烧结型NdFeB永磁体表面有机纳米复合膜的制备及性能

doi:10.3866/PKU.WHXB201301102

Abstract

Abstract:

A nanofilm (TES-SAMs) was prepared by self-assembly of 6-(3-triethoxysilylpropylamino)-1,3, 5-triazine-2,4-dithiol monosodium (TES) on a sintered NdFeB surface. A nano composite film (TES-ATP) was then prepared on the TES-SAMs surface by a self-developed polymer plating technique using 6-(N-allyl-1,1,2,2-tetrahydroperfluorodecylamino)-1,3,5-triazine-2,4-dithiol monosodium (ATP). The surface of the TES-SAMs and TES-ATP were characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, spectroscopic ellipsometry, atomic force microscopy (AFM), and contact angle measurements. A UMT-2 tribometer was used to investigate their micro-tribological properties. The experimental results showed that the thicknesses of TES-SAMs and TES-ATP were 5.08 and 29.78 nm, respectively. The surface free energy of TES-ATP and TES-SAMs decreased from 73.13 mJ·m^-2 for the substrate to 10.19 and 63.39 mJ·m^-2, respectively. The contact angle of distilled water on TES-ATP was 123.5° , indicating transformation from a hydrophilic surface to a hydrophobic one. The friction coefficient was effectively reduced from 0.71 for the substrate to 0.22 for TES-SAMs and 0.12 for TES-ATP. In addition, the TES-ATP composite film possessed excellent anti-wear ability. Thus, the present TES-ATP composite film provides a novel approach to solving tribological issues in micro-electro-mechaanical system(MEMS).

Key words: Self assembled monolayer, Polymer plating, Composite film, Surface free energy, Hydrophobicity, Micro-tribological property

LIU Qin, KANG Zhi-Xin, FANG Gang. Preparation and Properties of Polymeric Nano Composite Filmon Surface of Sintered NdFeB Permanent Magnet[J]. Acta Phys. -Chim. Sin. 2013, 29(04), 821-828. doi: 10.3866/PKU.WHXB201301102

