导电金属有机框架材料在电催化中的成就，挑战和机遇

doi:10.3866/PKU.WHXB202010025

Abstract

Abstract:

To fulfill the demands of green and sustainable energy, the production of novel catalysts for different energy conversion processes is critical. Owing to the intriguing advantages of the intrinsic active species, tunable crystal structure, remarkable chemical and physical properties, and good stability, metal-organic frameworks (MOFs) have been extensively investigated in various electrochemical energy conversions, such as the CO₂ reduction reaction, N₂ reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, and oxygen reduction reaction. More importantly, it is feasible to change the chemical environments, pore sizes, and porosity of MOFs, which will theoretically facilitate the diffusion of reactants across the open porous networks, thereby improving the electrocatalytic performance. However, owing to the high energy barriers of charge transfer and limited free charge carriers, most MOFs show poor electrical conductivity, thus limiting their diverse applications. As reported previously, MOFs were used as a porous substrate to confine the growth of nanoparticles or co-doped electrocatalysts after annealing. The conductive MOFs can combine the advantages of conventional MOFs with electronic conductivity, which significantly enhance the electrocatalytic performance. In addition, conductive MOFs can achieve conductivity via electronic or ionic routes without post-annealing treatment, thereby extending their potential applications. Different synthesis strategies have recently been developed to endow MOFs with electrical conductivity, such as post-synthesis modification, guest molecule introduction, and composite formatting. The performance of conductive MOFs can even outperform those of commercial RuO₂ catalysts or Pt-group catalysts. However, it is difficult to endow most MOFs with high conductivity. This review summarizes the mechanisms of constructing conductive MOFs, such as redox hopping, through-bond pathways, through-space pathways, extended conjugation, and guest-promoted transport. Synthetic methods, including hydro/solvothermal synthesis and interface-assisted synthesis, are introduced. Recent advances in the use of conductive MOFs as heterogeneous catalysts in electrocatalysis have been comprehensively elucidated. It has been reported that conductive MOFs can demonstrate considerable catalytic activity, selectivity, and stability in different electrochemical reactions, revealing the immense potential for future displacement of Pt-group catalysts. Finally, the challenges and opportunities of conductive MOFs in electrocatalysis are discussed. Based on systematic synthesis strategies, more conductive MOFs can be constructed for electrocatalytic reactions. In addition, the morphology and structure of conductive MOFs, which can change the electrochemical accessibility between substrates and MOFs, are also crucial for catalysis, and thus, they should be extensively studied in the future. It is believed that a breakthrough for high-performance conductive MOF-based electrocatalysts could be achieved.

Key words: Conductive metal-organic frameworks, Electrocatalysis, CO2 reduction reaction, N2 reduction reaction, Oxygen evolution reaction, Hydrogen evolution reaction, Oxygen reduction reaction

Zengqiang Gao, Congyong Wang, Junjun Li, Yating Zhu, Zhicheng Zhang, Wenping Hu. Conductive Metal-Organic Frameworks for Electrocatalysis:Achievements, Challenges, and Opportunities[J]. Acta Phys. -Chim. Sin. 2021, 37(7), 2010025. doi: 10.3866/PKU.WHXB202010025

