氮掺杂石墨烯气凝胶锚定RuP纳米粒子用于水合肼氧化辅助产氢

doi:10.3866/PKU.WHXB202303028

Abstract

Abstract:

'Green hydrogen' is a promising clean energy carrier for use instead of traditional fuels. For obtaining 'green hydrogen', electrochemical water splitting has been receiving considerable attention due to its eco-friendly and low-cost properties. However, the sluggish kinetics of the anodic oxygen evolution reaction (OER) reduces the efficiency of hydrogen production. Accordingly, the hydrazine oxidation reaction (HzOR) with low theoretical potential (−0.33 V vs. RHE) has been proposed as a reasonable alternative for the OER. In this study, graphene aerogel (GA) was utilized as a conductive substrate with a 3D porous framework. Ru^Ⅲ-polyethyleneimine (Ru^Ⅲ-PEI) complexes were adsorbed on the GA surface. Phytic acid (PA) was further adsorbed to form Ru^Ⅲ-PEI-GA-PA hybrids through the hydrogen bond interaction between PA and PEI, which can serve as a precursor to synthesize RuP nanoparticles anchored on N-doped GA (RuP/N-GA) through the phosphorization reaction. In the pyrolysis process, the ultra-small RuP was formed at the GA surface. Additionally, the decomposition of PEI and PA can introduce abundant N and P heteroatoms into the structure of GA. As a result, RuP/N-GA hybrids achieve efficient HzOR with a low working potential of −54 mV at 10 mA∙cm⁻². Moreover, the novel RuP/N-GA hybrids with low Ru loading also exhibit a promising hydrogen evolution reaction (HER) activity with an overpotential of −19.6 mV at 10 mA∙cm⁻². Among various RuP/N-GA hybrids, the Tafel plot of HER at RuP/N-GA-900 reveals the smallest value to be 37.03 mV∙dec⁻¹, which affords the fastest HER kinetics. Meanwhile, the result suggests that the HER at RuP/N-GA-900 undergoes a Heyrovsky mechanism similar to that of Pt. The theoretical results revealed that the anchored structure and the presence of N heteroatoms can promote the HzOR on RuP nanoparticles. The free energy of hydrazine molecular adsorption on RuP/N-GA was −0.68 eV, indicating that N-doping in the RuP/N-GA structure can adjust the electronic structure of the Ru active site, which also contributes to the enhanced HzOR activity of the Ru site. Additionally, RuP/N-GA hybrids exhibited excellent cycling and long-term stability for both HER and HzOR, superior to those of commercial Pt/C. Based on the bifunctional activity of RuP/N-GA hybrids, the constructed two-electrode hydrazine split system exhibits an extremely low cell voltage of 41 mV at 10 mA∙cm⁻² for the hydrogen production, which achieves the goal of energy-saved hydrogen production at low voltage. The excellent electrocatalytic activity of RuP/N-GA hybrids is attributed to the ultrasmall RuP nanoparticles for abundant Ru active sites. Meanwhile, the synergistic effect between N-doping in GA frameworks with RuP nanoparticles contributes to the activity enhancement of RuP/N-GA hybrids, in which the 3D porous N-GA with few-layer morphology accelerates the electron and mass transfer and the electron interaction between N-GA and RuP nanoparticles promotes the electrocatalytic activity of RuP nanoparticles for both HER and HzOR. This study extends the bifunctional electrocatalyst for the HER and HzOR to achieve energy-saved hydrogen production and sheds new light on the design and synthesis of advanced electrocatalysts via the adsorption-phosphatization method.

Key words: Ruthenium phosphide, Graphene aerogel, Anchored structure, Hydrazine oxidation reaction, Hydrogen evolution reaction

Zheng-Min Wang, Qing-Ling Hong, Xiao-Hui Wang, Hao Huang, Yu Chen, Shu-Ni Li. RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production[J]. Acta Phys. -Chim. Sin. 2023, 39(12), 2303028. doi: 10.3866/PKU.WHXB202303028

