Acta Phys. -Chim. Sin. ›› 1996, Vol. 12 ›› Issue (10): 885-891.doi: 10.3866/PKU.WHXB19961006

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The Phase Behavior and Structure of SDS/BA/H2O System

Shen Ming,Liu Tian-Qing,Guo Rong   

  1. Department of Chemistry,Teacher's College,Yangzhou University,Jiangsu,Yangzhou 225002
  • Received:1996-04-18 Revised:1996-05-30 Published:1996-10-15
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Abstract:

Micelle, microemulsion, lamellar liquid crystal and hexagonal liquid crystal can be formed in SDS/BA/H2O system, and the exchanging between them can be explained by the R ratio. The value of distribution coefficient of BA in O/W microemulsion, K=168, shows that most of BA molecules should be solubilized in the SDS micelle phase. With increasing the weight ratio of BA/SDS, d0 values have almost no change and the penetration of solvent, α, slightly increases in the lamellar liquid crystal, and the radius r in hexagonal liquid crystal is almost unchanged and the penetrations of solvent, α, increase in hexagonal liquid crystal.

Key words: Surfactant, Micelle, Microemulsion, Lamellar liquid crystal, Hexagonal liquid crystal