花瓣状微球MoS2/石墨烯复合材料的制备及其电化学性能

doi:10.3866/PKU.WHXB201408043

Abstract

Abstract:

MoS₂/graphene composites were synthesized using L-cysteine and sodium molybdate as the sources of sulfur and molybdenum, and L-cysteine was found to be beneficial for two-dimensional layered structure formation. Polyvinylpyrrolidone (PVP)-assisted hydrothermal synthesis gave petal-shaped MoS₂/ reduction of graphene oxide (RGO) composite electrode materials (PVP-MoS₂/RGO). X-ray diffraction and transmission electron microscopy confirmed that MoS₂ changed to a less ordered layer structure from the multilayer stacking structure after moderate addition of PVP. Scanning electron microscopy showed that the moderate PVP-assisted MoS₂/RGO material had a petal-shaped microsphere morphology with good dispersion. The ordered stacking structure with less layers and good dispersion of the composite materials shorten the embedded in/out path of lithium ions in MoS₂, which obviously improved their capacity, cycle stability, and rate performance as lithium ion battery anode materials.

Key words: Petal shaped microsphere, PVP-MoS₂/RGO, Capacity, Cycle stability, Rate performance

ZHANG Chuan-Xiang, ZHANG Xiao-Xue, TAO Hai-Jun. Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres[J]. Acta Phys. -Chim. Sin. 2014, 30(10), 1963-1969. doi: 10.3866/PKU.WHXB201408043

