Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (09): 847-851.doi: 10.3866/PKU.WHXB19940915

• Note • Previous Articles     Next Articles

Synthesis and Crystal Structure of Rh2(μ-SC6H5)2(CO)4

Wu Bing-Fang, Su Hai-Quan, Yan Xiu-Ying, Hu Xiang, Liu Shu-Tang, Liu Qi-Wang, Shi Jian-Qiu   

  1. Department of Chemsitry,Nei Monggu University,Huhehot 010021|Fujian Institute of Research of the Structure of Matter,Academia Sinica,Fuzhou 350002
  • Received:1993-04-27 Revised:1993-10-04 Published:1994-09-15
  • Contact:

PDF

2902

Like

Abstract:

 The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoclinic, space group P21/a, a=17.390(8), b=8.983(9),c=24.35(2)Å, β =103.84(4); V=3693(5)Å3, Z=8, DC=1.93g.cm-3. R=0.057, RW=0.064, The intramolecular Rh-Rh distances are 3.090 and 3.078Å respectively.

Key words: Dinuclear rhodium carbonyl, Bridging thiolate ligand, Crystal structure