新型丝素蛋白膜的结构和热分解动力学机理

doi:10.3866/PKU.WHXB201611023

Abstract

Abstract:

A new CaCl₂-formic acid dissolution method was used to prepare silk fibroin (SF) films. Films SF-1.5 and SF-3.0 were prepared using 1.50% (w, mass fraction) and 3.00% (w) CaCl₂-formic acid solutions, respectively. The molecular conformations and crystal structures of the films were characterized by Fourier transform infrared spectroscopy and X-ray diffraction. The thermal stability, thermal decomposition properties, and effect of CaCl₂ concentration on the thermodynamic parameters, kinetic parameters, and formation mechanism of the SF films were investigated using thermogravimetry techniques and the models of Kissinger, Ozawa, and Vyazovkin. The results showed that the SF-1.5 film mainly contained β-sheet structure, while the main molecular conformation in the SF-3.0 film was random coils. The decomposition temperature, activation energy, and activation enthalpy of SF-3.0 were lower than those of SF-1.5, while the thermal stability of SF-1.5 was higher than that of SF-3.0. In addition, the thermal decomposition of the SF films was studied by the Achar and Coats-Redfern methods. The mechanism of decomposition of these SF films followed the two-dimensional diffusion (cylindrical symmetry) law in the temperature range of 190.00-330.00℃.

Key words: Silk fibroin, Thermal decomposition mechanism, Thermodynamics, Thermogravimetry, Fourier transform infrared spectroscopy

Hai-Yang YU,Fang WANG,Qi-Chun LIU,Qing-Yu MA,Zheng-Gui GU. Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films[J]. Acta Phys. -Chim. Sin. 2017, 33(2), 344-355. doi: 10.3866/PKU.WHXB201611023

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Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films

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