CeO2基固溶体氧缺位拉曼光谱表征的研究进展

doi:10.3866/PKU.WHXB201203052

Abstract

Abstract: This review summarizes the current status of the evolution and observation of oxygen vacancies in CeO₂-doped solid solutions as characterized by Raman spectroscopy. Three Raman peaks at 465, 560, and 600 cm^-1 are ascribed to the F_2g symmetrical stretching vibration mode of CeO₂ in a fluorite structure, oxygen vacancies, and a MO₈-type complex, respectively. The presence of oxygen vacancies was related to the ionic valence states of the dopant, while the MO₈-type complex was associated with the ionic radii of the dopant. The oxygen vacancy concentration correlated with the sample absorbance and the surface enrichment of oxygen vacancies. The in situ Raman spectroscopic investigations show that the atmospheric composition and temperature had a large influence on the absorbance of the samples, which in turn alters the detection depth of the Raman laser and the observed oxygen vacancy concentration.

Key words: Raman spectroscopy, Oxygen vacancy, CeO₂-based solid solution, Absorbance

LI Lan, HU Geng-Shen, LU Ji-Qing, LUO Meng-Fei. Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy[J]. Acta Phys. -Chim. Sin. 2012, 28(05), 1012-1020. doi: 10.3866/PKU.WHXB201203052

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Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy

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Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy