一种精密恒温环境微量燃烧-溶解-反应多用量热计的设计及应用

doi:10.3866/PKU.WHXB201702213

Abstract

Abstract:

The SRC-100 type solution-reaction calorimeter was improved to a more precise and versatile isoperibol combustion-solution-reaction microcalorimeter. The energy equivalent of the calorimeter was calibrated to be C_calor=(987.63±0.61) J·K^-1 by the electric calibration method. The standard massic energy of combustion of benzoic acid and succinic acid were determined by the developed isoperibol combustion-solution-reaction microcalorimeter as △_cU_{m, B}^θ(cr, T=298.15K)=-(26425.99±10.70) J·g^-1 and △_cU_{m, S}^θ(cr, T=298.15K)=-(12621.97±5.30) J·g^-1, respec-tively. The uncertainty of the measurement was less than 0.04% and the accuracy was higher than 0.05%.

Key words: Combustion-solution-reaction microcalorimeter, Standard massic energy of combustion, Benzoic acid, Succinic acid

Xu LI,Qiang-Guo LI,Jian-Hong JIANG,Hui-Wen GU,Chuan-Hua LI,Sheng-Xiong XIAO,Xia LI. Design and Application of a Precise Isoperibol Combus-tion-Solution-Reaction Microcalorimeter[J]. Acta Phys. -Chim. Sin. 2017, 33(6), 1114-1122. doi: 10.3866/PKU.WHXB201702213

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Design and Application of a Precise Isoperibol Combus-tion-Solution-Reaction Microcalorimeter

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