kim J. ; Yoo T. Y. ; Lee C. W. ; Ahn C -Y. J. Am. Chem. Soc. 2020, 142, 13406. doi: 10.1021/jacs.0c02203
42	Lou S. ; Zhao Y. ; Wang J. ; Yin G. ; Du C. ; Sun X Small 2019, 15, 1904740. doi: 10.1002/smll.201904740
43	Pan L. ; Zhu X. D. ; Xie X. M. ; Liu Y. T Adv. Funct. Mater. 2015, 25, 3341. doi: 10.1002/adfm.201404348
44	Dong W. ; Huang F eScience 2023, 100158. doi: 10.1016/j.esci.2023.100158
45	Dong W. ; Xie M. ; Zhao S. ; Qin Q. ; Huang F Mater. Sci. Eng., R 2023, 152, 100713. doi: 10.1016/j.mser.2022.100713
46	Fang S. ; Bresser D. ; Passerini S Adv. Energy Mater. 2020, 10, 1902485. doi: 10.1002/aenm.201902485
47	Dong W. ; Xu J. ; Wang C. ; Lu Y. ; Liu X. ; Wang X. ; Yuan X. ; Wang Z. ; Lin T. ; Sui M Adv. Mater. 2017, 29, 1700136. doi: 10.1002/adma.201700136
48	Xu J. ; Dong W. ; Song C. ; Tang Y. ; Zhao W. ; Hong Z. ; Huang F J. Mater. Chem. A 2016, 4, 15698. doi: 10.1039/C6TA05645H
49	Xu J. ; Wang D. ; Kong S. ; Li R. ; Hong Z. ; Huang F J. Mater. Chem. A 2020, 8, 5744. doi: 10.1039/C9TA13602A
50	Wen G. ; Ren B. ; Park M. G. ; Yang J. ; Dou H. ; Zhang Z. ; Deng Y. P. ; Bai Z. ; Yang L. ; Gostick J Angew. Chem. Int. Ed. 2020, 59, 12860. doi: 10.1002/anie.202004149
51	Li X. ; Li J. ; Ali R. N. ; Wang Z. ; Hu G. ; Xiang B Chem. Eng. J. 2019, 368, 764. doi: 10.1016/j.cej.2019.03.020
52	Liang S. ; Cheng Y. J. ; Zhu J. ; Xia Y. ; Müller-Buschbaum P Small Methods 2020, 4, 2000218. doi: 10.1002/smtd.202000218
53	Pan J. ; Zhang Y. ; Li L. ; Cheng Z. ; Li Y. ; Yang X. ; Yang J. ; Qian Y Small Methods 2019, 3, 1900231. doi: 10.1002/smtd.201900231
54	Lin X. ; Dong C. ; Zhao S. ; Peng B. ; Zhou C. ; Wang R. ; Huang F Adv. Sci. 2022, 9, 2202026. doi: 10.1002/advs.202202026
55	Li R. ; Xu J. ; Lv Z. ; Dong W. ; Huang F Sci. China Mater. 2022, 65, 695. doi: 10.1007/s40843-021-1783-0
56	Liu P. ; Hao Q. ; Xia X. ; Lei W. ; Xia H. ; Chen Z. ; Wang X Electrochim. Acta 2016, 214, 1. doi: 10.1016/j.electacta.2016.08.022
57	Bresser D. ; Passerini S. ; Scrosati B Energy Environ. Sci. 2016, 9, 3348. doi: 10.1039/C6EE02346K
58	Zhao Y. ; Li X. ; Yan B. ; Xiong D. ; Li D. ; Lawes S. ; Sun X Adv. Energy Mater. 2016, 6, 1502175. doi: 10.1002/aenm.201502175
59	Kim Y. ; Um J. H. ; Lee H. ; Choi W. ; Choi W. I. ; Lee H. S. ; Kim O. H. ; Kim J. M. ; Cho Y. H. ; Yoon W. S Small 2020, 16, 1905868. doi: 10.1002/smll.201905868
60	Kim S. ; Evmenenko G. ; Xu Y. ; Buchholz D. B. ; Bedzyk M. ; He K. ; Wu J. ; Dravid V. P Adv. Funct. Mater. 2018, 28, 1805723. doi: 10.1002/adfm.201805723
61	Wang Y. ; Han J. ; Gu X. ; Dimitrijev S. ; Hou Y. ; Zhang S J. Mater. Chem. A 2017, 5, 18737. doi: 10.1039/C7TA05798A
62	Zhao Z. ; Tian G. ; Sarapulova A. ; Melinte G. ; Gómez-Urbano J. L. ; Li C. ; Liu S. ; Welter E. ; Etter M. ; Dsoke S ACS Appl. Mater. Interf. 2019, 11, 29888. doi: 10.1021/acsami.9b08539
