“三明治式”多层Au/Pt复合薄膜的制备及其对甲醇的电氧化

doi:10.3866/PKU.WHXB20110803

Abstract

Abstract:

Pt/Au composite monolayer films were fabricated by combining interfacial assembly and under-potential deposition (UPD) with redox replacement. Based on the Pt/Au composite monolayers, an organic linker-free method was proposed for the fabrication of sandwich-like Pt/Au composite multilayer films: (Pt/Au)_n, Pt_m/Au, and (Pt₃/Au)_k (n, m, or k represents the layer number). Electron microscopy was used to characterize the morphologies of the Au monolayer films and the Pt/Au composite multilayer films. For each type of composite multilayer films, a common characteristic was that the effective electroactive areas increased with an increase in the layer number. Additionally, the electrocatalytic activities of the composite multilayer films for methanol electrooxidation are systematically discussed by examining the catalytic current densities and its tolerance toward carbonaceous species. For the same series of composite multilayer films (Pt/Au)₃, Pt₃/Au, and (Pt₃/Au)₂ showed a higher catalytic current density than bulk Pt (Pt_bulk). Among the three composite multilayer films, (Pt/Au)₃ showed the best catalytic performance in terms of the current density and tolerance toward carbonaceous species. The tolerance of (Pt/Au)₃ to carbonaceous species was found to be better than that of the commercial Pt/C catalyst. This better electrocatalytic activity may be attributed to the maximum synergistic effect between Au and Pt, which depends on the Pt:Au atomic ratio and also the arrangement of Pt and Au nanoparticles.

Key words: Interfacial self-assembly, Under-potential deposition, Au/Pt composite multilayer film, Electrooxidation, Methanol

ZHAO Jing, SUN Yue, LI Yong-Jun, LIANG Ren. Preparation of ‘Sandwich-Like’ Au/Pt Composite Multilayer Films for Methanol Electrooxidation[J]. Acta Phys. -Chim. Sin. 2011, 27(08), 1868-1874. doi: 10.3866/PKU.WHXB20110803

References

(1) Steele, B. C. H.; Heinzel, A. Nature 2001, 414, 345.
(2) Liu, H. S.; Song, C. J.; Zhang, L.; Zhang, J. J.;Wang, H. J.; Wilkinson, D. P. J. Power Sources 2006, 155, 95.
(3) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245.
(4) Iwasita, T.; Hoster, H.; John-Anacker, A.; Lin,W. F.; Vielstich, W. Langmuir 1999, 16, 522.
(5) Liu, Z.; Reed, D.; Kwon, G. M.; Shamsuzzoha, D.; Nikles, E. J. Phys. Chem. C 2007, 111, 14223.
(6) Zhou, S. G.; McIlwrath, K.; Jackson, G.; Eichhorn, B. J. Am. Chem. Soc. 2006, 128, 1780.
(7) Guo, S. J.; Zhai, J. F.; Fang, Y.X.; Dong, S. J.;Wang, E. Chem. Asian J. 2008, 3, 1156.
(8) Zhao, D.; Xu, B. Q. Angew. Chem. Int. Edit. 2006, 45, 4955.
(9) Kiani, A.; Fard, E. N. Electrochim. Acta 2009, 54, 7254.
(10) Du, Y.; Xu, J. J.; Chen, H. Y. Electrochem. Commun. 2009, 11, 1717.
(11) Wang, J. J.; Yin, G. P.;Wang, G. J.;Wang, Z. B.; Gao, Y. Z. Electrochem. Commun. 2008, 10, 831.
(12) Markovic, N. M.; Ross, P. N. Surf. Sci. Rep. 2002, 45, 117.
(13) Mott, D.; Luo, J.; Njoki, P. N.; Lin, Y.;Wang, L. Y.; Zhong, C. J. Catal. Today 2007, 122, 378.
(14) Zeng, J. H.; Yang, J.; Lee, J. Y.; Zhou,W. J. J. Phys. Chem. B 2006, 110, 24606.
(15) Zhang, J. L.; Vukmirovic, M. B.; Sasaki, K.; Nilekar, A. U.; Mavrikakis, M.; Adzic, R. R. J. Am. Chem. Soc. 2005, 127, 12480.
(16) Zhang, J. L.; Vukmirovic, M. B.; Xu, Y.; Mavrikakis, M.; Adzic, R. R. Angew. Chem. Int. Edit. 2005, 44, 2132.
(17) Du, B. C.; Tong,Y. Y. J. Phys. Chem. B 2005, 109, 17775.
(18) Hammer, B.; Morikawa, Y.; Norskov, J. K. Phys. Rev. Lett. 1996, 76, 2141.
(19) Hammer, B.; Norskov, J. K. Adv. Catal. 2000, 45, 71.
(20) Park, S.; Yang, P.; Corredor, P.;Weaver, M. J. J. Am. Chem. Soc. 2002, 124, 2428.
(21) Aramata, A.; Modern Aspects of Electrochemistry, Vol. 31; Bockris, J. O. M.; White, R. E.; Conway, B. E. Eds, Kluwer Academic Publishers: New York, 1998; pp 181-250.
(22) Tang, H.; Chen, J. H.;Wang, M. Y.; Nie, L. H.; Kuang,Y. F.; Yao, S. Z. Appl. Catal. A 2004, 275, 43.
(23) Shin, T. Y.; Yoo, S. H.; Park, S. Chem. Mater. 2008, 20, 5682.
(24) Liu, P. P.; Ge, X. B.;Wang, R. Y.; Ma, H. Y.; Ding,Y. Langmuir 2009, 25, 561.
(25) Park, I. S.; Lee, K. S.; Choi, J. H.; Park, H. Y.; Sung,Y. E. J. Phys. Chem. C 2007, 111, 19126.
(26) Ge, X.;Wang, R.; Liu, P.; Ding,Y. Chem. Mater. 2007, 19, 5827.
(27) Kumar, S.; Zou, S. Z. Langmuir 2007, 23, 7365.
(28) Patra, S.; Das, J.; Yang, H. Electrochim. Acta 2009, 54, 3441.
(29) Huang, M.; Jin, Y.; Jiang, H.; Sun, X.; Chen, H.; Liu, B.;Wang, E.; Dong, S. J. Phys. Chem. B 2005, 109, 15264.
(30) Li, Y. J.; Huang,W. J.; Sun, S. G. Angew. Chem. Int. Edit. 2006, 45, 2537.
(31) Liu, C.; Li, Y. J.;Wang, M. H.; He, Y.; Yeung, E. S. Nanotechnology 2009, 20, 065604.
(32) Wang, M. H.; Li, Y. J.; Xie, Z. X.; Liu, C.; Yeung, E. S. Mater. Chem. Phys. 2010, 119, 153.
(33) Wang, M. H.; Hu, J.W.; Li, Y. J.; Yeung, E. S. Nanotechnology 2010, 21, 145608.
(34) Li, Y. J.; Liu, C.; Yang, M. H.; He, Y.; Yeung, E. S. J. Electroanal. Chem. 2008, 622, 103.
(35) Frens, G. Nat. Phys. Sci. 1973, 241, 20.
(36) Uosaki, K.; Ye, S.; Naohara, H.; Oda, Y.; Haba, T.; Kondo, T. J. Phys. Chem. B 1997, 101, 7566.
(37) Kolb, D. M. Adv. Electrochem. Electrochem. Eng. 1978, 11, 125.
(38) Mrozek, M. F.; Xie, Y.;Weaver, M. J. Anal. Chem. 2001, 73, 5953.
(39) Brankovic, S. R.;Wang, J. X.; Adzic, R. R. Surf. Sci. 2001, 474, L173.
(40) Maillard, F.; Eikerling, M.; Cherstiouk, O. V.; Schreier, S.; Savinova, E.; Stimming, U. Faraday Discuss. 2004, 125, 357.
(41) Mayrhofer, K. J. J.; Arenz, M.; Blizanac, B. B.; Stamenkovic, V.; Ross, P. N.; Markovic, N. M. Electrochim. Acta 2005, 50, 5144.
(42) Arenz, M.; Mayrhofer, K. J. J.; Stamenkovic, V.; Blizanac, B. B.; Tomoyuki, T.; Ross, P. N.; Markovic, N. M. J. Am. Chem. Soc. 2005, 127, 6819.
(43) Biegler, T.; Rand, D. A. J.;Woods, R. J. Electroanal. Chem. 1971, 29, 269.
(44) Liu, Z.; Ling, X. Y.; Su, X.; Lee, J. Y. J. Phys. Chem. B 2004, 108, 8234.
(45) Chang, S. C.; Ho, Y.;Weaver, M. J. Surf. Sci. 1992, 265, 81.
(46) Park, S.; Xie, Y.;Weaver, M. J. Langmuir 2002, 18, 5792.
(47) Zhang, J.; Lima, F. H. B.; Shao, M. H.; Sasaki, K.;Wang, J. X.; Hanson, J.; Adzic, R. R. J. Phys. Chem. B 2005, 109, 22701.
(48) Zhang, J.; Mo, Y.; Vukmirovic, M. B.; Klie, R.; Sasaki, K.; Adzic, R. R. J. Phys. Chem. B 2004, 108, 10955.

[1]	Meng Li, Fulin Yang, Jinfa Chang, Alex Schechter, Ligang Feng. MoP-NC Nanosphere Supported Pt Nanoparticles for Efficient Methanol Electrolysis [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2301005-0.
[2]	Jie Wang, Guigao Liu, Qinbai Yun, Xichen Zhou, Xiaozhi Liu, Ye Chen, Hongfei Cheng, Yiyao Ge, Jingtao Huang, Zhaoning Hu, Bo Chen, Zhanxi Fan, Lin Gu, Hua Zhang. Epitaxial Growth of Unconventional 4H-Pd Based Alloy Nanostructures on 4H-Au Nanoribbons towards Highly Efficient Electrocatalytic Methanol Oxidation [J]. Acta Phys. -Chim. Sin., 2023, 39(10): 2305034-.
[3]	Ying Liu, Xiaofang Liu, Lin Xia, Chaojie Huang, Zhaoxuan Wu, Hui Wang, Yuhan Sun. Methanol Synthesis by CO_x Hydrogenation over Cu/ZnO/Al₂O₃ Catalyst via Hydrotalcite-Like Precursors: the Role of CO in the Reactant Mixture [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2002017-.
[4]	Lin Lv, Liyang Zhang, Xuebing He, Hong Yuan, Shuxin Ouyang, Tierui Zhang. Energy-Efficient Hydrogen Production via Electrochemical Methanol Oxidation Using a Bifunctional Nickel Nanoparticle-Embedded Carbon Prism-Like Microrod Electrode [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2007079-.
[5]	Congming Li, Kuo Chen, Xiaoyue Wang, Nan Xue, Hengquan Yang. Understanding the Role of Cu/ZnO Interaction in CO₂ Hydrogenation to Methanol [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009101-.
[6]	Yanqiu Wang, Zixin Zhong, Tangkang Liu, Guoliang Liu, Xinlin Hong. Cu@UiO-66 Derived Cu⁺-ZrO₂ Interfacial Sites for Efficient CO₂ Hydrogenation to Methanol [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2007089-.
[7]	Menggang Li, Zhonghong Xia, Yarong Huang, Lu Tao, Yuguang Chao, Kun Yin, Wenxiu Yang, Weiwei Yang, Yongsheng Yu, Shaojun Guo. Rh-Doped PdCu Ordered Intermetallics for Enhanced Oxygen Reduction Electrocatalysis with Superior Methanol Tolerance [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 1912049-.
[8]	Zhenmin Xu, Zhenfeng Bian. Photocatalytic Methane Conversion [J]. Acta Phys. -Chim. Sin., 2020, 36(3): 1907013-.
[9]	Hanlin Lyu, Bing Hu, Guoliang Liu, Xinlin Hong, Lin Zhuang. Inverse Decoration of ZnO on Small-Sized Cu/Sio₂ with Controllable Cu-ZnO Interaction for CO₂ Hydrogenation to Produce Methanol [J]. Acta Physico-Chimica Sinica, 2020, 36(11): 1911008-.
[10]	Shuyi ZHANG,Jingxian BAO,Bo WU,Liangshu ZHONG,Yuhan SUN. Research Progress on the Photocatalytic Conversion of Methane and Methanol [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 923-939.
[11]	Jincheng GUO,Yanfen LIN,Na TIAN,Shigang SUN. Modification of Tetrahexahedral Pd Nanocrystals with Ru and Their Performance for Methanol Electro-oxidation [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 749-754.
[12]	Yazhi YIN,Bing HU,Guoliang LIU,Xiaohai ZHOU,Xinlin HONG. ZnO@ZIF-8 Core-Shell Structure as Host for Highly Selective and Stable Pd/ZnO Catalysts for Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(3): 327-336.
[13]	Yanfang LIU,Bing HU,Yazhi YIN,Guoliang LIU,Xinlin HONG. One-Pot Surfactant-Free Synthesis of Transition Metal/ZnO Nanocomposites for Catalytic Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 223-229.
[14]	Yanliang ZHAI, Shaolong ZHANG, Luoming ZHANG, Yunshan SHANG, Wenxuan WANG, Yu SONG, Caitong JIANG, Yanjun GONG. Effect of B and Al Distribution in ZSM-5 Zeolite on Methanol to Propylene Reaction Performance [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1248-1258.
[15]	Yanhui YI,Xunxun WANG,Li WANG,Jinhui YAN,Jialiang ZHANG,Hongchen GUO. Plasma-Triggered CH₃OH/NH₃ Coupling Reaction for Synthesis of Nitrile Compounds [J]. Acta Phys. -Chim. Sin., 2018, 34(3): 247-255.

Preparation of ‘Sandwich-Like’ Au/Pt Composite Multilayer Films for Methanol Electrooxidation

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0