Figures/Tables 11

References 121

1	Li H. ; Eddaoudi M. ; O'Keeffe M. ; Yaghi O. M. Nature 1999, 402, 276. doi: 10.1038/46248
2	Tranchemontagne D. J. ; Mendoza-Cortés J. L. ; O'Keeffe M. ; Yaghi O. M. Chem. Soc. Rev. 2009, 38, 1257. doi: 10.1039/B817735J
3	Zhang Z. ; Chen Y. ; Xu X. ; Zhang J. ; Xiang G. ; He W. ; Wang X. Angew. Chem. Int. Ed. 2014, 53, 429. doi: 10.1002/anie.201308589
4	Zhou H.-C. ; Long J. R. ; Yaghi O. M. Chem. Rev 2012, 112, 673. doi: 10.1021/cr300014x
5	Furukawa H. ; Cordova K. E. ; O'Keeffe M. ; Yaghi O. M. Science 2013, 341, 1230444. doi: 10.1126/science.1230444
6	Chen X.-H. ; Wei Q. ; Hong J.-D. ; Xu R. ; Zhou T.-H. Rare Met. 2019, 38, 413. doi: 10.1007/s12598-019-01259-6
7	Bavykina A. ; Kolobov N. ; Khan I. S. ; Bau J. A. ; Ramirez A. ; Gascon J. Chem. Rev 2020, 120, 8468. doi: 10.1021/acs.chemrev.9b00685
8	Wang Y. ; Li Q. ; Shi W. ; Cheng P. Chin. Chem. Lett. 2020, 31, 1768. doi: 10.1016/j.cclet.2020.01.010
9	Zhang K. ; Liang Z. ; Zou R. Sci. China Mater. 2020, 63, 7. doi: 10.1007/s11426-019-9613-1
10	Song Z. ; Zhang L. ; Doyle-Davis K. ; Fu X. ; Luo J.-L. ; Sun X. Adv. Energy Mater. 2020, 10, 2001561. doi: 10.1002/aenm.202001561
11	Zhao M. ; Huang Y. ; Peng Y. ; Huang Z. ; Ma Q. ; Zhang H. Chem. Soc. Rev. 2018, 47, 6267. doi: 10.1039/C8CS00268A
12	Liu J. ; Wöll C. Chem. Soc. Rev. 2017, 46, 5730. doi: 10.1039/C7CS00315C
13	Li B. ; Wen H.-M. ; Cui Y. ; Zhou W. ; Qian G. ; Chen B. Adv. Mater. 2016, 28, 8819. doi: 10.1002/adma.201601133
14	Ding M. ; Flaig R. W. ; Jiang H.-L. ; Yaghi O. M. Chem. Soc. Rev 2019, 48, 2783. doi: 10.1039/C8CS00829A
15	Li J.-R. ; Sculley J. ; Zhou H.-C. Chem. Rev 2012, 112, 869. doi: 10.1021/cr200190s
16	Zhang Z. ; Chen Y. ; He S. ; Zhang J. ; Xu X. ; Yang Y. ; Nosheen F. ; Saleem F. ; He W. ; Wang X. Angew. Chem. Int. Ed 2014, 53, 12517. doi: 10.1002/anie.201406484
17	Dhakshinamoorthy A. ; Asiri A. M. ; Garcia H. Adv. Mater 2019, 31, 1900617. doi: 10.1002/adma.201900617
18	Sun L. ; Campbell M. G. ; Dincă M. Angew. Chem. Int. Ed 2016, 55, 3566. doi: 10.1002/anie.201506219
19	Talin A. A. ; Centrone A. ; Ford A. C. ; Foster M. E. ; Stavila V. ; Haney P. ; Kinney R. A. ; Szalai V. ; El Gabaly F. ; Yoon H.P. ;et al Science 2014, 343, 66. doi: 10.1126/science.1246738
20	Li W.-H. ; Deng W.-H. ; Wang G.-E. ; Xu G. Energy Chem. 2020, 2, 100029. doi: 10.1016/j.enchem.2020.100029
21	Li W. H. ; Ding K. ; Tian H. R. ; Yao M.-S. ; Nath B. ; Deng W.-H. ; Wang Y. ; Xu G. Adv. Funct. Mater 2017, 27, 1702067. doi: 10.1002/adfm.201702067
22	Ko M. ; Mendecki L. ; Mirica K. A. Chem. Commun. 2018, 54, 7873. doi: 10.1039/C8CC02871K
23	Li P. ; Wang B. Isr. J. Chem. 2018, 58, 1010. doi: 10.1002/ijch.201800078
24	Stavila V. ; Talin A. A. ; Allendorf M. D. Chem. Soc. Rev 2014, 43, 5994. doi: 10.1039/C4CS00096J
25	Bhardwaj S. K. ; Bhardwaj N. ; Kaur R. ; Mehta J. ; Sharma A. L. ; Kim K.-H. ; Deep A. J. Mater. Chem. A 2018, 6, 14992. doi: 10.1039/C8TA04220A
26	Clough A. J. ; Yoo J. W. ; Mecklenburg M. H. ; Marinescu S. C. J. Am. Chem. Soc. 2015, 137, 118. doi: 10.1021/ja5116937
27	Miner E. M. ; Fukushima T. ; Sheberla D. ; Sun L. ; Surendranath Y. ; Dincă M. Nat. Commun. 2016, 7, 10942. doi: 10.1038/ncomms10942
28	Miner E. M. ; Wang L. ; Dincă M. Chem. Sci. 2018, 9, 6286. doi: 10.1039/C8SC02049C
29	Cheng W.-Z. ; Liang J.-L. ; Yin H.-B. ; Wang Y.-J. ; Yan W.-F. ; Zhang J.-N. Rare Met. 2020, 39, 815. doi: 10.1007/s12598-020-01440-2
30	Liu X. ; Yue T. ; Qi K. ; Qiu Y. ; Xia B. Y. ; Guo X. Chin. Chem. Lett 2020, 31, 2189. doi: 10.1016/j.cclet.2019.12.009
31	Zhao R. ; Liang Z. ; Zou R. ; Xu Q. Joule 2018, 2, 2235. doi: 10.1016/j.joule.2018.09.019
32	Shinde S. S. ; Lee C. H. ; Jung J.-Y. ; Wagh N. K. ; Kim S.-H. ; Kim D.-H. ; Lin C. ; Lee S. U. ; Lee J.-H. Energy Environ. Sci. 2019, 12, 727. doi: 10.1039/C8EE02679C
33	Liu J. ; Song X. ; Zhang T. ; Liu S. ; Wen H. ; Chen L. Angew. Chem. Int. Ed. 2020, 59, 2. doi: 10.1002/anie.202006102
34	Sheberla D. ; Bachman J. C. ; Elias J. S. ; Sun C.-J. ; Shao-Horn Y. ; Dincă M. Nat. Mater. 2017, 16, 220. doi: 10.1038/nmat4766
35	Du W. ; Bai Y.-L. ; Yang Z. ; Li R. ; Zhang D. ; Ma Z. ; Yuan A. ; Xu J. Chin. Chem. Lett 2020, 31, 2309. doi: 10.1016/j.cclet.2020.04.017
36	Campbell M. G. ; Sheberla D. ; Liu S. F. ; Swager T. M. ; Dincă M. Angew. Chem. Int. Ed 2015, 54, 4349. doi: 10.1002/anie.201411854
37	Campbell M. G. ; Liu S. F. ; Swager T. M. ; Dincă M. J. Am. Chem. Soc 2015, 137, 13780. doi: 10.1021/jacs.5b09600
38	Aubrey M. L. ; Kapelewski M. T. ; Melville J. F. ; Oktawiec J. ; Presti D. ; Gagliardi L. ; Long J. R. J. Am. Chem. Soc 2019, 141, 5005. doi: 10.1021/jacs.9b00654
39	Meng Z. ; Aykanat A. ; Mirica K. A. J. Am. Chem. Soc 2019, 141, 2046. doi: 10.1021/jacs.8b11257
40	Wu G. ; Huang J. ; Zang Y. ; He J. ; Xu G. J. Am. Chem. Soc 2017, 139, 1360. doi: 10.1021/jacs.6b08511
41	Huang X. ; Sheng P. ; Tu Z. ; Zhang F. ; Wang J. ; Geng H. ; Zou Y. ; Di C.-A. ; Yi Y. ; Sun Y. ; Xu W. ; Zhu D. Nat. Commun. 2015, 6, 7408. doi: 10.1038/ncomms8408
42	Lahiri N. ; Lotfizadeh N. ; Tsuchikawa R. ; Deshpande V. V. ; Louie J. J. Am. Chem. Soc 2017, 139, 19. doi: 10.1021/jacs.6b09889
43	Wang B. ; Luo Y. ; Liu B. ; Duan G. ACS Appl. Mater. Interfaces 2019, 11, 35935. doi: 10.1021/acsami.9b14319
44	Song X. ; Wang X. ; Li Y. ; Zheng C. ; Zhang B. ; Di C.-A. ; Li F. ; Jin C. ; Mi W. ; Chen L. ; Hu W. Angew. Chem. Int. Ed 2020, 59, 1118. doi: 10.1002/anie.201911543
45	Zhao W. ; Peng J. ; Wang W. ; Liu S. ; Zhao Q. ; Huang W. Coordin. Chem. Rev. 2018, 377, 44. doi: 10.1016/j.ccr.2018.08.023
46	Dong R. ; Zhang Z. ; Tranca D.C. ; Zhou S. ; Wang M. ; Adler P. ; Liao Z. ; Liu F. ; Sun Y. ; Shi W. ;et al Nat. Commun 2018, 9, 2637. doi: 10.1038/s41467-018-05141-4
47	Yang C. ; Dong R. ; Wang M. ; Petkov P. S. ; Zhang Z. ; Wang M. ; Han P. ; Ballabio M. ; Bräuninger S.A. ; Liao Z. ;et al Nat. Commun. 2019, 10, 3260. doi: 10.1038/s41467-019-11267-w
48	Qiu T. ; Liang Z. ; Guo W. ; Tabassum H. ; Gao S. ; Zou R. ACS Energy Lett. 2020, 5, 520. doi: 10.1021/acsenergylett.9b02625
49	Chu S. ; Majumdar A. Nature 2012, 488, 294. doi: 10.1038/nature11475
50	Liu J. ; Zhu D. ; Guo C. ; Vasileff A. ; Qiao S.-Z. Adv. Energy Mater. 2017, 7, 1700518. doi: 10.1002/aenm.201700518
51	Wang H.-F. ; Chen L. ; Pang H. ; Kaskel S. ; Xu Q. Chem. Soc. Rev. 2020, 49, 1414. doi: 10.1039/C9CS00906J
52	Xie L. ; Skorupskii G. ; Dincă M. Chem. Rev. 2020, 120, 8536. doi: 10.1021/acs.chemrev.9b00766
53	Sheberla D. ; Sun L. ; Blood-Forsythe M. A. ; Er S. ; Wade C. R. ; Brozek C. K. ; Aspuru-Guzik A. ; Dincă M. J. Am. Chem. Soc 2014, 136, 8859. doi: 10.1021/ja502765n
54	Narayan T. C. ; Miyakai T. ; Seki S. ; Dincă M. J. Am. Chem. Soc 2012, 134, 12932. doi: 10.1021/ja3059827
55	Park S. S. ; Hontz E. R. ; Sun L. ; Hendon C. H. ; Walsh A. ; Van Voorhis T. ; Dincă M. J. Am. Chem. Soc. 2015, 137, 1774. doi: 10.1021/ja512437u
56	Xie L. S. ; Alexandrov E. V. ; Skorupskii G. ; Proserpio D. M. ; Dincă M. Chem. Sci 2019, 10, 8558. doi: 10.1039/C9SC03348C
57	Pathak A. ; Shen J.-W. ; Usman M. ; Wei L.-F. ; Mendiratta S. ; Chang Y.-S. ; Sainbileg B. ; Ngue C.-M ; Chen R.-S. ; Hayashi M. ;et al Nat. Commun. 2019, 10, 1721. doi: 10.1038/s41467-019-09682-0
58	Xie L. ; Skorupskii G. ; Dincă M. Chem. Rev 2020, 120, 8536. doi: 10.1021/acs.chemrev.9b00766
59	Makiura R. ; Motoyama S. ; Umemura Y. ; Yamanaka H. ; Sakata O. ; Kitagawa H. Nat. Mater. 2010, 9, 565. doi: 10.1038/nmat2769
60	Dong R. ; Pfeffermann M. ; Liang H. ; Zheng Z. ; Zhu X. ; Zhang J. ; Feng X. Angew. Chem. Int. Ed 2015, 54, 12058. doi: 10.1002/anie.201506048
61	Kambe T. ; Sakamoto R. ; Hoshiko K. ; Takada K. ; Miyachi M. ; Ryu J.-H. ; Sasaki S. ; Kim J. ; Nakazato K. ; Takata M. ;et al J. Am. Chem. Soc. 2013, 135, 2462. doi: 10.1021/ja312380b
62	Pal T. ; Kambe T. ; Kusamoto T. ; Foo M. L. ; Matsuoka R. ; Sakamoto R. ; Nishihara H. ChemPlusChem 2015, 80, 1255. doi: 10.1002/cplu.201500206
63	Sun X. ; Wu K.-H. ; Sakamoto R. ; Kusamoto T. ; Maeda H. ; Ni X. ; Jiang W. ; Liu F. ; Sasaki S. ; Masunaga H. ;et al Chem. Sci 2017, 8, 8078. doi: 10.1039/C7SC02688A
64	Pal T. ; Doi S. ; Maeda H. ; Wada K. ; Tan C. M. ; Fukui N. ; Sakamoto R. ; Tsuneyuki S. ; Sasaki S. ; Nishihara H. Chem. Sci 2019, 10, 5218. doi: 10.1039/C9SC01144G
65	Huang X. ; Li H. ; Tu Z. ; Liu L. ; Wu X. ; Chen J. ; Liang Y. ; Zou Y. ; Yi Y. ; Sun J. ; et al J. Am. Chem. Soc 2018, 140, 15153. doi: 10.1021/jacs.8b07921
66	Sheberla D. ; Bachman J. C. ; Elias J. S. ; Sun C.-J. ; Shao-Horn Y. ; Dincă M. Nat. Mater 2017, 16, 220. doi: 10.1038/nmat4766
67	Du W. ; Bai Y.-L. ; Yang Z. ; Li R. ; Zhang D. ; Ma Z. ; Yuan A. ; Xu J. Chin. Chem. Lett 2020, 31, 2309. doi: 10.1016/j.cclet.2020.04.017
68	Campbell M. G. ; Sheberla D. ; Liu S. F. ; Swager T. M. ; Dincă M. Angew. Chem. Int. Ed 2015, 54, 4349. doi: 10.1002/anie.201411854
69	Campbell M. G. ; Liu S. F. ; Swager T. M. ; Dincă M. J. Am. Chem. Soc. 2015, 137, 13780. doi: 10.1021/jacs.5b09600
70	Dunwell M. ; Lu Q. ; Heyes J. M. ; Rosen J. ; Chen J. G. ; Yan Y. ; Jiao F. ; Xu B. J. Am. Chem. Soc. 2017, 139, 3774. doi: 10.1021/jacs.6b13287
71	Zhao C. ; Dai X. ; Yao T. ; Chen W. ; Wang X. ; Wang J. ; Yang J. ; Wei S. ; Wu Y. ; Li Y. J. Am. Chem. Soc. 2017, 139, 8078. doi: 10.1021/jacs.7b02736
72	Lu Y. ; Zhang J. ; Wei W. ; Ma D. D. ; Wu X. T. ; Zhu Q. L. ACS Appl. Mater. Interfaces 2020, 12, 37986. doi: 10.1021/acsami.0c06537
73	Li X. ; Zhu Q. L. EnergyChem 2020, 2, 100033. doi: 10.1016/j.enchem.2020.100033
74	Ma D. D. ; Zhu Q. L. Coord. Chem. Rev. 2020, 422, 213483. doi: 10.1016/j.ccr.2020.213483
75	Aubrey M. L. ; Kapelewski M. T. ; Melville J. F. ; Oktawiec J. ; Presti D. ; Gagliardi L. ; Long J. R. J. Am. Chem. Soc. 2019, 141, 5005. doi: 10.1021/jacs.9b00654
76	Meng Z. ; Aykanat A. ; Mirica K. A. J. Am. Chem. Soc. 2019, 141, 2046. doi: 10.1021/jacs.8b11257
77	Hod I. ; Sampson M. D. ; Deria P. ; Kubiak C. P. ; Farha O. K. ; Hupp J. T. ACS Catal 2015, 5, 6302. doi: 10.1021/acscatal.5b01767
78	Albo J. ; Vallejo D. ; Beobide G. ; Castillo O. ; Castaño P. ; Irabien A. ChemSusChem 2017, 10, 1100. doi: 10.1002/cssc.201600693
79	Dong B.-X. ; Qian S.-L. ; Bu F.-Y. ; Wu Y.-C. ; Feng L.-G. ; Teng Y.-L. ; Liu W.-L. ; Li Z.-W. ACS Appl. Energy Mater 2018, 1, 4662. doi: 10.1021/acsaem.8b00797
80	Perfecto-Irigaray M. ; Albo J. ; Beobide G. ; Castillo O. ; Irabien A. ; Pérez-Yáñez S. RSC Adv 2018, 8, 21092. doi: 10.1039/C8RA02676A
81	Qiu Y.-L. ; Zhong H.-X. ; Zhang T.-T. ; Xu W.-B. ; Su P.-P. ; Li X.-F. ; Zhang H.-M. ACS Appl. Mater. Interfaces 2018, 10, 2480. doi: 10.1021/acsami.7b15255
82	Kornienko N. ; Zhao Y. ; Kley C. S. ; Zhu C. ; Kim D. ; Lin S. ; Chang C. J. ; Yaghi O. M. ; Yang P. J. Am. Chem. Soc 2015, 137, 14129. doi: 10.1021/jacs.5b08212
83	Guntern Y. T. ; Pankhurst J. R. ; Vávra J. ; Mensi M. ; Mantella V. ; Schouwink P. ; Buonsanti R. Angew. Chem. Int. Ed. 2019, 58, 12632. doi: 10.1002/anie.201905172
84	Wu J.-X. ; Hou S.-Z. ; Zhang X.-D. ; Xu M. ; Yang H.-F. ; Cao P.-S. ; Gu Z.-Y. Chem. Sci 2019, 10, 2199. doi: 10.1039/C8SC04344B
85	Cao C. ; Ma D. D. ; Gu J. F. ; Xie X. ; Zeng G. ; Li X. ; Han S. G. ; Zhu Q. L. ; Wu X. T. ; Xu Q. Angew. Chem. Int. Ed. 2020, 59, 15014. doi: 10.1002/anie.202005577
86	Brezny A. C. ; Johnson S. I. ; Raugei S. ; Mayer J. M. J. Am. Chem. Soc. 2020, 142, 4108. doi: 10.1021/jacs.9b13654
87	Pegis M. L. ; Wise C. F. ; Martin D. J. ; Mayer J. M. Chem. Rev. 2018, 118, 2340. doi: 10.1021/acs.chemrev.7b00542
88	Zhao S. ; Yin H. ; Du L. ; He L. ; Zhao K. ; Chang L. ; Yin G. ; Zhao H. ; Liu S. ; Tang Z. ACS Nano 2014, 8, 12660. doi: 10.1021/nn505582e
89	Lai Q. ; Zheng L. ; Liang Y. ; He J. ; Zhao J. ; Chen J. ACS Catal 2017, 7, 1655. doi: 10.1021/acscatal.6b02966
90	Guo J. ; Li Y. ; Cheng Y. ; Dai L. ; Xiang Z. ACS Nano 2017, 11, 8379. doi: 10.1021/acsnano.7b03807
91	Yin P. ; Yao T. ; Wu Y. ; Zheng L. ; Lin Y. ; Liu W. ; Ju H. ; Zhu J. ; Hong X. ; Deng Z. ; et al Angew. Chem. Int. Ed. 2016, 55, 10800. doi: 10.1002/anie.201604802
92	Liu X.-H. ; Hu W.-L. ; Jiang W.-J. ; Yang Y.-W. ; Niu S. ; Sun B. ; Wu J. ; Hu J.-S. ACS Appl. Mater. Interfaces 2017, 9, 28473. doi: 10.1021/acsami.7b07410
93	Yoon H. ; Lee S. ; Oh S. ; Park H. ; Choi S. ; Oh M. Small 2019, 15, 1805232. doi: 10.1002/smll.201805232
94	Chen G. ; Stevens M. B. ; Liu Y. ; King L. A. ; Park J. ; Kim T. R. ; Bao Z. ; Sinclair R. ; Jaramillo T. F. ; Bao Z. Small Methods 2020, 4, 2000085. doi: 10.1002/smtd.202000085
95	Roger I. ; Shipman M. A. ; Symes M. D. Nat. Rev. Chem. 2017, 1, 1. doi: 10.1038/s41570-016-0003
96	Chen W. ; Pei J. ; He C.-T. ; Wan J. ; Ren H. ; Wang Y. ; Dong J. ; Wu K. ; Cheong W.-C. ; Mao J. ;et al Adv. Mater. 2018, 30, 1800396. doi: 10.1002/adma.201800396
97	Liu T. ; Li P. ; Yao N. ; Cheng G. ; Chen S. ; Luo W. ; Yin Y. Angew. Chem. Int. Ed. 2019, 306, 627. doi: 10.1002/anie.201901409