63	Zhen X. ; Guo X -J. Acta Phys. -Chim. Sin. 2017, 33, 845. doi: 10.3866/PKU.WHXB201612222
	甄绪; 郭雪静. 物理化学学报, 2017, 33, 845d. doi: 10.3866/PKU.WHXB201612222
64	Yu J. ; Wang Y. ; Mou L. ; Fang D. ; Chen S. ; Zhang S ACS Nano 2018, 12, 2035. doi: 10.1021/acsnano.8b00168
65	Zhang J. ; Liang J. ; Zhu Y. ; Wei D. ; Fan L. ; Qian Y J. Mater. Chem. A 2014, 2, 2728. doi: 10.1039/C3TA13228E
66	Wang X. ; Dong C. ; Lou M. ; Dong W. ; Yuan X. ; Tang Y. ; Huang F J. Power Sources 2017, 360, 124. doi: 10.1016/j.jpowsour.2017.05.104
67	Dong W. ; Zhao Y. ; Wang X. ; Yuan X. ; Bu K. ; Dong C. ; Wang R. ; Huang F Adv. Mater. 2018, 30, 1801409. doi: 10.1002/adma.201801409
68	Dong W. ; Li R. ; Xu J. ; Tang Y. ; Huang F Cell Rep. Phys. Sci. 2022, 3, 101109. doi: 10.1016/j.xcrp.2022.101109
69	Becker S. M. ; Scheuermann M. ; Sepelak V. ; Eichhöfer A. ; Chen D. ; Mönig R. ; Ulrich A. S. ; Hahn H. ; Indris S Phys. Chem. Chem. Phys. 2011, 13, 19624. doi: 10.1039/C1CP22298H
70	Ma J. ; Zhang Z. ; Mentbayeva A. ; Yuan G. ; Wang B. ; Wang H. ; Wang G Electrochim. Acta 2019, 312, 31. doi: 10.1016/j.electacta.2019.04.167
71	Li W. ; Yin Y.-X. ; Xin S. ; Song W.-G. ; Guo Y -G. Energy Environ. Sci. 2012, 5, 8007. doi: 10.1039/C2EE21580B
72	Li L. ; Peng S. ; Wang J. ; Cheah Y. L. ; Teh P. ; Ko Y. ; Wong C. ; Srinivasan M ACS Appl. Mater. Interf. 2012, 4, 6005. doi: 10.1021/am301664e
73	Li R. ; Zhang R. ; Lou Z. ; Huang T. ; Jiang K. ; Chen D. ; Shen G Nanoscale 2019, 11, 12116. doi: 10.1039/C9NR03641E
74	Veerappan G. ; Zhang K. ; Ma M. ; Kang B. ; Park J. H Electrochim. Acta 2016, 214, 31. doi: 10.1016/j.electacta.2016.07.076
75	Li W. ; Chen D. ; Shen G J. Mater. Chem. A 2015, 3, 20673. doi: 10.1039/C5TA04175A
76	Xu S. ; Peng B. ; Pang X. ; Huang F ACS Mater. Lett. 2022, 4, 2195. doi: 10.1021/acsmaterialslett.2c00810
77	Wang L. P. ; Leconte Y. ; Feng Z. ; Wei C. ; Zhao Y. ; Ma Q. ; Xu W. ; Bourrioux S. ; Azais P. ; Srinivasan M Adv. Mater. 2016, 29, 1603286. doi: 10.1002/adma.201603286
78	Liu X. ; Teng D. ; Li T. ; Yu Y. ; Shao X. ; Yang X J. Power Sources 2014, 272, 614. doi: 10.1016/j.jpowsour.2014.08.084
79	Dong C. ; Dong W. ; Zhang Q. ; Huang X. ; Gu L. ; Chen I.-W. ; Huang F J. Mater. Chem. A 2020, 8, 626. doi: 10.1039/C9TA11330D
80	Xu H. ; Zhou Y.-N. ; Lu F. ; Fu Z -W. J. Electrochem. Soc. 2011, 158, A285. doi: 10.1149/1.3532037
81	Kwon, C.; Kim, H.; Toupance, T.; Jousseaume, B.; Campet, G.; Fluorine-Doped Tin Oxide Electrods for Lithium Batteries. In Fluorinated Materials for Energy Conversion; Elsevier: The Netherlands, 2005; p. 103.
82	Cui D. ; Zheng Z. ; Peng X. ; Li T. ; Sun T. ; Yuan L J. Power Sources 2017, 362, 20. doi: 10.1016/j.jpowsour.2017.07.024
83	Lin Y. ; Zhong K. ; Zheng J. ; Liang M. ; Xu G. ; Feng Q. ; Li J. ; Huang Z ACS Appl. Energy Mater. 2021, 4, 9848. doi: 10.1021/acsaem.1c01883

