利用Zn掺杂制备高效稳定工业级电解水的NiBP微球催化剂研究

doi:10.1016/j.actphy.2025.100079

Abstract

Abstract:

Green hydrogen holds great promise for the future energy ecosystem and designing alternative electrocatalysts is essential for industrial-scale green hydrogen production for high-current water splitting under industrial conditions. Herein, the Zn-doped NiBP microsphere electrocatalyst is fabricated via a multi-step process combining hydrothermal and electrochemical approaches, followed by post-annealing. The optimized Zn/NiBP electrode outperforms the majority of previously reported catalysts, with low overpotentials of 95 mV for HER (hydrogen evolution reaction) and 280 mV for OER (oxygen evolution reaction) at 100 mA∙cm⁻² in 1 mol∙L⁻¹ KOH. The bifunctional Zn/NiBP||Zn/NiBP demonstrates a 3.10 V cell voltage at 2000 mA∙cm⁻² in 1 mol∙L⁻¹ KOH, surpassing the benchmark Pt/C||RuO₂ systems. The Pt/C||Zn/NiBP hybrid system exhibits exceptionally low cell voltages of 2.50 and 2.30 V at 2000 mA∙cm⁻² in 1 and 6 mol∙L⁻¹ KOH respectively, demonstrating excellent overall water-splitting performance under challenging industrial conditions. Furthermore, the 2-E system shows remarkable stability over 120 hours at 1000 mA∙cm⁻² in 1 and 6 mol∙L⁻¹ KOH, indicating the robust anti-corrosion properties of the Zn/NiBP microspheres. Zn-doped NiBP microspheres exhibit enhanced electrochemical conductivity, active surface area and intrinsic electrocatalytic activity due to synergistic interactions among Zn, Ni, B and P, enabling rapid charge transfer and superior electrocatalytic performance for efficient hydrogen generation.

Key words: High current, Zn-doping, Hydrogen generation, Electrocatalyst, Hybrid electrocatalyst.

Sumiya Akter Dristy, Md Ahasan Habib, Shusen Lin, Mehedi Hasan Joni, Rutuja Mandavkar, Young-Uk Chung, Md Najibullah, Jihoon Lee. Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting[J]. Acta Phys. -Chim. Sin. 2025, 41(7), 100079. doi: 10.1016/j.actphy.2025.100079

Figures/Tables 9

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References 87

1	A.Z. Arsad, M.A. Hannan, A.Q. Al-Shetwi, R.A. Begum, M.J. Hossain, P.J. Ker, T.M.I. Mahlia. Int. J. Hydrogen Energy 2023, 48, 27841. doi: 10.1016/j.ijhydene.2023.04.014
2	A.E. Yüzbaşıoğlu, C. Avşar, A.O. Gezerman. Curr. Res. Green Sustain. Chem. 2022, 5, 100307. doi: 10.1016/j.crgsc.2022.100307
3	M. Amin, H.H. Shah, A.G. Fareed, W.U. Khan, E. Chung, A. Zia, Z.U.R. Farooqi, C. Lee. Int. J. Hydrogen Energy 2022, 47, 33112. doi: 10.1016/j.ijhydene.2022.07.172
4	U.Y. Qazi. Energies 2022, 15, 4741. doi: 10.3390/en15134741
5	W.-J. Jiang, T. Tang, Y. Zhang, J.-S. Hu. Acc. Chem. Res. 2020, 53, 1111. doi: 10.1021/acs.accounts.0c00127
6	R. Santhosh Kumar, S.C. Karthikeyan, S. Ramakrishnan, S. Vijayapradeep, A. Rhan Kim, J.-S. Kim, D. Jin Yoo. Chem. Eng. J. 2023, 451, 138471. doi: 10.1016/j.cej.2022.138471
7	S.D. Bhoyate, J. Kim, F.M. de Souza, J. Lin, E. Lee, A. Kumar, R.K. Gupta. Coord. Chem. Rev. 2023, 474, 214854. doi: 10.1016/j.ccr.2022.214854
8	R. Zheng, C. Zhao, J. Xiong, X. Teng, W. Chen, Z. Hu, Z. Chen. Sustain. Energy Fuels 2021, 5, 4023. doi: 10.1039/D1SE00697E
9	P.J. Chirik, K.M. Engle, E.M. Simmons, S.R. Wisniewski. Org. Process Res. Dev. 2023, 27, 1160. doi: 10.1021/acs.oprd.3c00025
10	S. Bulakhe, N. Shinde, J.S. Kim, R.S. Mane, R. Deokate. Int. J. Energy Res. 2022, 46, 17829. doi: 10.1002/er.8458
11	M.N. Lakhan, A. Hanan, A. Hussain, I. Ali Soomro, Y. Wang, M. Ahmed, U. Aftab, H. Sun, H. Arandiyan. Chem. Commun. 2024, 60, 5104. doi: 10.1039/D3CC06015B
12	H. Su, J. Jiang, S. Song, B. An, N. Li, Y. Gao, L. Ge. Chinese J. Catal. 2023, 44, 7- 49. doi: 10.1016/S1872-2067(22)64149-4
13	Y. Xin, Q. Hua, C. Li, H. Zhu, L. Gao, X. Ren, P. Yang, A. Liu. J. Mater. Chem. A 2024, 12, 23147. doi: 10.1039/D4TA03393K
14	L. Huo, C. Jin, K. Jiang, Q. Bao, Z. Hu, J. Chu. Adv. Energy Sustain. Res. 2022, 3, 2100189. doi: 10.1002/aesr.202100189
15	X. Deng, R. Zhang, Q. Li, W. Gu, L. Hao. ChemistrySelect 2022, 7, e202200091. doi: 10.1002/slct.202200091
16	G. Anandha babu, S. Perumal, M.K.A. Mohammed, M. Govindasamy, A.A. Alothman, M. Ouladsmane, R. Ganesan. Int. J. Hydrogen Energy 2024, 54, 652. doi: 10.1016/j.ijhydene.2023.06.063
17	S. Lin, R. Mandavkar, M.A. Habib, S.A. Dristy, M.H. Joni, J.-H. Jeong, J. Lee. J. Colloid Interface Sci. 2024, 677, 587. doi: 10.1016/j.jcis.2024.08.009
18	W. Li, Y. Deng, L. Luo, Y. Du, X. Cheng, Q. Wu. J. Colloid Interface Sci. 2023, 639, 416. doi: 10.1016/j.jcis.2023.02.071
19	P. Ye, K. Fang, H. Wang, Y. Wang, H. Huang, C. Mo, J. Ning, Y. Hu. Nat. Commun. 2024, 15, 1012. doi: 10.1038/s41467-024-45320-0
20	L. Huang, R. Yao, X. Wang, S. Sun, X. Zhu, X. Liu, M.G. Kim, J. Lian, F. Liu, Y. Li, H. Zong, S. Han, X. Ding. Energy Environ. Sci. 2022, 15, 2425. doi: 10.1039/D1EE02764F
21	J. Du, Z. Zou, C. Xu. Electrochem. Sci. Adv. 2021, 1, e2000038. doi: 10.1002/elsa.202000038
22	M. Ahasan Habib, R. Mandavkar, S. Lin, S. Burse, T. Khalid, M. Hasan Joni, J.H. Jeong, J. Lee. Chem. Eng. J. 2023, 462, 142177. doi: 10.1016/j.cej.2023.142177
23	S. Anantharaj, S.R. Ede, K. Sakthikumar, K. Karthick, S. Mishra, S. Kundu. ACS Catal. 2016, 6, 8069. doi: 10.1021/acscatal.6b02479
24	M.K. Sikdar, A. Singh, S. Bhakta, M. Sahoo, S.N. Jha, D.K. Shukla, D. Kanjilal, P.K. Sahoo. Phys. Chem. Chem. Phys. 2022, 24, 18255. doi: 10.1039/D2CP02514K
25	X. Zhao, Z. Li, S. Wu, M. Lu, X. Xie, D. Zhan, J. Yan. Adv. Electron. Mater. 2024, 10, 2300610. doi: 10.1002/aelm.202300610
26	S. Guo, Z. Du, S. Dai. Phys. Status Solidi 2009, 246, 2329. doi: 10.1002/pssb.200945192
27	C. Huang, B. Zhang, Y. Wu, Q. Ruan, L. Liu, J. Su, Y. Tang, R. Liu, P.K. Chu. Appl. Catal. B-Environ. 2021, 297, 120461. doi: 10.1016/j.apcatb.2021.120461
28	A. Mitra, M. Mallik, S. Sengupta, S. Banthia, K. Das, S. Das. Cryst. Growth Des. 2017, 17, 1539. doi: 10.1021/acs.cgd.6b01420
29	M.A. Habib, S. Lin, M.H. Joni, S.A. Dristy, R. Mandavkar, J.-H. Jeong, J. Lee. J. Energy Chem. 2025, 100, 397. doi: 10.1016/j.jechem.2024.08.060
30	M. Batool, A. Hameed, M.A. Nadeem. Coord. Chem. Rev. 2023, 480, 215029. doi: 10.1016/j.ccr.2023.215029
31	Y. Hong, J. Choi, E. Lee, Y.J. Hwang. Nanoscale 2024, 16, 11564. doi: 10.1039/D4NR01186D
32	H. Pan, R. Hao, L. Wang, Y. Yu, N. Yang. ChemSusChem 2024, 18, e202400900. doi: 10.1002/cssc.202400900
33	Y. Wei, X. Wang, M. Sun, M. Ma, J. Tian, M. Shao. ENERGY Environ. Mater. 2024, 7, e12630. doi: 10.1002/eem2.12630
34	J. Cao, Z. Jiao, R. Zhu, H. Long, Y. Zheng, J. Pan, J. Wang, F. Luo, C. Li, Q. Wei. J. Alloys Compd. 2022, 914, 165362. doi: 10.1016/j.jallcom.2022.165362
35	S.-Y. Lu, L. Wang, C. Wu, J. Zhang, W. Dou, T. Hu, R. Wang, Y. Liu, Q. Yang, H. Yi. ACS Sustain. Chem. Eng. 2024, 12, 6376. doi: 10.1021/acssuschemeng.4c00479
36	R. Mandavkar, M.A. Habib, S. Lin, R. Kulkarni, S. Burse, J.-H. Jeong, J. Lee. Appl. Mater. Today 2022, 29, 101579. doi: 10.1016/j.apmt.2022.101579
37	D. Briggs, Handb. Adhes, second ed., 2005, p. 621, https://doi.org/10.1002/0470014229.ch22.
38	D. Rathore, A. Banerjee, S. Pande. ACS Appl. Nano Mater. 2022, 5, 2664. doi: 10.1021/acsanm.1c04359
39	G. Fu, X. Kang, Y. Zhang, X. Yang, L. Wang, X.-Z. Fu, J. Zhang, J.-L. Luo, J. Liu. Nano-Micro Lett. 2022, 14, 200. doi: 10.1007/s40820-022-00940-3
40	P. Krishnamurthy, T. Maiyalagan, G. Panomsuwan, Z. Jiang, M. Rahaman. Catalysts 2023, 13, 1095. doi: 10.3390/catal13071095
41	H. Li, Y. Wang, C. Liu, S. Zhang, H. Zhang, Z. Zhu. Int. J. Hydrogen Energy 2022, 47, 20718. doi: 10.1016/j.ijhydene.2022.04.200
42	M.A. Ashraf, Y. Yang, D. Zhang, B.T. Pham. J. Colloid Interface Sci. 2020, 577, 265. doi: 10.1016/j.jcis.2020.05.060
43	C.M. Coaty, A.A. Corrao, V. Petrova, P.G. Khalifah, P. Liu. J. Phys. Chem. C 2019, 123, 17873. doi: 10.1021/acs.jpcc.9b04172
44	[M.A. Habib, S. Burse, S. Lin, R. Mandavkar, M.H. Joni, J. Jeong, S. Lee, J. Lee, Small (2023) 2307533, https://doi.org/10.1002/smll.202307533.
45	C. Prakash, P. Sahoo, R. Yadav, A. Pandey, V.K. Singh, A. Dixit. Int. J. Hydrogen Energy 2023, 48, 21969. doi: 10.1016/j.ijhydene.2023.03.093
46	L. Jiang, R. Wang, Z. Xiang, X. Wang. Int. J. Hydrogen Energy 2024, 51, 898. doi: 10.1016/j.ijhydene.2023.10.238
47	S. Burse, R. Kulkarni, R. Mandavkar, M.A. Habib, S. Lin, Y.-U. Chung, J.-H. Jeong, J. Lee. Nanomaterials 2022, 12, 3283. doi: 10.3390/nano12193283
48	L. Quan, H. Jiang, G. Mei, Y. Sun, B. You. Chem. Rev. 2024, 124, 3694. doi: 10.1021/acs.chemrev.3c00332
49	J. Jayabharathi, B. Karthikeyan, B. Vishnu, S. Sriram. Phys. Chem. Chem. Phys. 2023, 25, 8992. doi: 10.1039/D2CP05522H
50	S.Y. Lim, S. Park, S.W. Im, H. Ha, H. Seo, K.T. Nam. ACS Catal. 2020, 10, 235. doi: 10.1021/acscatal.9b03544
51	M.A. Habib, R. Mandavkar, S. Burse, S. Lin, R. Kulkarni, C.S. Patil, J.H. Jeong, J. Lee. Mater. Today Energy 2022, 26, 101021. doi: 10.1016/j.mtener.2022.101021
52	T. Zhao, B. Gong, G. Xu, J. Jiang, L. Zhang. Chinese J. Catal. 2024, 61, 269. doi: 10.1016/S1872-2067(24)60037-9
53	R. Srivastava, H. Chaudhary, A. Kumar, F.M. de Souza, S.R. Mishra, F. Perez, R.K. Gupta. Discov. Nano 2023, 18, 148. doi: 10.1186/s11671-023-03937-y
54	H. Liu, X. Li, L. Chen, X. Zhu, P. Dong, M.O.L. Chee, M. Ye, Y. Guo, J. Shen. Adv. Funct. Mater. 2022, 32, 1. doi: 10.1002/adfm.202107308
55	B. Han, X. Du, J. Li, H. Wang, G. Liu, J. Li. Appl. Surf. Sci. 2022, 604 doi: 10.1016/j.apsusc.2022.154617
56	S. Lin, M.A. Habib, R. Mandavkar, R. Kulkarni, S. Burse, Y.-U. Chung, C. Liu, Z. Wang, S. Lin, J.-H. Jeong, J. Lee. Adv. Sustain. Syst. 2022, 6, 2200213. doi: 10.1002/adsu.202200213
57	E. Hu, Y. Feng, J. Nai, D. Zhao, Y. Hu, X.W.D. Lou. Sci. 2018, 11, 872. doi: 10.1039/C8EE00076J
58	Y. Qi, Q. Zhang, S. Meng, D. Li, W. Wei, D. Jiang, M. Chen. lectrochim. Acta 2020, 334 doi: 10.1016/j.electacta.2020.135633
59	P. Zhou, X. Lv, D. Xing, F. Ma, Y. Liu, Z. Wang, P. Wang, Z. Zheng, Y. Dai, B. Huang. Appl. Catal. B-Environ. 2020, 263, 118330. doi: 10.1016/j.apcatb.2019.118330
60	E. Hatami, A. Toghraei, G. Barati Darband. Int. J. Hydrogen Energy 2021, 46, 9394. doi: 10.1016/j.ijhydene.2020.12.110
61	Y. Liu, J. Cao, Y. Chen, M. Wei, X. Liu, X. Li, Q. Wu, B. Feng, Y. Zhang, L. Yang. CrystEngComm 2022, 24, 1704. doi: 10.1039/d1ce01555a
62	S. Chen, H. Huang, P. Jiang, K. Yang, J. Diao, S. Gong, S. Liu, M. Huang, H. Wang, Q. Chen. ACS Catal. 2020, 10, 1152. doi: 10.1021/acscatal.9b04922
63	Q. Ma, R. Dong, H. Liu, A. Zhu, L. Qiao, Y. Ma, J. Wang, J. Xie, J. Pan. J. Alloys Compd. 2020, 820, 153438. doi: 10.1016/j.jallcom.2019.153438
64	Y. Teng, X.D. Wang, J.F. Liao, W.G. Li, H.Y. Chen, Y.J. Dong, D. Bin Kuang. Adv. Funct. Mater. 2018, 28 doi: 10.1002/adfm.201802463
65	D. Wang, L. Gu, X. Luo, R. Su, Y. Shang, Y. Wang, S. Hao, Y. Yang. J. Electroanal. Chem. 2022, 924, 116875. doi: 10.1016/j.jelechem.2022.116875
66	X. Lin, J. Xu, Z. Peng. Sustain. Times 2024, 3, 100023. doi: 10.1016/j.nxsust.2023.100023
67	Y. Hao, X. Cao, C. Lei, Z. Chen, X. Yang, M. Gong. Mater. Today Catal 2023, 2, 100012. doi: 10.1016/j.mtcata.2023.100012
68	C. Linder, S.G. Rao, R.D. Boyd, A. le Febvrier, P. Eklund, S. Munktell, E.M. Björk. ACS Appl. Energy Mater. 2022, 5, 10838. doi: 10.1021/acsaem.2c01499
69	W. Zhang, M. Liu, X. Gu, Y. Shi, Z. Deng, N. Cai. Chem. Rev. 2023, 123, 7119. doi: 10.1021/acs.chemrev.2c00573
70	P. Zhai, M. Xia, Y. Wu, G. Zhang, J. Gao, B. Zhang, S. Cao, Y. Zhang, Z. Li, Z. Fan, C. Wang, X. Zhang, J.T. Miller, L. Sun, J. Hou. Nat. Commun. 2021, 12, 1. doi: 10.1038/s41467-021-24828-9
71	L. Ye, Y. Zhang, B. Guo, D. Cao, Y. Gong. Dalt. Trans. 2021, 50, 13951. doi: 10.1039/d1dt02341a
72	Q.-N. Ha, N. Susanto Gultom, C.-H. Yeh, D.-H. Kuo. Chem. Eng. J. 2023, 472, 144931. doi: 10.1016/j.cej.2023.144931
73	C. Guan, W. Xiao, H. Wu, X. Liu, W. Zang, H. Zhang, J. Ding, Y.P. Feng, S.J. Pennycook, J. Wang. Nano Energy 2018, 48, 73. doi: 10.1016/j.nanoen.2018.03.034
74	Q. Che, N. Bai, Q. Li, X. Chen, Y. Tan, X. Xu. Nanoscale 2018, 10, 15238. doi: 10.1039/c8nr03944e
75	G. Ren, Q. Hao, J. Mao, L. Liang, H. Liu, C. Liu, J. Zhang. Nanoscale 2018, 10, 17347. doi: 10.1039/C8NR05494K
76	X. Cheng, Z. Pan, C. Lei, Y. Jin, B. Yang, Z. Li, X. Zhang, L. Lei, C. Yuan, Y. Hou. J. Mater. Chem. A 2019, 7, 965. doi: 10.1039/c8ta11223a
77	Y. Dong, Z. Deng, H. Zhang, G. Liu, X. Wang. Nano Lett. 2023, 23, 9087. doi: 10.1021/acs.nanolett.3c02940
78	X. Li, T. Wu, N. Li, S. Zhang, W. Chang, J. Chi, X. Liu, L. Wang. Adv. Funct. Mater. 2024, 34, 2400734. doi: 10.1002/adfm.202400734
79	J. Chen, L. Zhang, J. Li, X. He, Y. Zheng, S. Sun, X. Fang, D. Zheng, Y. Luo, Y. Wang, J. Zhang, L. Xie, Z. Cai, Y. Sun, A.A. Alshehri, Q. Kong, C. Tang, X. Sun. J. Mater. Chem. A 2023, 11, 1116. doi: 10.1039/D2TA08568B
80	Y. Hu, H. Yu, L. Qi, J. Dong, P. Yan, T.T. Isimjan, X. Yang. ChemSusChem 2021, 14, 1565. doi: 10.1002/cssc.202002873
81	H. Sun, C. Tian, G. Fan, J. Qi, Z. Liu, Z. Yan, F. Cheng, J. Chen, C.-P. Li, M. Du. Adv. Funct. Mater. 2020, 30, 1910596. doi: 10.1002/adfm.201910596
82	Y. Liu, X. Gu, W. Jiang, H. Li, Y. Ma, C. Liu, Y. Wu, G. Che. Dalt. Trans. 2022, 51, 9486. doi: 10.1039/D2DT01098D
83	H. Mao, X. Liu, S. Wu, G. Sun, G. Zhou, J. Chi, L. Wang. Adv. Energy Mater. 2023, 13, 2302251. doi: 10.1002/aenm.202302251
84	M. Ning, F. Zhang, L. Wu, X. Xing, D. Wang, S. Song, Q. Zhou, L. Yu, J. Bao, S. Chen. Energy Environ. Sci. 2022, 15, 3945. doi: 10.1039/D2EE01094A
85	X. Hou, C. Yu, T. Ni, S. Zhang, J. Zhou, S. Dai, L. Chu, M. Huang. Chinese J. Catal. 2024, 61, 192. doi: 10.1016/S1872-2067(24)60030-6
86	Q. Lv, J. Han, X. Tan, W. Wang, L. Cao, B. Dong. ACS Appl. Energy Mater. 2019, 2, 3910. doi: 10.1021/acsaem.9b00599
87	X. Luo, X. Tan, P. Ji, L. Chen, J. Yu, S. Mu. EnergyChem 2023, 5, 100091. doi: 10.1016/j.enchem.2022.100091

Electrocatalyst	Overpotential (mV)		Reference
Electrocatalyst	At 100 mA∙cm⁻²	At 300 mA∙cm⁻²	Reference
V/FeBP	94	185	[47]
Zn/NiBP	95	233	Our Work
Ni-Mo-B	95	200	[54]
W₃CoB₃	120	N/A	[51]
Cu-NiP_x/NiSe_y	163	N/A	[55]
NiMoB	170	255	[36]
CoMnB	175	210	[56]
Ni-Co-P	190	N/A	[57]
NC_0.9F_0.1P	198	N/A	[58]
V-Ni_0.2Mo_0.8N	220	N/A	[59]
Ni–Fe	243	N/A	[60]
Fe-NiSe	345	N/A	[61]

Electrocatalyst	Overpotential (mV)		Reference
Electrocatalyst	At 100 mA∙cm⁻²	At 300 mA∙cm⁻²	Reference
Cu-NiP_x/NiSe_y	230	340	[55]
V/FeBP	258	342	[47]
Mn-RuO₂	260	N/A	[62]
Zn/NiBP	280	360	Our Work
MFO-TS-30	285	N/A	[63]
W₃CoB₃	295	N/A	[51]
Ni-Co-P	350	N/A	[57]
CoMnB	380	470	[56]
NiMoB	380	490	[36]
Fe-Mn-O NS/CC	390	N/A	[64]
NC_0.9F_0.1P	450	N/A	[58]
Ru/Ni-Co-P	450	N/A	[65]

