水热法制备NiS/Cd1-xZnxS及其高效光催化产氢性能

doi:10.3866/PKU.WHXB201411175

Abstract

Abstract:

NiS-modified Cd_1-xZn_xS has been prepared using a simple hydrothermal method. Notably, the H₂ evolution rate of 0.5% (y, molar fraction) NiS/Cd_0.3Zn_0.7S(1840 μmol·h^-1) was found to be 2.1- and 1.3-fold greater than those of Cd_0.3Zn_0.7S(884 μmol·h^-1) and 0.5% (w, mass fraction) Pt (1390 μmol·h^-1), respectively, when 0.35 mol·L^-1 Na₂SO₃ and 0.25 mol·L^-1 Na₂Swere used as sacrificial agents. The apparent quantumefficiency of 0.5% (y) NiS/Cd_0.3Zn_0.7S at 420 nm was 36.8%. The characterization of this material by X-ray diffraction (XRD), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) showed that the NiS particles provided the active sites required for H₂ evolution and transferring the photo generated electrons, and therefore enhanced the photocatalytic activity of the catalyst towards H₂ production.

Key words: Cd_1-xZn_xS, NiS, Hydrothermal method, Photocatalytic activity, Hydrogen production

LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng. Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution[J]. Acta Phys. -Chim. Sin. 2015, 31(1), 153-158. doi: 10.3866/PKU.WHXB201411175

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Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution

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Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution