水热法制备Fe3O4/rGO纳米复合物作为锂离子电池阳极材料

doi:10.3866/PKU.WHXB201609072

Abstract

Abstract:

Fe₃O₄/rGO nanocomposites were prepared by hydrothermal method using Fe(OH)3 as precursor of magnetite nanoparticles, graphene oxide (GO) as precursor of reduced graphene oxide (rGO), hydrazine and trisodium citrate as mixed reducing agent. The morphologies, structures and compositions of the products were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The electrochemical characteristics of assembled coin-type cells versus metallic lithium were evaluated by cyclic voltammetry and galvanostatic charge-discharge. The uniform morphology, high reductive level of rGO and the role of rGO buffering the volume changes of Fe₃O₄ nanoparticles in the charging-discharging process can be responsible for the good electrochemical performance of Fe₃O₄/rGO nanocomposites.

Key words: Lithium ion battery, Nanocomposite, Magnetite, Graphene, Anode material

Shou-Pu ZHU,Tian WU,Hai-Ming SU,Shan-Shan QU,Yong-Juan XIE,Ming CHEN,Guo-Wang DIAO. Hydrothermal Synthesis of Fe₃O₄/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin. 2016, 32(11), 2737-2744. doi: 10.3866/PKU.WHXB201609072

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Hydrothermal Synthesis of Fe₃O₄/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries

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