Electrocatalyst	Potential (V)		Reference
Electrocatalyst	At 100 mA∙cm⁻²	At 300 mA∙cm⁻²	Reference
V/FeBP	1.55	1.72	[47]
Ru/NiFe	1.56	1.65	[70]
W₃CoB₃	1.62	N/A	[51]
Zn/NiBP	1.63	1.82	Our Work
Ru/Fe₃O₄	1.69	1.78	[71]
Li-V/Ni₃S₂	1.70	1.77	[72]
CoMnB	1.72	1.85	[56]
NiMoB	1.76	2.18	[36]
Ru/MoO₂	1.88	N/A	[73]
(Ni-Fe)S_x/(OH)_y	1.88	N/A	[74]
Ni₃S₂	1.89	N/A	[75]
Fe₂O₃@Ni₂P/Ni(PO₃)₂	1.97	2.3	[76]

Electrocatalyst	Potential (V)		Reference
Electrocatalyst	At 500 mA∙cm⁻²	At 1, 000 mA∙cm⁻²	Reference
MnO-CoP/NF	1.77	N/A	[77]
Ru-Ni₂P/Fe₂P	1.81	N/A	[78]
NiFeS/NF	1.82	N/A	[79]
P-MoS₂/CoP	1.94	2.10	[80]
Zn/NiBP	1.98	2.36	Our Work
Co₄N-CeO₂	1.99	2.28	[81]
MoO_x/Fe₁₋xS/IF	1.99	N/A	[82]
CoMnB	2.20	2.50	[56]

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Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting

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