ZnCoP/CdLa2S4肖特基异质结的构建促进光催化产氢

doi:10.3866/PKU.WHXB202404030

物理化学学报 >> 2024, Vol. 40 >> Issue (11): 2404030.doi: 10.3866/PKU.WHXB202404030

所属专题：太阳燃料制备

ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢

何建印¹, 陈柳云¹, 谢新玲¹, 秦祖赠¹, 纪红兵¹^,², 苏通明¹^,*()

¹ 广西大学化学化工学院, 广西石化资源加工与过程强化技术重点实验室, 南宁 530004
² 浙江工业大学化学工程学院, 浙江绿色石化与轻烃转化研究院, 杭州 310014

收稿日期:2024-04-19 修回日期:2024-05-20 录用日期:2024-05-21 发布日期:2024-10-14
通讯作者: Email: sutm@gxu.edu.cn (苏通明)
基金资助:
国家自然科学基金项目(22208065); 广西自然科学基金项目(2022GXNSFBA035483); 广西石化资源加工及过程强化技术重点实验室开放项目(2023K012); 广西八桂学者专项资金

Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution

Jianyin He¹, Liuyun Chen¹, Xinling Xie¹, Zuzeng Qin¹, Hongbing Ji¹^,², Tongming Su¹^,*()

¹ Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
² Institute of Green Petroleum Processing and Light Hydrocarbon Conversion, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Received:2024-04-19 Revised:2024-05-20 Accepted:2024-05-21 Published:2024-10-14
Contact: Email: sutm@gxu.edu.cn (Tongming Su)
Supported by:
the National Natural Science Foundation of China(22208065); Guangxi Natural Science Foundation(2022GXNSFBA035483); Opening Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology(2023K012); Special Funding for 'Guangxi Bagui Scholars'

1. WHXB202404030-SI-9p.pdf(2647KB)

摘要/Abstract

摘要：

采用异质结光催化剂来光催化产氢被认为是一种解决环境和能源危机的有效方法。本文采用水浴加热辅助的物理混合法制备了ZnCoP/CdLa₂S₄肖特基异质结，以提高光催化产氢的效率。由于ZnCoP具有较高的功函数和金属导电性，光生电子可以通过ZnCoP/CdLa₂S₄界面从CdLa₂S₄转移到ZnCoP上，从而抑制了光生电子与空穴的复合。此外，在ZnCoP与CdLa₂S₄的界面处形成的肖特基异质结抑制了电子从ZnCoP回流到CdLa₂S₄，进一步促进了电子-空穴对的分离。同时，与CdLa₂S₄相比，ZnCoP/CdLa₂S₄异质结具有更强的可见光吸收性能。此外，ZnCoP可作为电子受体和产氢的活性位点。紧密的ZnCoP/CdLa₂S₄界面、ZnCoP较高的功函数和金属电导率与肖特基结之间的协同作用显著增强了CdLa₂S₄光催化产氢的性能。当ZnCoP的质量分数为30%时，30ZCP/CLS复合材料具有最佳的光催化性能，在可见光照射下，以Na₂S和Na₂SO₃为牺牲剂时，光催化产氢的速率达到10.26 mmol·g^-1·h^-1，是CdLa₂S₄的7.7倍。结合活性数据和表征结果，提出了ZnCoP/CdLa₂S₄肖特基异质结光催化产氢可能的反应机理。

关键词: CdLa₂S₄, ZnCoP, 肖特基异质结, 光催化, 电荷转移

Abstract:

Photocatalytic hydrogen evolution by heterojunction photocatalysts is considered an effective way to address environmental and energy crises. In this work, a novel ZnCoP/CdLa₂S₄ Schottky heterojunction was prepared via a physical mixing method assisted by water bath heating and used to enhance the efficiency of photocatalytic hydrogen production. Owing to the higher work function and metallic conductivity of ZnCoP, the photoinduced electrons can transfer from CdLa₂S₄ to ZnCoP through the ZnCoP/CdLa₂S₄ interface, which suppresses the recombination of photoinduced electrons and holes. Moreover, the Schottky heterojunction formed at the interface between ZnCoP and CdLa₂S₄ inhibits electron backflow from ZnCoP to CdLa₂S₄, which further promotes the separation of electron-hole pairs. Meanwhile, the ZnCoP/CdLa₂S₄ heterojunction exhibited enhanced visible light absorption compared to CdLa₂S₄. In addition, ZnCoP acts as an electron acceptor and hydrogen evolution active site. The synergistic effect of the tight ZnCoP/CdLa₂S₄ interface, the higher work function and metallic conductivity of ZnCoP, and the formation of Schottky junctions significantly enhance the photocatalytic hydrogen production evolution performance of CdLa₂S₄. When the amount of ZnCoP was 30 wt% (wt%, mass fraction), the 30ZCP/CLS composite showed the highest photocatalytic performance, and the hydrogen production rate reached 10.26 mmol·g^-1·h^-1 under visible light irradiation and with Na₂S and Na₂SO₃ as sacrificial agents, which was 7.7 times that of CdLa₂S₄. Combined with the activity data and characterization results, a potential mechanism for photocatalytic hydrogen production over ZnCoP/CdLa₂S₄ Schottky heterojunctions was proposed.

Key words: CdLa₂S₄, ZnCoP, Schottky heterojunction, Photocatalytic, Charge transfer

何建印, 陈柳云, 谢新玲, 秦祖赠, 纪红兵, 苏通明. ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢[J]. 物理化学学报, 2024, 40(11), 2404030. doi: 10.3866/PKU.WHXB202404030

Jianyin He, Liuyun Chen, Xinling Xie, Zuzeng Qin, Hongbing Ji, Tongming Su. Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution[J]. Acta Phys. -Chim. Sin. 2024, 40(11), 2404030. doi: 10.3866/PKU.WHXB202404030

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202404030

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I11/2404030

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ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢

Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution

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