98	Duan J. ; Chen S. ; Zhao C. Nat. Commun. 2017, 8, 15341. doi: 10.1038/ncomms15341
99	Zheng F. ; Zheng C. ; Gao X. ; Du C. ; Zhang Z. ; Chen W. Electrochim. Acta 2019, 7, 9743. doi: 10.1016/j.electacta.2019.03.175
100	Huang H. ; Zhao Y. ; Bai Y. ; Li F. ; Zhang Y. ; Chen Y. Adv. Sci. 2020, 7, 2000012. doi: 10.1002/advs.202000012
101	Yang C. ; Zhu Y. ; Liu J. ; Qin Y. ; Wang H. ; Liu H. ; Chen Y. ; Zhang Z. ; Hu W. Nano Energy 2020, 77, 105126. doi: 10.1016/j.nanoen.2020.105126
102	Geng Z. ; Liu Y. ; Kong X. ; Li P. ; Li K. ; Liu Z. ; Du J. ; Shu M. ; Si R. ; Zeng J. Adv. Mater 2018, 30, 1803498. doi: 10.1002/adma.201803498
103	Guo C. ; Ran J. ; Vasileff A. ; Qiao S.-Z. Energy Environ. Sci. 2018, 11, 45. doi: 10.1039/C7EE02220D
104	Yuan L. ; Wu Z. ; Jiang W. ; Tang T. ; Niu S. ; Hu J.-S. Nano Res. 2020, 13, 1376. doi: 10.1007/s12274-020-2637-8
105	Abghoui Y. ; Garden A. L. ; Howalt J. G. ; Vegge T. ; Skúlason E. ACS Catal 2016, 6, 635. doi: 10.1021/acscatal.5b01918
106	Fukushima T. ; Drisdell W. ; Yano J. ; Surendranath Y. J. Am. Chem. Soc 2015, 137, 10926. doi: 10.1021/jacs.5b06737
107	Cui Q. ; Qin G. ; Wang W. ; K. R G. ; Du A. ; Sun Q. J. Mater. Chem. A 2019, 7, 14510. doi: 10.1039/C9TA02926E
108	Xiong W. ; Cheng X. ; Wang T. ; Luo Y. ; Feng J. ; Lu S. ; Asiri A. M. ; Li W. ; Jiang Z. ; Sun X. Nano Res. 2020, 13, 1008. doi: 10.1007/s12274-020-2733-9
109	Zhou J. ; Dou Y. ; Zhou A. ; Guo R.-M. ; Zhao M.-J. ; Li J.-R. Adv. Energy Mater. 2017, 7, 1602643. doi: 10.1002/aenm.201602643
110	Li M. ; Xia Z. ; Huang Y. ; Tao L. ; Chao Y. ; Yin K. ; Yang W. ; Yang W. ; Yu Y. ; Guo S. Acta Phys. -Chim. Sin. 2020, 36, 1912049.
	李蒙刚; 夏仲泓; 黄雅荣; 陶璐; 晁玉广; 尹坤; 杨文秀; 杨微微; 于永生; 郭少军; 物理化学学报, 2020, 36, 1912049. doi: 10.3866/PKU.WHXB201912049
111	Zheng F. ; Zhang Z. ; Xiang D. ; Li P. ; Du C. ; Zhuang Z. ; Li X. ; Chen W. J. Colloid Interf. Sci. 2019, 555, 541. doi: 10.1016/j.jcis.2019.08.005
112	Shen J.-Q. ; Liao P.-Q. ; Zhou D.-D. ; He C.-T. ; Wu J.-X. ; Zhang W.-X. ; Zhang J.-P. ; Chen X.-M. J. Am. Chem. Soc 2017, 139, 1778. doi: 10.1021/jacs.6b12353
113	Wang L. ; Wu Y. ; Cao R. ; Ren L. ; Chen M. ; Feng X. ; Zhou J. ; Wang B. ACS Appl. Mater. Interfaces 2016, 8, 16736. doi: 10.1021/acsami.6b05375
114	Zhao S. ; Wang Y. ; Dong J. ; He C.-T. ; Yin H. ; An P. ; Zhao K. ; Zhang X. ; Gao C. ; Zhang L. ;et al Nat. Energy 2016, 1, 16184. doi: 10.1038/nenergy.2016.184
115	Lu X.-F. ; Liao P.-Q. ; Wang J.-W. ; Wu J.-X. ; Chen X.-W. ; He C.-T. ; Zhang J.-P. ; Li G.-R. ; Chen X.-M. J. Am. Chem. Soc. 2016, 138, 8336. doi: 10.1021/jacs.6b03125
116	Cao C. ; Ma D. D. ; Xu Q. ; Wu X. T. ; Zhu Q. L. Adv. Funct. Mater. 2019, 29, 1807418. doi: 10.1002/adfm.201807418
117	Li X. ; Ma D. D. ; Cao C. ; Zou R. ; Xu Q. ; Wu X. T. ; Zhu Q. L. Small 2019, 15, 1902218. doi: 10.1002/smll.201902218
118	Zheng F. ; Zhang C. ; Gao X. ; Du C. ; Zhuang Z. ; Chen W. Electrochim. Acta 2019, 306, 627. doi: 10.1016/j.electacta.2019.03.175
119	Liu J. ; Zhu D. ; Guo C. ; Vasileff A. ; Qiao S.-Z. Adv. Energy Mater. 2017, 7, 1700518. doi: 10.1002/aenm.201700518
120	Zheng F. ; Zhang Z. ; Zhang C. ; Zhang C. ; Chen W. ACS Omega 2020, 5, 2495. doi: 10.1021/acsomega.9b03295
121	Centi G. SmartMat 2020, e1005. doi: 10.1002/smm2.1005

