碱式硫酸锌转化法制备ZnO多孔片及其光致发光性能

doi:10.3866/PKU.WHXB201302045

Abstract

Abstract:

Highly crystalline, porous ZnO sheets were prepared from chemically-deposited zinc sulfate hydroxide hydrate (ZSH) sheets by sintering at 1000 ℃. The formation mechanism of ZSH in Zn²⁺- hexamethyltetramine (HMT) precursor system, the transformation process of ZSH to ZnO, and the crystalline, microstructural and optical properties of the ZnO sheets were investigated. The porous ZnO sheets possessed a well-defined hexagonal shape with controllable size (10-50 μm) and thickness (200-500 nm), high crystallinity, and strong ultraviolet photoluminescence without detectable defectrelated visible emission. Submicron-sized pores (100-500 nm) and polygonal or irregular ZnO particles resulting from the limited mass transport during high temperature sintering were observed in the ZnO sheets. Analysis of the formation mechanism indicated that the high affinity of SO₄^2- for Zn²⁺ was responsible for the formation of ZSH in the Zn²⁺-HMT precursor system, and the thermolysis of ZSH affected the morphology and microstructure of the ZnO sheets. This work reveals a facile route to porous ZnO nanostructures with good crystallinity and optical properties, which make them suitable for application in catalysis, and photo and/or electrical devices.

Key words: ZnO, Porous sheet, Zinc sulfate hydroxide hydrate, Photoluminescence

HE Peng, GAO Xiang-Dong, WU Li-Bin, JIANG Zheng-Wu, WANG Cai-Lu, LI Xiao-Min. Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance[J].Acta Phys. -Chim. Sin., 2013, 29(04): 874-880.

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Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance

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