Litdium storage mechanism	Oxide	Theoretical specific capacity (mAh·g⁻¹)	Potential (V vs. Li⁺/Li)	Advantages	Drawbacks
Intercalation type	TiO₂	335	1.75	High structure stability, small volume change during litdium insertion, long cycle life, and excellent rate performance	Low tdeoretical specific capacity, high potential, and high cost
	Li₂Ti₃O₁₂	175	1.55
	Nb₂O₅	202	1.63
	V₂O₅	294	3.30
Conversion type	MnO	756	1.25	High tdeoretical specific capacity	High potential, large volume expansion during litdium insertion, low initial coulombic efficiency, high polarization voltage and low energy efficiency
	Fe₂O₃	1007	1.70
	CoO	715	1.85
	NiO	718	2.20
Alloying type	Si	4200	0.35	High tdeoretical specific capacity, low potential	Large volume expansion during litdium insertion, low initial coulombic efficiency
	Ge	1624	0.30
	Sn	994	0.50
	Sb	660	0.90
	In	1012	0.70

[1]	祝鑫彤, 曹斌, 闫崇, 唐城, 陈爱兵, 张强. 锂离子电池石墨负极包覆研究进展[J]. 物理化学学报, 2025, 41(9): 100096 - .
[2]	宋亮亮, 梁颢严, 李顺清, 邱报, 刘兆平. 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略[J]. 物理化学学报, 2025, 41(8): 100085 - .
[3]	黄奥羽, 许君, 黄玉, 储圭, 王卯, 王黎丽, 孙永奇, 蒋臻, 朱晓波. 通过简单的浆料添加剂调整电极-电解液界面以实现稳定的高电压锂离子电池[J]. 物理化学学报, 2025, 41(4): 100037 - .
[4]	郭宇, 黄志伟, 胡雨青, 李俊哲, 徐杰. 钠离子电池中铁基异质结构负极材料的最新研究进展[J]. 物理化学学报, 2025, 41(3): 100022 - .
[5]	黄辰悦, 郑鸿飞, 秦宁, 王灿沛, 王利光, 陆俊. 单晶高镍三元正极材料：挑战与策略[J]. 物理化学学报, 2024, 40(9): 2308051 - .
[6]	张景硕, 翟越, 赵子云, 何家兴, 魏伟, 肖菁, 吴士超, 杨全红. 锂离子电池硅基负极用功能粘结剂的研究进展[J]. 物理化学学报, 2024, 40(6): 2306006 - .
[7]	李莹, 赵钰燊, 陈凯, 刘旭, 伊廷锋, 陈立锋. 高性能锂离子电池用N掺杂C-Sn交联纳米纤维自支撑电极的理性设计[J]. 物理化学学报, 2024, 40(3): 2305007 - .
[8]	胡雪晨, 夏求应, 岳钒, 何欣怡, 梅正浩, 王金石, 夏晖, 黄晓东. LiNbO₃负极薄膜电化学性能及全固态薄膜锂离子电池应用[J]. 物理化学学报, 2024, 40(2): 2309046 - .
[9]	张思宇, 谷昆泓, 鲁兵安, 韩俊伟, 周江. 退役锂离子电池正极的湿法冶金回收工艺：可持续技术的进展与应用[J]. 物理化学学报, 2024, 40(10): 2309028 - .
[10]	李琪, 黎平安, 刘泽通, 张佳辉, 张浩, 余维来, 胡先罗. 同轴静电纺丝构筑微/纳米结构隔膜与电极材料用于锂离子电池：从原理到应用[J]. 物理化学学报, 2024, 40(10): 2311030 - .
[11]	鲁航语, 侯瑞林, 褚世勇, 周豪慎, 郭少华. 高比能锂离子电池层状富锂正极材料改性策略研究进展[J]. 物理化学学报, 2023, 39(7): 2211057 -0 .
[12]	汪茹, 刘志康, 严超, 伽龙, 黄云辉. 高安全锂离子电池复合集流体的界面强化[J]. 物理化学学报, 2023, 39(2): 2203043 -0 .
[13]	朱思颖, 李辉阳, 胡忠利, 张桥保, 赵金保, 张力. 锂离子电池氧化亚硅负极结构优化和界面改性研究进展[J]. 物理化学学报, 2022, 38(6): 2103052 - .
[14]	杨越, 朱加伟, 王鹏彦, 刘海咪, 曾炜豪, 陈磊, 陈志祥, 木士春. 镶嵌于NH₂-MIL-125 (Ti)衍生氮掺多孔碳中的花状超细纳米TiO₂作为高活性和稳定性的锂离子电池负极材料[J]. 物理化学学报, 2022, 38(6): 2106002 - .
[15]	莫英, 肖逵逵, 吴剑芳, 刘辉, 胡爱平, 高鹏, 刘继磊. 锂离子电池隔膜的功能化改性及表征技术[J]. 物理化学学报, 2022, 38(6): 2107030 - .

高性能双金属氧化物负极的理性设计及储锂特性

Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 83

相关文章 15

Metrics

推荐阅读 0

高性能双金属氧化物负极的理性设计及储锂特性

Rational Design of Bimetallic Oxide Anodes for Superior Li+ Storage

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 83

相关文章 15

Metrics

推荐阅读 0

Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage