介孔氮化碳材料合成的研究进展

doi:10.3866/PKU.WHXB201605052

Abstract

Abstract:

Graphitic carbon nitride (g-C₃N₄) is a new metal-free material. Owing to its multiple unique physicochemical properties, g-C₃N₄ has promising applications in various research fields, including heterogeneous catalysis, photocatalysis, fuel cells, and gas storage. Compared with bulk g-C₃N₄ prepared via direct thermal condensation, mesoporous g-C₃N₄ possesses a higher surface area and abundant accessible mesoporous pores. These features expose many more surface active sites, thereby improving the performance of this material in catalysis as well as in other applications. Thermal condensation is the most convenient strategy to prepare g-C₃N₄ and, when fabricating mesoporous g-C₃N₄, one may employ hard-, soft-, or non-templating method. This paper reviews recent advances in the synthesis of mesoporous g-C₃N₄ using all three routes. Specifically, several crucial issues regarding the hard-templating method are discussed with regard to the synthetic mechanism associated with various precursors and the physicochemical properties of the g-C₃N₄ products. Novel soft- and non-templating approaches for the preparation of mesoporous g-C₃N₄ are also addressed and a detailed comparison to the hard-templating method is provided. Finally, future prospects for the development of mesoporous g-C₃N₄ materials are also assessed.

Key words: Graphitic carbon nitride, Mesoporous material, Nanocasting method, Hard-templating method, Soft-templating method

Yue WANG,Quan JIANG,Jie-Kun SHANG,Jie XU,Yong-Xin LI. Advances in the Synthesis of Mesoporous Carbon Nitride Materials[J]. Acta Phys. -Chim. Sin. 2016, 32(8), 1913-1928. doi: 10.3866/PKU.WHXB201605052

References

1	Schreiner P. R. Chem. Soc. Rev. 2003, 32, 289.
2	Su D. S. ; Zhang J. ; Frank B. ; Thomas A. ; Wang X. ; Paraknowitsch J. ; Schl?gl R. ChemSusChem 2010, 3, 169.
3	Lotsch B. V. ; Schnick W. Chem.-Eur. J. 2007, 13, 4956.
4	Zhang Y. ; Mori T. ; Ye J. Sci. Adv. Mater. 2012, 4, 282.
5	Thomas A. ; Fischer A. ; Goettmann F. ; Antonietti M. ; Müller J. O. ; Schl?gl R. ; Carlsson J. M. J. Mater. Chem. 2008, 18, 4893.
6	Liu A. ; Cohen M. Phys. Rev. B 1985, 41, 10727.
7	Teter D. M. ; Hemley R. J. Science 1996, 271, 53.
8	Kroke E. ; Schwarz M. Coord. Chem. Rev. 2004, 248, 493.
9	Zhang J. S. ; Wang B. ; Wang X. C. Acta Phys.-Chim. Sin. 2013, 29, 1865.
9	张金水; 王博; 王心晨. 物理化学学报, 2013, 29, 1865.
10	Goettmann F. ; Fischer A. ; Antonietti M. ; Thomas A. Angew. Chem. Int. Edit. 2006, 45, 4467.
11	Ansari M. B. ; Min B. H. ; Mo Y. H. ; Park S. E. Green Chem. 2011, 13, 1416.
12	Zhu J. ; Wei Y. ; Chen W. ; Zhao Z. ; Thomas A. Chem. Commun. 2010, 46, 6965.
13	Xu J. ; Long K. Z. ; Wang Y. ; Xue B. ; Li Y. X. Appl. Catal. A 2015, 496, 1.
14	Gong Y. ; Li M. ; Li H. ; Wang Y. Green Chem. 2015, 17, 715.
15	Wang X. ; Maeda K. ; Thomas A. ; Takanabe K. Nat. Mater. 2009, 8, 76.
16	Su F. ; Mathew S. C. ; Lipner G. ; Fu X. ; Antonietti M. ; Blechert S. ; Wang X. J. Am. Chem. Soc. 2010, 132, 16299.
17	Cao S. ; Low J. ; Yu J. ; Jaroniec M. Adv. Mater. 2015, 27, 2150.
18	Cao S. ; Yu J. J. Phys. Chem. Lett. 2014, 5, 2101.
19	Bai X. ; Yan S. ; Wang J. ; Wang L. ; Jiang W. ; Wu S. ; Sun C. ; Zhu Y. J. Mater. Chem. A 2014, 2, 17521.
20	Yin S. ; Han J. ; Zhou T. ; Xu R. Catal. Sci. Technol. 2015, 5, 5048.
21	Zheng Y. ; Liu J. ; Liang J. ; Jaroniec M. ; Qiao S. Z. Energy Environ. Sci. 2012, 5, 6717.
22	Kim M. ; Hwang S. ; Yu J. S. J. Mater. Chem. 2007, 17, 1656.
23	Park S. S. ; Chu S.W. ; Xue C. ; Zhao D. ; Ha C. S. J. Mater. Chem. 2011, 21, 108017.
24	Koh G. ; Zhang Y.W. ; Pan H. Int. J. Hydrog. Energy 2012, 37, 4170.
25	Wang Y. ; Wang X. ; Antonietti M. Angew. Chem. Int. Edit. 2012, 51, 68.
26	Chu Z. Y. ; Yuan B. ; Yan T. N. J. Inorg. Mater. 2014, 29, 785.
27	Li Q. ; Yang J. ; Feng D. ; Wu Z. ; Wu Q. ; Park S. S. ; Ha C. S. ; Zhao D. Nano Res. 2010, 3, 632.
28	Xu J. ; Wu H. T. ; Wang X. ; Xue B. ; Li Y. X. ; Cao Y. Phys. Chem. Chem. Phys. 2013, 15, 4510.
29	Lu A. H. ; Schüth F. Adv. Mater. 2006, 18, 1793.
30	Tiemann M. Chem. Mater. 2007, 20, 961.
31	Yang H. ; Zhao D. J. Mater. Chem. 2005, 15, 1217.
32	Schüth F. Angew. Chem. Int. Edit. 2003, 42, 3604.
33	Groenewolt M. ; Antonietti M. Adv. Mater. 2005, 17, 1789.
34	Fischer, A."Reactive Hard Templating": from Carbon Nitridesto Metal Nitrides. Ph. D. Dissertation, Max Planck Institute ofColloids and Interfaces: Potsdam, 2008.
35	Chen X. ; Jun Y. S. ; Takanabe K. ; Maeda K. ; Domen K. ; Fu X. ; Antonietti M. ; Wang X. Chem. Mater. 2009, 21, 4093.
36	Lee E. Z. ; Jun Y. S. ; Hong W. H. ; Thomas A. ; Jin M. M. Angew. Chem. Int. Edit. 2010, 49, 9706.
37	Wehrstedt K. D. ; Wildner W. ; Güthner T. ; Holzrichter K. ; Mertschenk B. ; Ulrich A. J. Hazard. Mater. 2009, 170, 829.
38	Jürgens B. ; Irran E. ; Senker J. ; Kroll P. ; Müller H. ; Schnick W. J. Am. Chem. Soc. 2003, 125, 10288.
39	Ansari M. B. ; Jin H. ; Parvin M. N. ; Park S. E. Catal. Today 2012, 185, 211.
40	Wang Y. ; Wang F. ; Zuo Y. ; Zhang X. ; Cui L. F. Mater. Lett. 2014, 136, 271.
41	Xu J. ; Chen T. ; Jiang Q. ; Li Y. X. Chem.-Asian J. 2014, 9, 3269.
42	Tian C. ; Lu C. ; Wang B. ; Xie X. ; Miao Y. ; Li X. RSC Adv. 2015, 5, 103829.
43	Schaber P. M. ; Colson J. ; Higgins S. ; Thielen D. ; Anspach B. ; Brauer J. Thermochim. Acta 2004, 424, 131.
44	Liu J. ; Zhang T. ; Wang Z. ; Dawson G. ; Chen W. J. Mater. Chem. 2011, 21, 14398.
45	Zhang G. ; Zhang J. ; Zhang M. ; Wang X. J. Mater. Chem. 2012, 22, 8083.
46	Su Q. ; Sun J. ; Wang J. ; Yang Z. ; Cheng W. ; Zhang S. Catal. Sci. Technol. 2014, 4, 1556.
47	Lee S. C. ; Lintang H. O. ; Yuliati L. Chem.-Asian J. 2012, 7, 2139.
48	Lotsch B. V. ; Schnick W. New J. Chem. 2004, 28, 1129.
49	Long B. ; Lin J. ; Wang X. J. Mater. Chem. A 2014, 2, 2942.
50	Zhu J. ; Xiao P. ; Li H. ; Carabineiro S. A. C. ACS Appl. Mater. Inter. 2014, 6, 16449.
51	Qiu Y. ; Gao L. Chem. Commun. 2003, 2378
52	Vinu A. ; Ariga K. ; Mori T. ; Nakanishi T. ; Hishita S. ; Golberg D. ; Bando Y. Adv. Mater. 2005, 17, 1648.
53	Vinu A. Adv. Funct. Mater. 2008, 18, 816.
54	Vinu A. ; Srinivasu P. ; Sawant D. P. ; Mori T. ; Ariga K. ; Chang J. S. ; Jhung S. H. ; Balasubramanian V. V. ; Hwang Y. K. Chem. Mater. 2007, 19, 4367.
55	Jin X. ; Balasubramanian V. V. ; Selvan S. T. ; Sawant D. P. ; Chari M. A. ; Lu G. Q. ; Vinu A. Angew. Chem. Int. Edit. 2009, 48, 7884.
56	Talapaneni S. N. ; Anandan S. ; Mane G. P. ; Anand C. ; Dhawale D. S. ; Varghese S. ; Mano A. ; Mori T. ; Vinu A. J. Mater. Chem. 2012, 22, 9831.
57	Xu J. ; Long K. Z. ; Chen T. ; Xue B. ; Li Y. X. ; Cao Y. Catal. Sci. Technol. 2013, 3, 3192.
58	Xu J. ; Wu F. ; Wu H. T. ; Xue B. ; Li Y. X. ; Cao Y. Microporous Mesoporous Mat. 2014, 198, 223.
59	Xu J. ; Shen K. ; Xue B. ; Li Y. X. ; Cao Y. Catal. Lett. 2013, 143, 600.
60	Xu J. ; Shen K. ; Xue B. ; Li Y. X. J. Mol. Catal. A 2013, 372, 105.
61	Thrower P. A. Carbon 2004, 42, 2367.
62	Xu J. ; Chen T. ; Wang X. ; Xue B. ; Li Y. X. Catal. Sci. Technol. 2014, 4, 2126.
63	Ryoo R. ; Joo S. H. ; Jun S. J. Phys. Chem. B 1999, 103, 7743.
64	Shen W. ; Dong X. ; Zhu Y. ; Chen H. ; Shi J. Microporous Mesoporous Mat. 2005, 85, 157.
65	Shi Y. ; Wan Y. ; Zhang R. ; Zhao D. Adv. Funct. Mater. 2008, 18, 2436.
66	Zhang J. ; Guo F. ; Wang X. Adv. Funct. Mater. 2013, 23, 3008.
67	Borchardt L. ; Kockrick E. ; Wollmann P. ; Kaskel S. ; Guron M. M. ; Sneddon L. G. ; Geiger D. Chem. Mater. 2010, 22, 4660.
68	Bojdys M. J. ; Müller J. O. ; Antonietti M. ; Thomas A. Chem.-Eur. J. 2008, 14, 8177.
69	Su F. ; Antonietti M. ; Wang X. Catal. Sci. Technol. 2012, 2, 1005.
70	Xu J. ; Wu F. ; Jiang Q. ; Li Y. X. Catal. Sci. Technol. 2015, 5, 447.
71	Zhang Y. ; Thomas A. ; Antonietti M. J. Am. Chem. Soc. 2008, 131, 50.
72	Xu J. ; Wang Y. ; Shang J. K. ; Jiang Q. ; Li Y. X. Catal. Sci. Technol. 2016, 6, 4192.
73	Yan H. Chem. Commun. 2012, 48, 3430.
74	Wang Y. ; Wang X. ; Antonietti M. ; Zhang Y. ChemSusChem 2010, 3, 435.
75	Zhao D. ; Feng J. ; Huo Q. ; Melosh N. ; Fredrickson G. H. ; Chmelka B. F. ; Stucky G. D. Science 1998, 279, 548.
76	Wei J. ; Zhou D. ; Sun Z. ; Deng Y. ; Xia Y. ; Zhao D. Adv. Funct. Mater. 2013, 23, 2322.
77	Li H. ; Wang L. ; Liu Y. ; Lei J. ; Zhang J. Res. Chem. Intermed. 2016, 42, 3979.
78	Min S. ; Lu G. J. Phys. Chem. C 2012, 116, 19644.
79	Han K. K. ; Wang C. C. ; Li Y. Y. ; Wan M. M. ; Wang Y. ; Zhu J. H. RSC Adv. 2013, 3, 9465.
80	Ding J. ; Liu Q. ; Zhang Z. ; Liu X. ; Zhao J. ; Cheng S. ; Zong B. ; Dai W. L. Appl. Catal. B 2015, 165, 511.
81	Zhang X. ; Xie X. ; Wang H. ; Zhang J. ; Pan B. ; Xie Y. J. Am. Chem. Soc. 2012, 135, 18.
82	Xu J. ; Zhang L. ; Shi R. ; Zhu Y. J. Mater. Chem. A 2013, 1, 14766.
83	Lu X. ; Xu K. ; Chen P. ; Jia K. ; Liu S. ; Wu C. J. Mater. Chem. A 2014, 2, 18924.
84	Dong F. ; Li Y. ; Wang Z. ; Ho W. K. Appl. Sur. Sci. 2015, 358, 393.
85	Niu P. ; Zhang L. ; Liu G. ; Cheng H. M. Adv. Funct. Mater. 2012, 22, 4763.
86	Dong X. ; Cheng F. J. Mater. Chem. A 2015, 3, 23642.
87	Kumar S. ; Surendar T. ; Kumar B. ; Baruah A. ; Shanker V. RSC Adv. 2014, 4, 8132.

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Advances in the Synthesis of Mesoporous Carbon Nitride Materials

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