Figures/Tables 9

References 51

1	Gao Z. Q. ; Wang C. Y. ; Li J. J. ; Zhu Y. T. ; Zhang Z. C. ; Hu W. P. Acta Phys. -Chim. Sin. 2021, 37, 2010025.
	高增强; 王聪勇; 李俊俊; 朱亚廷; 张志成; 胡文平; 物理化学学报, 2021, 37, 2010025. doi: 10.3866/PKU.WHXB202010025
2	Wang T. J. ; Jiang Y. C. ; He J. W. ; Li F. M. ; Ding Y. ; Chen P. ; Chen Y. Carbon Energy 2022, 4, 283. doi: 10.1002/cey2.170
3	Hong Q. L. ; Miao B. Q. ; Wang T. J. ; Li F. M. ; Chen Y. Energy Lab. 2023, 1, 220022. doi: 10.54227/elab.20220022
4	Qin R. ; Wang P. Y. ; Lin C. ; Cao F. ; Zhang J. Y. ; Chen L. ; Mu S. C. Acta Phys. -Chim. Sin. 2021, 37, 2009099.
	秦睿; 王鹏彦; 林灿; 曹菲; 张金咏; 陈磊; 木士春; 物理化学学报, 2021, 37, 2009099. doi: 10.3866/PKU.WHXB202009099
5	Lei Z. N. ; Ma X. Y. ; Hu X. Y. ; Fan J. ; Liu E. Z. Acta Phys. -Chim. Sin. 2022, 38, 2110049.
	雷卓楠; 马心怡; 胡晓云; 樊君; 刘恩周; 物理化学学报, 2022, 38, 2110049. doi: 10.3866/PKU.WHXB202110049
6	Xue Q. ; Bai X. Y. ; Zhao Y. ; Li Y. N. ; Wang T. J. ; Li Y. N. ; Sun H. Y. ; Li F. M. ; Chen P. ; Jin P. J. ; Yin S. B. ; et al J. Energy Chem. 2022, 65, 94. doi: 10.1016/j.jechem.2021.05.034
7	Song W. ; Li M. ; Wang C. ; Lu X. Carbon Energy 2021, 3, 101. doi: 10.1002/cey2.85
8	Zhao T. W. ; Wang Y. ; Karuturi S. ; Catchpole K. ; Zhang Q. ; Zhao C. Carbon Energy 2020, 2, 582. doi: 10.1002/cey2.79
9	Liu Y. ; Li W. D. ; Wu H. ; Lu S. Y. Acta Phys. -Chim. Sin. 2021, 37, 2009082.
	刘源; 李卫东; 吴捍; 卢思宇; 物理化学学报, 2021, 37, 2009082. doi: 10.3866/PKU.WHXB202009082
10	Hu Q. ; Gao K. ; Wang X. ; Zheng H. J. ; Cao J. G. ; Mi L. R. ; Huo Q. H. ; Yang H. P. ; Liu J. H. ; He C. X. Nat. Commun. 2022, 13, 3958. doi: 10.1038/s41467-022-31660-2
11	Li C. ; Jang H. ; Kim M. G. ; Hou L. ; Liu X. ; Cho J. Appl. Catal. B 2022, 307, 121204. doi: 10.1016/j.apcatb.2022.121204
12	Ding Y. ; Cao K. W. ; He J. W. ; Li F. M. ; Huang H. ; Chen P. ; Chen Y. Chin. J. Catal. 2022, 43, 1535. doi: 10.1016/S1872-2067(21)63977-3
13	Zhang F. ; Zhu Y. L. ; Chen Y. ; Lu Y. ; Lin Q. ; Zhang L. ; Tao S. W. ; Zhang X. W. ; Wang H. T. J. Mater. Chem. A 2020, 8, 12810. doi: 10.1039/D0TA04491A
14	Chang Q. B. ; Ma J. W. ; Zhu Y. Z. ; Li Z. ; Xu D. Y. ; Duan X. Z. ; Peng W. C. ; Li Y. ; Zhang G.L. ; Zhang F. B. ACS Sustain. Chem. Eng. 2018, 6, 6388. doi: 10.1021/acssuschemeng.8b00187
15	Chi J. Q. ; Gao W. K. ; Lin J. H. ; Dong B. ; Yan K. L. ; Qin J. F. ; Liu Bin. ; Chai Y. M. ; Liu C.G. ChemSusChem 2018, 11, 743. doi: 10.1002/cssc.201702010
16	Guo L. ; Luo F. ; Guo F. ; Zhang Q. ; Qu K. ; Yang Z. H. ; Cai W. W. Chem. Commun. 2019, 55, 7623. doi: 10.1039/C9CC03675J
17	Li Y. ; Luo Y. ; Zhang Z. Q. ; Yu ; Li C. ; Zhang Q. ; Zheng Z. ; Liu H. K. ; Liu B. L. ; Dou S. X. Carbon 2021, 183, 362. doi: 10.1016/j.carbon.2021.07.039
18	Chen Y. J. ; Li J. ; Wang N. ; Zhou Y. N. ; Zheng J. ; Chu W. J. Energy Chem. 2022, 448, 137611. doi: 10.1016/j.cej.2022.137611
19	Zhu Y. ; Zhang J. ; Qian Q. ; Li Y. ; Li Z. ; Liu Y. ; Xiao C. ; Zhang G. Q. ; Xie Y. Angew. Chem. Int. Ed. 2022, 61, e202113082. doi: 10.1002/anie.202113082
20	Qian Q. Z. ; Zhang J. H. ; Li J. M. ; Li Y. P. ; Jin X. ; Zhu Y. ; Liu Y. ; Li Z. Y. ; El-Harairy A. ; Xiao C. ; Zhang G. Q. ; Xie Y. Angew. Chem. Int. Ed. 2021, 60, 5984. doi: 10.1002/anie.202014362
21	Wang Z. ; Xu L. ; Huang F. ; Qu L. ; Li J. ; Owusu K. A. ; Liu Z. A. ; Lin Z. F. ; Xiang B. H. ; Liu X. Adv. Energy Mater. 2019, 9, 1900390. doi: 10.1002/aenm.201900390
22	Liu Y. ; Zhang J. ; Li Y. ; Qian ; Li Q. Z. ; Zhu Y. ; Zhang G. Q. Nat. Commun. 2020, 11, 1853. doi: 10.1038/s41467-020-15563-8
23	Cui S. F. ; Wu W. ; Liu C. ; Wang Y. ; Chen Q. M. ; Liu X. R. Nanoscale 2021, 13, 18247. doi: 10.1039/D1NR04075H
24	Xue Q. ; Ding Y. ; Xue Y. Y. ; Li F. M. ; Chen P. ; Chen Y. Carbon 2018, 139, 137. doi: 10.1016/j.Carbon.2018.06.052
25	Wang Y. H. ; Li R. Q. ; Li H. B. ; Huang H. L. ; Guo Z. J. ; Chen H. Y. ; Zheng Y. ; Qu K. G. Rare Metals 2021, 40, 1040. doi: 10.1007/s12598-020-01665-1
26	Primo A. ; Neatu F. ; Florea M. ; Parvulescu V. ; Garcia H. Nat. Commun. 2014, 5, 5291. doi: 10.1038/ncomms6291
27	Ge R. ; Wang S. ; Su J. ; Dong Y. ; Lin Y. ; Zhang Q. ; Chen L. Nanoscale 2018, 10, 13930. doi: 10.1039/C8NR03554G
28	Li Y. ; Sun Y. ; Qin Y. ; Zhang W. ; Wang L. ; Luo M. H. ; Yang H. ; Guo S. Adv. Energy Mater. 2020, 10, 1903120. doi: 10.1002/aenm.201903120
29	Li Y. ; Chu F. ; Liu Y. ; Kong Y. ; Tao Y. ; Li Y. ; Qin Y. Chem. Commun. 2018, 54, 13076. doi: 10.1039/C8CC08276F
30	Kweon D. H. ; Okyay M. S. ; Kim S. J. ; Jeon J. P. ; Noh H. J. ; Park N. ; Mahmood J. ; Baek J. B. Nat. Commun. 2020, 11, 1278. doi: 10.1038/s41467-020-15069-3
31	Sun H. C. ; Yang J. M. ; Li J. G. ; Li Z. S. ; Ao X. ; Liu Y. Z. ; Zhang Y. ; Li Y. ; Wang C. ; Tang H. Appl. Catal. B 2020, 272, 118988. doi: 10.1016/j.apcatb.2020.118988
32	Zhao Y. M. ; Wang X. W. ; Cheng G. Z. ; Luo W. ACS Catal. 2020, 10, 11751. doi: 10.1021/acscatal.0c03148
33	Liu X. ; Liu F. ; Yu J. ; Xiong G. ; Zhao L. ; Sang Y. ; Zuo S. ; Zhang J. ; Liu H. ; Zhou W. Adv. Sci. 2020, 7, 2001526. doi: 10.1002/advs.202001526
34	Guo J. X. ; Yan D. Y. ; Qiu K. W. ; Mu C. ; Jiao D. ; Wang H. ; Lin T. J. Energy Chem. 2019, 37, 143. doi: 10.1016/j.jechem.2018.12.011
35	Xu J. ; Wang S. I. ; Yang C. L. ; Li T. T. ; Liu Q. C. ; Kong X. Chem. Eng. J. 2021, 421, 129741. doi: 10.1016/j.cej.2021.129741
36	Muthurasu A. ; Chhetri K. ; Dahal B. ; Kim H. Y. Nanoscale 2022, 14, 6557. doi: 10.1039/D2NR00060A
37	Yang Q. ; Zhu B. ; Wang F. ; Zhang C. ; Cai J. J. Nano Res. 2022, 15, 5134. doi: 10.1007/s12274-022-4148-2
38	Li J. ; Zhang C. ; Zhang C. ; Ma H. ; Yang Y. ; Guo Z. ; Wang Y. ; Ma H. Chem. Eng. J. 2022, 430, 132953. doi: 10.1016/j.cej.2021.132953
39	Wang J. ; Guan X. ; Li H. ; Zeng S. ; Li R. ; Yao Q. ; Chen H. ; Zheng Y. ; Qu K. Nano Energy 2022, 100, 107467. doi: 10.1016/j.nanoen.2022.107467
40	Li Y. ; Zhang J. ; Liu Y. ; Qian Q. ; Li Z. ; Zhu Y. ; Zhang G. Sci. Adv. 2020, 6, 131099. doi: 10.1126/sciadv.abb4197
41	Yang Q. F. ; Cui Y. C. ; Li Q. Y. ; Cai J. H. ; Wang D. ; Feng L. Chem. Eng. 2020, 8, 12089. doi: 10.1021/acssuschemeng.0c03410
42	Li Y. ; Wang W. ; Cheng M. ; Qian Q. ; Zhu Y. ; Zhang G. Catal. Sci. Technol. 2022, 12, 6258. doi: 10.1039/D2CY00055E
43	Wang H. ; Tao S. Nanoscale Adv. 2021, 3, 2280. doi: 10.1039/D1NA00043H
44	Zhou B. ; Li M. Y. ; Li Y. Y. ; Liu Y. B. ; Lu Y. X. ; Li W. ; Wu Y. J. ; Huo J. ; Wang Y. Y. ; Tao L. ; Wang S. Y. Chin. J. Catal. 2022, 43, 1131. doi: 10.1016/S1872-2067(21)63951-7
45	Ao Y. ; Chen S. ; Wang C. ; Lu X. J. Colloid Interface Sci. 2021, 601, 495. doi: 10.1016/j.jcis.2021.05.119
46	Chen S. ; Wang C. ; Liu S. ; Huang M. ; Lu J. J. Phys. Chem. Lett. 2021, 12, 4849. doi: 10.1021/acs.jpclett.1c00963
47	Zhang J. ; Liu Y. ; Li J. ; Jin X. ; Li Y. ; Qian Q. ; Wang Y. ; El-Harairy A. ; Li Z. ; Zhu Y. ; et al ACS Appl. Mater. Interfaces 2021, 13, 3881. doi: 10.1021/acsami.0c18684
48	Deng K. ; Mao Q. ; Wang W. ; Wang P. ; Wang Z. ; Xu Y. ; Li X. ; Wang H. J. ; Wang L. Appl. Catal. B 2022, 310, 121338. doi: 10.1016/j.apcatb.2022
49	Zhang M. ; Wang Z. ; Duan Z. ; Wang S. ; Xu Y. ; Li X. N. ; Wang L. ; Wang H. J. J. Mater. Chem. A 2021, 9, 18323. doi: 10.1039/D1TA05564J
50	Song Q. ; Li J. ; Wang S. ; Liu J. ; Liu X. ; Pang L. Y. ; Li H. ; Liu H. Small 2019, 15, e1903395. doi: 10.1002/smll.201903395
51	Zhou L. ; Shao M. ; Zhang C. ; Zhao J. ; He S. ; Rao D. ; Wei M. ; Evans D. G. ; Duan X. Adv. Mater. 2017, 29, 1604080. doi: 10.1002/adma.201604080

Electrocatalyst	Electrolyte	Overpotential/mV	Ref.
RuP/N-GA-900	1 mol∙L⁻¹ KOH	19.6	This work
RuP nanoparticles	1 mol∙L⁻¹ KOH	22	14
RuP_x nanoparticles in N, P-codoped carbon nanospheres	1 mol∙L⁻¹ KOH	74	15
RuP nanoparticles	1 mol∙L⁻¹ KOH	31	16
RuP₂ in N, P-codoped carbon	1 mol∙L⁻¹ KOH	52	17
Ru nanocrystal	1 mol∙L⁻¹ KOH	81	29
Ru nanoparticles on multi-walled carbon nanotubes	1 mol∙L⁻¹ KOH	17	30
NiTe nanoarrays with RuO₂	1 mol∙L⁻¹ KOH	19	31
P-doped Ru supported on XC-72 carbon	1 mol∙L⁻¹ KOH	31	32
S-doped RuP nanoparticles in N, P, and S-codoped carbon	1 mol∙L⁻¹ KOH	92	33
Ru/CoO hybrid	1 mol∙L⁻¹ KOH	55	34
RuBe nanosheets	1 mol∙L⁻¹ KOH	34.8	35
Ru MOF-assisted CoFe nanoarrays	1 mol∙L⁻¹ KOH	50	36
Ru nanoparticles on N-doped porous carbon nanosheets	1 mol∙L⁻¹ KOH	50	37

Catalyst	Electrolyte	Work potential/mV	Ref.
RuP/N-GA-900	1.0 mol∙L⁻¹ KOH + 0.4 mol∙L⁻¹ N₂H₄	−54	This work
Ru single atoms into WO₃	1.0 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ N₂H₄	−58	38
Ru nanoparticles on N-doped carbon	1.0 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ N₂H₄	−39	39
RuP₂ nanoparticles on carbon microsheets	1.0 mol∙L⁻¹ KOH + 0.3 mol∙L⁻¹ N₂H₄	−70	40
CoRuO_x in N-doped carbon shell	1.0 mol∙L⁻1 KOH + 0.5 mol∙L⁻¹ N₂H₄	−19	41
carbon-coated RuP₂ porous microsheets	1.0 mol∙L−1 KOH + 0.3 mol∙L⁻¹ N₂H₄	−36	42
NiFeP on nickel foam	1.0 mol∙L⁻¹ KOH + 0.1 mol∙L⁻¹ N₂H₄	77	43
Co-doped Ni₂P	1.0 mol∙L⁻¹ KOH + 0.1 mol∙L⁻¹ N₂H₄	10	44
PdCo nanoparticles into carbon nanofibers	3.0 mol∙L⁻¹ KOH + 0.2 mol∙L⁻¹ N₂H₄	25	45
CoP/Co nanoparticles on carbon layers	1.0 mol∙L⁻¹ KOH + 0.5 mol∙L⁻¹ N₂H₄	−69	46
V-doped Ni₃N nanosheet self-supported on Ni foam	1.0 mol∙L⁻¹ KOH + 0.1 mol∙L⁻¹ N₂H₄	2	47
Low-crystalline Rh metallene	1.0 mol∙L⁻¹ KOH + 0.1 mol∙L⁻¹ N₂H₄	−2	48
RhIr mesoporous nanospheres	1.0 mol∙L⁻¹ KOH + 0.5 mol∙L⁻1 N₂H₄	−12 mV	49