Type	Catalyst	Electrolyte	Potential	FE	Ref.
CO₂RR	Fe_MOF-525 films	1.0 mol·L^-1 TBAPF₆ + 1 mol·L^-1 TFE	-1.3 V vs. NHE	∼100% (CO + H₂)	77
	HKUST-1 (Cu, Ru)	0.5 mol·L^-1 KHCO₃	-1.0 V vs. Ag/AgCl	47.2% (alcohol)	80
	Al₂(OH)₂TCPP-Co	0.5 mol·L^-1 potassium carbonate	-0.7 V vs. RHE	76% (CO)	82
	Ag@Al-PMOFs	0.1 mol·L^-1 KHCO₃	-1.1 V vs. RHE	55.8% (CO)	83
	Cu₂(CuTCPP)	0.5 mol·L^-1 EMIMBF₄	-1.55 V vs. Ag/Ag⁺	68.4% (formate); 16.8% (acetate)	84
	bismuthine (Bi-ene)	1 mol·L^-1 KOH	-0.57V vs. RHE	99.8% (formate)	85
ORR	Ni₃(HITP)₂	0.1 mol·L^-1 KOH	∼0.75 V vs. RHE	63% (H₂O₂)	27
	(Co)PCN222	0.1 mol·L^-1 HClO₄	0.43V vs. RHE		94
NRR	Mo₃(HAB)₂		0.18 V		107
	Co₃(HHTP)₂	0.5 mol·L^-1 LiClO₄	–0.40 V vs. RHE	3.34%	108
OER	{Fe₃(μ₃-O)(bdc)₃}₄{Co₂(na)₄(L^T)₂}₃	water at pH = 13	225 mV		112
	Fe/Ni-BTC	0.1 mol·L^-1 KOH	270 mV	95%	113
	NiCo-UMOFNs	1.0 mol·L^-1 KOH	∼189 mV	99.3%	114
	MAF-X27-OH(Cu)	1.0 mol·L^-1 KOH	292 mV	100%	115
	NiFe-NFF	1.0 mol·L^-1 KOH	227 mV	~100%	116
	NiFe MOF/OM-NFH	1.0 mol·L^-1 KOH	270 mV		117
HER	NiFe-MOF	0.1 mol·L^-1 KOH	240 mV		98
	Pd@MOF-74	0.5 mol·L^-1 H₂SO₄	-0.106 V vs. RHE		99
	Ni₃(Ni₃·HAHATN)₂	0.1 mol·L^-1 KOH	115 mV		100

