单体摩尔比对共聚物电化学及电致变色性质的影响

doi:10.3866/PKU.WHXB201601047

Abstract

Abstract:

Copolymers were prepared by electropolymerization using different feed ratios of 6-(3, 6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate (BTC-H-Fc) and 3, 4-ethoxylenedioxythiophene (EDOT). The structure and performance of copolymers were characterized by electrochemical measurements, Fourier transform infrared (FT-IR) spectroscopy, and spectroelectrochemistry. The results showed that all the copolymers could exhibit desirable electrochemical features. Spectroelectrochemical studies indicated that P(BTC-H-Fc: EDOT)-1 was light green at the neutral state, and changed to green and then purple with increasing applied potential. P(BTC-H-Fc:EDOT)-4 possessed outstanding color-changing ability; its colors included chocolate brown, yellow brown, green, blue, and purple. P(BTC-H-Fc:EDOT)-8 could be chocolate brown, gray black, blue green, and sky blue. All the copolymer films possessed favorable optical contrast, switching time, and coloration efficiency, laying the foundation for their potential applications in electrochromic device.

Key words: Conjugated polymer, Electrochromism, Ferrocene, Electropolymerization, Coloration efficiency

Bin HU,Pei WANG,Xiao-Jing Lü,Ping-Jing WANG,Yu-Yu DAI,Mi OUYANG. Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers[J]. Acta Phys. -Chim. Sin. 2016, 32(4), 961-968. doi: 10.3866/PKU.WHXB201601047

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Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers

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