[1]	Yuqiong Li, Bing Lan, Bin Guan, Chunlong Dai, Fan Zhang, Zifeng Lin. Molten Salt Derived Mo₂CT_x MXene with Excellent Catalytic Performance for Hydrogen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2024, 40(9): 2306031-.
[2]	Wei Sun, Yongjing Wang, Kun Xiang, Saishuai Bai, Haitao Wang, Jing Zou, Arramel, Jizhou Jiang. CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2024, 40(8): 2308015-.
[3]	Wenjuan Tan, Yong Ye, Xiujuan Sun, Bei Liu, Jiajia Zhou, Hailong Liao, Xiulin Wu, Rui Ding, Enhui Liu, Ping Gao. Building P-Poor Ni₂P and P-Rich CoP₃ Heterojunction Structure with Cation Vacancy for Enhanced Electrocatalytic Hydrazine and Urea Oxidation [J]. Acta Phys. -Chim. Sin., 2024, 40(6): 2306054-.
[4]	Huasen Lu, Shixu Song, Qisen Jia, Guangbo Liu, Luhua Jiang. Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting [J]. Acta Phys. -Chim. Sin., 2024, 40(2): 2304035-.
[5]	Erjun Lu, Junqian Tao, Can Yang, Yidong Hou, Jinshui Zhang, Xinchen Wang, Xianzhi Fu. Carbon-Encapsulated Pd/TiO₂ for Photocatalytic H₂ Evolution Integrated with Photodehydrogenative Coupling of Amines to Imines [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2211029-0.
[6]	Siran Xu, Qi Wu, Bang-An Lu, Tang Tang, Jia-Nan Zhang, Jin-Song Hu. Recent Advances and Future Prospects on Industrial Catalysts for Green Hydrogen Production in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2209001-0.
[7]	Shuyi Zheng, Jia Wu, Ke Wang, Mengchen Hu, Huan Wen, Shibin Yin. Electronic Modulation of Ni-Mo-O Porous Nanorods by Co Doping for Selective Oxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2023, 39(12): 2301032-.
[8]	Xiaoming Li, Yidan Gao, Qingqiang Kong, Lijing Xie, Zhuo liu, Xiaoqian Guo, Yanzhen Liu, Xianxian Wei, Xiao Yang, Xinghua Zhang, Chengmeng Chen. Fabrication of Three-Dimensional Copper@Graphene Phase Change Composite with High Structural Stability and Low Leakage Rate [J]. Acta Phys. -Chim. Sin., 2022, 38(1): 2012091-.
[9]	Mengting Li, Xingqun Zheng, Li Li, Zidong Wei. Research Progress of Hydrogen Oxidation and Hydrogen Evolution Reaction Mechanism in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2007054-.
[10]	Yufei Bao, Ligang Feng. Formic Acid Electro-Oxidation Catalyzed by PdNi/Graphene Aerogel [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2008031-.
[11]	Yuan Liu, Weidong Li, Han Wu, Siyu Lu. Carbon Dots Enhance Ruthenium Nanoparticles for Efficient Hydrogen Production in Alkaline [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009082-.
[12]	Daqiang Yan, Lin Zhang, Zupeng Chen, Weiping Xiao, Xiaofei Yang. Nickel-Based Metal-Organic Framework-Derived Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution Reactions [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009054-.
[13]	Zengqiang Gao, Congyong Wang, Junjun Li, Yating Zhu, Zhicheng Zhang, Wenping Hu. Conductive Metal-Organic Frameworks for Electrocatalysis:Achievements, Challenges, and Opportunities [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2010025-.
[14]	Jingxuan Ge, Jun Hu, Yingting Zhu, Zonish Zeb, Dejin Zang, Zhaoxian Qin, Yichao Huang, Jiangwei Zhang, Yongge Wei. Recent Advances in Polyoxometalates for Applications in Electrocatalytic Hydrogen Evolution Reaction [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1906063-.
[15]	Zhou LIN,Linfan SHEN,Ximing QU,Junming ZHANG,Yanxia JIANG,Shigang SUN. Molybdenum Carbide Prepared by a Salt Sealing Approach as an Electrocatalyst for Enhanced Hydrogen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 523-530.

RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production

RichHTML

PDF

Like

Supplement

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 51

Related Articles 15

Metrics

Recommended 0