References

(1) Zhu, Z.; Qi, L.; Li,W.; Liao, X. Y. Acta Phys. -Chim. Sin. 2014, 30 (4), 669. [朱智, 其鲁, 李卫, 廖细英. 物理化学学报, 2014, 30 (4), 669.] doi: 10.3866/PKU.WHXB201402102
(2) Pan, A.; Zhu, T.;Wu, H. B.; Lou, X.W. Chem. Eur. J. 2013, 19(2), 494. doi: 10.1002/chem.201203596
(3) Yoshino, A. Angew . Chem. Int. Edit. 2012, 51 (24), 5798. doi: 10.1002/anie.v51.24
(4) Pan, A.;Wu, H. B.; Yu, L.; Lou, X.W. Angew. Chem. 2013, 125 (8), 2282. doi: 10.1002/ange.201209535
(5) Yang,W. C.; Bi, Y. J.; Yang, B. C.;Wang, D. Y.; Shi, S. Q. Acta Phys. -Chim. Sin. 2014, 30 (3), 460. [杨文超, 毕玉敬, 杨邦成, 王德宇, 施思齐. 物理化学学报, 2014, 30 (3), 460.] doi: 10.3866/PKU.WHXB201401074
(6) Ji, L.; Lin, Z.; Alcoutlabi, M.; Zhang, X. Energy Environ. Sci. 2011, 4(8), 2682. doi: 10.1039/c0ee00699h
(7) Xiao, J.;Wang, X.; Yang, X. Q.; Xun, S.; Liu, G.; Koech, P. K.; Liu, J.; Lemmon, J. P. Adv. Funct. Mater. 2011, 21 (15), 2840. doi: 10.1002/adfm.201002752
(8) Liu, H.; Su, D.; Zhou, R.; Sun, B.;Wang, G.; Qiao, S. Advanced Energy Materials 2012, 2(8), 970. doi: 10.1002/aenm.v2.8
(9) Ding, S.; Chen, J. S.; Lou, X.W. Chem. Eur. J. 2011, 17 (47), 13142. doi: 10.1002/chem.201102480
(10) Jiang, Z.;Wang, C.; Du, G.; Zhong, Y. J.; Jiang, J. Z. J . Mater. Chem. 2012, 22 (19), 9494. (11) Luo, B.; Fang, Y.;Wang, B.; Zhou, J.; Song, H.; Zhi, L. Energy Environ. Sci. 2012, 5(1), 5226. doi: 10.1039/c1ee02800f
(12) Liu, H.; Su, D.;Wang, G.; Qiao, S. J. Mater. Chem. 2012, 22 (34), 17437. doi: 10.1039/c2jm33992g
(13) Bhandavat, R.; David, L.; Singh, G. J. Phys. Chem. Lett. 2012, 3 (11), 1523. doi: 10.1021/jz300480w
(14) Lynden, A. J. Mater. Chem. 2012, 22 (26), 12988. doi: 10.1039/c2jm32468g
(15) Ding, S.; Zhang, D.; Chen, J. S.; Lou, X.W. Nanoscale 2012, 4 (1), 95. doi: 10.1039/c1nr11552a
(16) Zhang, C.;Wu, H. B.; Guo, Z.; Lou, X.W. Electrochem. Commun. 2012, 20, 7. doi: 10.1016/j.elecom.2012.03.039
(17) Chang, K.; Chen,W. ACS Nano 2011, 5 (6), 4720. doi: 10.1021/nn200659w
(18) Subba Reddy, C. V.; Jin, A. P.; Han, X.; Zhu, Q. Y.; Mai, L. Q.; Chen,W. Electrochem. Commun. 2006, 8 (2), 279. doi: 10.1016/j.elecom.2005.11.025
(19) Kumar, P. R.; Venkateswarlu, M.; Satyanarayana, N. J. Appl. Electrochem. 2012, 42 (3), 163. doi: 10.1007/s10800-012-0383-7
(20) Li, Q.; Li, M.; Chen, Z.; Li, C. Mater. Res. Bull. 2004, 39, 981. doi: 10.1016/j.materresbull.2004.03.017
(21) Joensen, P.; Frindt, R. F.; Morrison, S. R. Mater. Res. Bull. 1986, 21, 457. doi: 10.1016/0025-5408(86)90011-5
(22) Tao, H.; Yanagisawa, K.; Zhang, C.; Ueda, T.; Onda, A.; Li, N.; Shou, T.; Kamiya, S.; Tao. J. CrystEngComm. 2012, 14, 3027. doi: 10.1039/c2ce06543f
(23) Shi, H. Q.; Fu, X.; Zhou, X. D.;Wang, D. B.; Hu, Z. S. J. Solid State Chem. 2006, 179, 1690. doi: 10.1016/j.jssc.2006.02.030
(24) Peng, Y. Y.; Meng, Z. Y.; Zhong, C.; Lu, J.; Yang, Z. P.; Qian, Y. T. Mater. Chem. Phys. 2002, 73, 327. doi: 10.1016/S0254-0584(01)00364-9
(25) Tian, H.; Zhang, L.; Xu, Y.;Wu, D.;Wu, Z. H.; Lü, H. B.; Yuan, X. D. Acta Phys. -Chim. Sin. 2012, 28 (5), 1197. [田红, 张磊, 徐耀, 吴东, 吴忠华, 吕海兵, 袁晓东. 物理化学学报, 2012, 28 (5), 1197.] doi: 10.3866/PKU.WHXB201202231
(26) Py, M. A.; Haering, R. R. Can. J. Phys. 1983, 61 (1), 76. doi: 10.1139/p83-013
(27) Xu, L.; Ding, Y. S.; Chen, C. H.; Zhao, L. L.; Rimkus, C.; Joesten, R.; Suib, S. L. Chem. Mater. 2007, 20 (1), 308. (28) Mulhern, P. J. Can. J. Phys. 1989, 67 (11), 1049. doi: 10.1139/p89-184
(29) Hwang, H.; Kim, H.; Cho, J. Nano Lett. 2011, 11 (11), 4826.doi: 10.1021/nl202675f
(30) Zhou, X. S.;Wan, L. J.; Guo, Y. G. Nanoscale 2012, 4, 5868. doi: 10.1039/c2nr31822a
(31) Zhou, X.;Wang, Z.; Chen,W.; Ma, L.; Chen, D.; Lee, J. Y. J. Power Sources 2014, 251, 264. doi: 10.1016/j.jpowsour.2013.11.060
(32) Fang, X.; Yu, X.; Liao, S.; Shi, Y.; Hu, Y.;Wang, Z.; Stucky, G. D.; Chen, L. Microporous Mesoporous Mater. 2012, 151, 418. doi: 10.1016/j.micromeso.2011.09.032
(33) Miki, Y.; Nakazato, D.; Ikuta, H.; Uchida, T.;Wakihara, M. J. Power Sources 1995, 54 (2), 508. doi: 10.1016/0378-7753(94)02136-Q
(34) Liu, L.; Fan, Q.; Sun, C.; Gu, X.; Li, H.; Gao, F.; Chen, Y.; Dong, L. J. Power Sources 2013, 221, 141. doi: 10.1016/j.jpowsour.2012.07.105
(35) Rui, X.; Lu, Z.; Yu, H.; Yang, D.; Hng, H. H.; Lim, T. M.; Yan, Q. Nanoscale 2013, 5 (2), 556. doi: 10.1039/c2nr33422d
(36) Wang, H.; Liu, S.; Ren, Y.;Wang,W.; Tang, A. Energy Environ. Sci. 2012, 5 (3), 6173. doi: 10.1039/c2ee03215e
(37) Pan, A.; Zhang, J. G.; Cao, G.; Liang, S.;Wang, C.; Nie, Z.; Arey, B.W.; Xu,W.; Liu, D.; Xiao, J.; Li, G.; Liu, J. J. Mater. Chem. 2011, 21 (27), 10077. doi: 10.1039/c1jm10976f

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Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres

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Synthesis and Electrochemical Properties of MoS₂/Graphene Composites with Petal-Shaped Microspheres