一种适用于生物油低温制氢的碳纳米纤维促进的镍催化剂

doi:10.3866/PKU.WHXB201302225

Abstract

Abstract:

Hydrogen is a clean energy with high heat value that has been widely used in industry. Previous studies indicate that biomass can be converted in to gaseous fuels (hydrogen), liquid fuels and other chemicals. Biomass is the only renewable carbon resource and has attracted increasing attention because of the increasing price of oil and its environmental friendliness. To decrease energy consumption and minimize cost, it is very important to develop a process to produce hydrogen from bio-oil by low temperature steam reforming over non-noble metal catalysts. This work reports a carbon nanofiberssupported Ni (Ni/CNFs) catalyst prepared by the homogeneous impregnation method. The Ni/CNFs catalyst was successfully used to produce hydrogen via low-temperature (350-550℃) steam reforming of bio-oil. The effects of temperature and water steam/carbon molar ratio (n_S/n_C) on the reforming of bio-oil were investigated. The highest carbon conversion and H₂ yield over the 22% Ni/CNFs catalyst reached about 94.7% and 92.1%, respectively, at a reforming temperature of 550℃. The Ni/CNFs catalyst containing a uniform Ni distribution exhibited a much higher activity in low-temperature reforming of bio-oil at 350-450℃ than the usual Ni/Al₂O₃ catalyst. Reaction conditions were investigated and catalysts were characterized to reveal the relationship between catalyst structure and performance for hydrogen production from bio-oil.

Key words: Hydrogen, Bio-oil, Low temperature, Steam reforming, Carbon nanofibers-supported Ni catalyst

XU Yong, JIANG Pei-Wen, LI Quan-Xin. Carbon Nanofibers-Supported Ni Catalyst for Hydrogen Production from Bio-Oil through Low-Temperature Reforming[J]. Acta Phys. -Chim. Sin. 2013, 29(05), 1041-1047. doi: 10.3866/PKU.WHXB201302225

