Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

doi:10.3866/PKU.WHXB202312010

Abstract

Abstract:

Cu-Graphdiyne and CoNiWO₄ were synthesized by organic and hydrothermal methods, respectively. The establishment of an S-scheme heterojunction between Cu-Graphdiyne and CoNiWO₄ was achieved by interface engineering design. The efficient separation and transfer of photogenerated carriers are facilitated by the synergistic effect of the built-in electric field and band bending, while maintaining the strong redox capacity of the catalysts. The introduction of Cu-Graphdiyne effectively enhances the photo absorption capacity and conductivity of the composite catalyst, and significantly suppresses the recombination of photogenerated carriers. The unique two-dimensional planar network structure of Cu-Graphdiyne provides abundant active sites for photocatalytic processes, thereby facilitating the photocatalytic reaction. Density functional theory (DFT) calculations demonstrate that hot electrons generated by surface plasmon resonance effects of Cu will transfer to Graphdiyne to promote hydrogen evolution reaction. This study offers insights into potential applications of Cu-Graphdiyne and nickel-cobalt based catalysts in photocatalytic hydrogen evolution.

Key words: Cu-graphdiyne, S-scheme heterojunction, Interface engineering design, Hydrogen evolution reaction, DFT

Zhengyu Zhou, Huiqin Yao, Youlin Wu, Teng Li, Noritatsu Tsubaki, Zhiliang Jin. Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution[J]. Acta Phys. -Chim. Sin. 2024, 40(10), 2312010. doi: 10.3866/PKU.WHXB202312010

Figures/Tables 17

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Photocatalyst	Optical source	Sacrificial reagent	Hydrogen production in 5 h	Reference
GCNW20	LED 5 W	TEOA (15%)	4266 μmol∙g⁻¹	This work
NiS/GDY	LED 5 W	TEOA (15%)	4105 μmol∙g⁻¹	61
Co₃O₄/GDY	LED 5 W	TEOA (15%)	3070 μmol∙g⁻¹	62
GDY@g-C₃N₄/Pt	Solar 100 W	TEOA (15%)	3990 μmol∙g⁻¹	63
CdS/GD	LED	TEOA (0.3 mol∙L⁻¹)	2050 μmol∙g⁻¹	64
GD-CuI-NiTiO₃	LED 5 W	TEOA (15%)	2545 μmol∙g⁻¹	65

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Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

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