[1]	Hanyu Xu, Xuedan Song, Qing Zhang, Chang Yu, Jieshan Qiu. Mechanistic Insights into Water-Mediated CO₂ Electrochemical Reduction Reactions on Cu@C₂N Catalysts: A Theoretical Study [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303040-.
[2]	Xinxuan Duan, Marshet Getaye Sendeku, Daoming Zhang, Daojin Zhou, Lijun Xu, Xueqing Gao, Aibing Chen, Yun Kuang, Xiaoming Sun. Tungsten-Doped NiFe-Layered Double Hydroxides as Efficient Oxygen Evolution Catalysts [J]. Acta Phys. -Chim. Sin., 2024, 40(1): 2303055-.
[3]	Weifeng Xia, Chengyu Ji, Rui Wang, Shilun Qiu, Qianrong Fang. Metal-Free Tetrathiafulvalene Based Covalent Organic Framework for Efficient Oxygen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212057-0.
[4]	Ning Wang, Yi Li, Qian Cui, Xiaoyue Sun, Yue Hu, Yunjun Luo, Ran Du. Metal Aerogels: Controlled Synthesis and Applications [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212014-0.
[5]	Rong Hu, Liyun Wei, Jinglin Xian, Guangyu Fang, Zhiao Wu, Miao Fan, Jiayue Guo, Qingxiang Li, Kaisi Liu, Huiyu Jiang, Weilin Xu, Jun Wan, Yonggang Yao. Microwave Shock Process for Rapid Synthesis of 2D Porous La_0.2Sr_0.8CoO₃ Perovskite as an Efficient Oxygen Evolution Reaction Catalyst [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212025-0.
[6]	Yanhui Yu, Peng Rao, Suyang Feng, Min Chen, Peilin Deng, Jing Li, Zhengpei Miao, Zhenye Kang, Yijun Shen, Xinlong Tian. Atomic Co Clusters for Efficient Oxygen Reduction Reaction [J]. Acta Phys. -Chim. Sin., 2023, 39(8): 2210039-0.
[7]	Chang Lan, Yuyi Chu, Shuo Wang, Changpeng Liu, Junjie Ge, Wei Xing. Research Progress of Proton-Exchange Membrane Fuel Cell Cathode Nonnoble Metal M-N_x/C-Type Oxygen Reduction Catalysts [J]. Acta Phys. -Chim. Sin., 2023, 39(8): 2210036-0.
[8]	Shuai Yang, Yuxin Xu, Zikun Hao, Shengjian Qin, Runpeng Zhang, Yu Han, Liwei Du, Ziyi Zhu, Anning Du, Xin Chen, Hao Wu, Bingbing Qiao, Jian Li, Yi Wang, Bingchen Sun, Rongrong Yan, Jinjin Zhao. Recent Advances in High-Efficiency Perovskite for Medical Sensors [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2211025-0.
[9]	Aoqi Wang, Jun Chen, Pengfei Zhang, Shan Tang, Zhaochi Feng, Tingting Yao, Can Li. Relation between NiMo(O) Phase Structures and Hydrogen Evolution Activities of Water Electrolysis [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2301023-0.
[10]	Yifei Xu, Hanwen Yang, Xiaoxia Chang, Bingjun Xu. Introduction to Electrocatalytic Kinetics [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2210025-0.
[11]	Erjun Lu, Junqian Tao, Can Yang, Yidong Hou, Jinshui Zhang, Xinchen Wang, Xianzhi Fu. Carbon-Encapsulated Pd/TiO₂ for Photocatalytic H₂ Evolution Integrated with Photodehydrogenative Coupling of Amines to Imines [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2211029-0.
[12]	Yang Hu, Bin Liu, Luyao Xu, Ziqiang Dong, Yating Wu, Jie Liu, Cheng Zhong, Wenbin Hu. High-Throughput Synthesis and Screening of Pt-Based Ternary Electrocatalysts Using a Microfluidic-Based Platform [J]. Acta Phys. -Chim. Sin., 2023, 39(3): 2209004-0.
[13]	Siran Xu, Qi Wu, Bang-An Lu, Tang Tang, Jia-Nan Zhang, Jin-Song Hu. Recent Advances and Future Prospects on Industrial Catalysts for Green Hydrogen Production in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2209001-0.
[14]	Ruifang Wei, Dongfeng Li, Heng Yin, Xiuli Wang, Can Li. Operando Electrochemical UV-Vis Absorption Spectroscopy with Microsecond Time Resolution [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2207035-0.
[15]	Tianran Wei, Shusheng Zhang, Qian Liu, Yuan Qiu, Jun Luo, Xijun Liu. Oxygen Vacancy-Rich Amorphous Copper Oxide Enables Highly Selective Electroreduction of Carbon Dioxide to Ethylene [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2207026-0.

Conductive Metal-Organic Frameworks for Electrocatalysis:Achievements, Challenges, and Opportunities

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 121

Related Articles 15

Metrics

Recommended 0