References

(1) Gu, G. T.; Zhang, Z. J.; Dang, H. X. Acta Phys. -Chim. Sin.2002, 18, 669. [谷国团, 张治军,党鸿辛. 物理化学学报,2002, 18, 669.] doi: 10.3866/PKU.WHXB20020722
(2) Jiang, C.; Tsukruk, V. V. Adv. Mater. 2006, 18, 829.
(3) Ulman, A. Chem. Rev. 1996, 96, 1533. doi: 10.1021/cr9502357
(4) Van Ooij, W. J.; Zhu, D.; Stacy, M.; Seth, A.; Mugada, T.;Gandhi, J.; Puomi, P. Tsinghua Science and Technology 2005,10, 639. doi: 10.1016/S1007-0214(05)70134-6
(5) Deflorian, F.; Rossi, S.; Fedrizzi, L. Electrochim. Acta 2006, 51,6097. doi: 10.1016/j.electacta.2006.02.042
(6) Yoshimitsu, Z.; Nakajima, A.; Watanabe, T.; Hashimoto, K.Langmuir 2002, 18, 5818. doi: 10.1021/la020088p
(7) Li, S. M.; Zhou, S. Z.; Liu, J. H. Acta Phys. -Chim. Sin. 2009,25, 2581. [李松梅, 周思卓, 刘建华. 物理化学学报, 2009, 25,2581.] doi: 10.3866/PKU.WHXB20091214
(8) Liu, Y.; Evans, F. D.; Song, Q.; Grainger, D. W. Langmuir 1996,12, 1235. doi: 10.1021/la950504o
(9) Maboudian, R.; Ashurst, W. R.; Carraro, C. Sens. Actuators A2000, 82, 219. doi: 10.1016/S0924-4247(99)00337-4
(10) Mori, K.; Hirahara, H.; Oishi, Y.; Kumagai, N. Electrochem.Solid State Lett. 2000, 3, 546.
(11) Kang, Z. X.; Mori, K.; Oishi, Y. Surf. Coat. Tech. 2005, 195,162. doi: 10.1016/j.surfcoat.2004.07.128
(12) Kang, Z. X.; Ye, Q.; Sang, J.; Li, Y. Y. J. Mater. Process. Tech.2009, 209, 4543. doi: 10.1016/j.jmatprotec.2008.10.031
(13) Kang, Z. X.; Liu, Y. H.; Sang, J.; Wang, F.; Li, Y. Y.; Cong, P. H.Tribology 2011, 31, 12. [康志新, 刘应辉, 桑静,王芬,李元元, 丛培红.摩擦学学报, 2011, 31, 12.]
(14) Kang, Z. X.; Sang, J.; Shao, M.; Li, Y. Y. J. Mater. Process.Tech. 2009, 209, 4590. doi: 10.1016/j.jmatprotec.2008.10.029
(15) Speliotis, T.; Niarchos, D.; Meneroud, P.; Magnac, G.;Claeyssen, F.; Pepin, J.; Fermon, C.; Pannetier, M.; Biziere, N.J. Magn. Magn. Mater. 2007, 316, e120.
(16) Goel, V. K.; Ferrara, L. SAS Journal 2008, 2, 120. doi: 10.1016/S1935-9810(08)70028-8
(17) Bhushan, B. Microelectron. Eng. 2007, 84, 387. doi: 10.1016/j.mee.2006.10.059
(18) Mcguiness, P.; Jezeršek, D.; Kobe, S.; Markoli, B.; Spaió, S.;Saje, B. J. Magn. Magn. Mater. 2006, 305, 177. doi: 10.1016/j.jmmm.2005.12.009
(19) Cugat, O.; Reyne, G.; Delamare, J.; Rostaing, H. Sens.Actuators A 2006, 129, 265. doi: 10.1016/j.sna.2005.09.058
(20) Luo, J. B.; He, Y.; Wen, S. Z.; Zhong, J. Tribology 2005, 25,283. [雒建斌,何雨,温诗铸,钟掘.摩擦学学报, 2005,25, 283.]
(21) Bhushan, B.; Kasai, T.; Kulik, G.; Barbieri, L.; Hoffmann, P.Ultramicroscopy 2005, 105, 176. doi: 10.1016/j.ultramic.2005.06.034
(22) Kim, M. T. Thin Solid Films 1997, 311, 157. doi: 10.1016/S0040-6090(97)00683-4
(23) Hayakawa, T.; Yoshinari, M.; Nemoto, K. Biomaterials 2004,25, 119. doi: 10.1016/S0142-9612(03)00484-8
(24) Liu, Y. H.; Kang, Z. X. Acta Phys. -Chim. Sin. 2011, 27, 1777.[刘应辉,康志新. 物理化学学报, 2011, 27, 1777.] doi: 10.3866/PKU.WHXB20110725
(25) Castner, D. G.; Hinds, K.; Grainger, D. W. Langmuir 1996, 12,5083. doi: 10.1021/la960465w
(26) Ishida, T.; Choi, N.; Mizutani, W.; Tokumoto, H.; Kojima, I.;Azehara, H.; Hokari, H.; Akiba, U.; Fujihira, M. Langmuir1999, 15, 6799. doi: 10.1021/la9810307
(27) Rodriguez, J. A.; Hrbek, J.; Dvorak, J.; Jirsak, T.; Maiti, A.Chem. Phys. Lett. 2001, 336, 377. doi: 10.1016/S0009-2614(01)00182-8
(28) Liao, J. G.; Wang, X. J.; Zuo, Y.; Zhang, L.; Wen, J. Q.; Li, Y.B. J. Inorg. Mater. 2008, 23, 145. [廖建国, 王学江, 左奕,张利, 文季秋, 李玉宝. 无机材料学报, 2008, 23, 145.] doi: 10.3724/SP.J.1077.2008.00145
(29) Satyanarayana, N.; Sinha, S. K. J. Phys. D-Appl. Phys. 2005,38, 3512. doi: 10.1088/0022-3727/38/18/029
(30) Harun, M. K.; Lyon, S. B.; Marsh, J. Prog. Org. Coat. 2003, 46,21. doi: 10.1016/S0300-9440(02)00165-0
(31) Ferraria, A. M.; Lopes Da Silva, J. D.; Botelho Do Rego, A. M.Polymer 2003, 44, 7241. doi: 10.1016/j.polymer.2003.08.038
(32) Sultana, T.; Georgiev, G. L.; Auner, G.; Newaz, G.; Herfurth, H.J.; Patwa, R. Appl. Surf. Sci. 2008, 255, 2569. doi: 10.1016/j.apsusc.2008.07.149
(33) Mori, K.; Sasaki, Y.; Sai, S.; Kaneda, S.; Hirahara, H.; Oishi, Y.Langmuir 1995, 11, 1431. doi: 10.1021/la00005a004
(34) Gindl, M.; Sinn, G.; Gindl, W.; Reiterer, A.; Tschegg, S.Colloids Surf. A Physicochem. Eng. Aspects 2001, 181, 279.doi: 10.1016/S0927-7757(00)00795-0
(35) Cui, B. F.; Zhou, H. D.; Zhang, J. Y.; Chen, J. M. Tribology2011, 31, 1. [崔宝凤, 周惠娣,张俊彦, 陈建敏.摩擦学学报,2011, 31, 1.]
(36) Sun, C. G.; Zhang, H. C.; Gao, Y. Z. Chinese Journal ofMaterials Research 2009, 23, 6. [孙昌国, 张会臣,高玉周.材料研究学报, 2009, 23, 6.]

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Preparation and Properties of Polymeric Nano Composite Filmon Surface of Sintered NdFeB Permanent Magnet

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