References

(1) Galdámez, J. R.; García, L.; Bilbao, R. Energy Fuels 2005, 19,1133. doi: 10.1021/ef049718g
(2) Hou, T.; Yuan, L. X.; Ye, T. Q.; Gong, L.; Tu, J.; Yamamoto, M.;Youshifumi, T.; Li, Q. X. Int. J. Hydrog. Energy 2009, 34, 9095.doi: 10.1016/j.ijhydene.2009.09.012
(3) Haryanto, A.; Fernando, S.; Murali, N.; Adhikari, S. EnergyFuels 2005, 19, 2098. doi: 10.1021/ef0500538
(4) Das, D.; Vezirog?lu, T. N. Int. J. Hydrog. Energy 2001, 26, 13.doi: 10.1016/S0360-3199(00)00058-6
(5) Nourouzi, L. S.; Larachi, F.; Benali, M. Ind. Eng. Chem. Res.2008, 47, 7118. doi: 10.1021/ie800773a
(6) Holladay, J. D.; Hu, J.; King, D. L.;Wang, Y. Catal. Today2009, 139, 244. doi: 10.1016/j.cattod.2008.08.039
(7) Medrano, J. A.; Oliva, M.; Ruiz, J.; García, L.; Arauzo, J.Energy 2011, 36, 2215. doi: 10.1016/j.energy.2010.03.059
(8) Bridgwater, A. V. Biomass Bioenerg. 2012, 38, 68. doi: 10.1016/j.biombioe.2011.01.048
(9) Yildiz, K.; Arif, H, I. Int. J. Hydrog. Energy 2009, 34, 8799.doi: 10.1016/j.ijhydene.2009.08.078
(10) Kan, T.; Xiong, J. X.; Li, X. L.; Ye, T. Q.; Yuan, L. X.;Youshifumi, T.; Yamamoto, M.; Li, Q. X. Int. J. Hydrog. Energy2010, 35, 518. doi: 10.1016/j.ijhydene.2009.11.010
(11) Ye, T. Q.; Yuan, L. X.; Chen, Y. Q.; Kan, T.; Tu, J.; Zhu, X. F.;Torimoto, Y.; Yamamoto, M.; Li, Q. X. Catal. Lett. 2009, 127,323. doi: 10.1007/s10562-008-9683-2
(12) Ekaterini, C. V.; Angeliki, A. L. Appl. Catal. A 2007, 351, 111.
(13) Xie, J. J.; Su, D. R.; Yin, X. L.;Wu, C. Z.; Zhu, J. X. Int. J.Hydrog. Energy 2011, 36, 15560.
(14) Kinoshita, C. M.; Turn, S. Q. Int. J. Hydrog. Energy 2003, 28,1065.
(15) Chornet, E.; Czernik, S. Nature 2002, 418, 928.
(16) Huber, G.W.; Shabaker, J.W.; Dumesic, J. A. Science 2003,300, 2075. doi: 10.1126/science.1085597
(17) Stefan, C.; Robert, E.; Richard, F. Catal. Today 2007, 129, 265.doi: 10.1016/j.cattod.2006.08.071
(18) Ekaterini, C. V.; Angeliki, A. L. Int. J. Hydrog. Energy 2007, 32,212. doi: 10.1016/j.ijhydene.2006.08.021
(19) Jonathan, R. M.; Joelle, D. B.; Shannon, M.; Robert, J. E.;Stefan, C.; Richard, J. F.; Anthony, M. D. Int. J. Hydrog. Energy2009, 34, 8519. doi: 10.1016/j.ijhydene.2009.07.099
(20) Kechagiopoulos, P. N.; Voutetakis, S. S.; Lemonidou, A. A.;Vasalos, I. A. Energy Fuels 2006, 20, 2155. doi: 10.1021/ef060083q
(21) Ba, T.; Chaala, A.; Garcia, P. M.; Rodrigue, D.; Roy, C. EnergyFuels 2004, 18, 704. doi: 10.1021/ef030118b
(22) Seyedeyn, A. F.; Salehi, E.; Abedi, J.; Harding, T. Fuel Process.Technol. 2011, 92, 563. doi: 10.1016/j.fuproc.2010.11.012
(23) Rioche, C.; Kulkarni, S.; Meunier, F. C.; Breen, J. P.; Burch, R.Appl. Catal. B 2005, 61, 130. doi: 10.1016/j.apcatb.2005.04.015
(24) Garcia, L.; French, R.; Czernik, S.; Chornet, E. Appl. Catal. A2000, 201, 225. doi: 10.1016/S0926-860X(00)00440-3
(25) Takanabe, K.; Aika, K.; Seshan, K.; Lefferts, L. J. Catal. 2004,227, 101. doi: 10.1016/j.jcat.2004.07.002
(26) Liguras, D. K.; Kondarides, D. I.; Verykios, X. E. Appl. Catal.B 2003, 43, 345. doi: 10.1016/S0926-3373(02)00327-2
(27) Kugai, J.; Velu, S.; Song, C. Catal. Lett. 2005, 101, 255. doi: 10.1007/s10562-005-4901-7
(28) Aupretre, F.; Descorme, C.; Duprez, D. Catal. Commun. 2002,3, 263. doi: 10.1016/S1566-7367(02)00118-8
(29) Domine, M. E.; Iojoiu, E. E.; Davidian, T.; Guilhaume, N.;Mirodatos, C. Catal. Today 2008, 133-135, 565.
(30) Xu, X.W.; Jiang, E. C.;Wang, M. F.; Li, B. S. Renew. Energy2012, 39, 126. doi: 10.1016/j.renene.2011.07.030
(31) Wang, S. R.; Li, X. B; Guo, L.; Luo, Z. Y. Int. J. Hydrog.Energy 2012, 37, 11122. doi: 10.1016/j.ijhydene.2012.05.011
(32) Wang, C.; Qiu, J. S.; Liang, C. H.; Xing, L.; Yang, X. M. Catal.Commun. 2008, 9, 1749.
(33) Bezemer, G. L.; Radstake, P. B.; Falke, U.; Oosterbeek, H.;Kuipers, H, P.; Dillen, A. J.; Jong, K. P. J. Catal. 2006, 237,152. doi: 10.1016/j.jcat.2005.10.031
(34) Eva, D.; Marta, L.; Salvador, O. Int. J. Hydrog. Energy 2010,35, 4576.
(35) Wang, H. J.; Zhao, F. Y.; Fujitac, S. I.; Masahiko, A. Catal.Commun. 2008, 9, 362. doi: 10.1016/j.catcom.2007.07.002
(36) Cortright, R. D.; Davda, R. R.; Dumesic, J. A. Nature 2002,418, 964. doi: 10.1038/nature01009

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Carbon Nanofibers-Supported Ni Catalyst for Hydrogen Production from Bio-Oil through Low-Temperature Reforming

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