高倍率性能锂离子电池Li[Ni1/3Co1/3Mn1/3]O2正极材料的制备及其电化学性能

doi:10.3866/PKU.WHXB201503091

Abstract

Abstract:

A spherical Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode material for lithium-ion batteries was synthesized using a combination of modified carbonate co-precipitation and solid-state methods. The as-prepared material was analyzed using X- ray diffractometry (XRD), scanning electron microscopy (SEM), galvanostatic chargedischarge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results indicate that the material synthesized using this new method has a well-ordered layered structure, α-NaFeO₂ [space group: R3m(166)], a spherical morphology, and an average particle size of 157 nm. Electrochemical measurements showed that the material has a good rate capability and long-term cycling performance. At a current density of 0.1C (1.0C=180mA·g^-1) in the voltage range 2.7-4.3 V, the initial discharge capacity was 156.4 mAh·g^-1 and the coulombic efficiency was 81.9%. At 0.5C, 5C, and 20C, the specific capacities of the material were 136.9, 111.3, and 81.3 mAh·g^-1, respectively. After 100 cycles at 1C, the material retained 92.9% of its initial capacity; this is higher than those of materials prepared using conventional carbonate co-precipitation (87.0%).

Key words: Lithium-ion battery, Cathode material, Li[Ni_1/3Co_1/3Mn_1/3]O₂, Rate capacity, Modified carbonate co-precipitation

ZHANG Ji-Bin, HUAWei-Bo, ZHENG Zhuo, LIU Wen-Yuan, GUO Xiao-Dong, ZHONG Ben-He. Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin. 2015, 31(5), 905-912. doi: 10.3866/PKU.WHXB201503091

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Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries

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Preparation and Electrochemical Performance of Li[Ni1/3Co1/3Mn1/3]O2 Cathode Material for High-Rate Lithium-Ion Batteries

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Preparation and Electrochemical Performance of Li[Ni_1/3Co_1/3Mn_1/3]O₂ Cathode Material for High-Rate Lithium-Ion Batteries