非对称性Janus粒子的制备与可控组装

doi:10.3866/PKU.WHXB201208222

Abstract

Abstract:

Janus particles have different or asymmetric hemispheres both in structure and chemical properties. These particles have attracted increasing attention because of their unique characteristics and potential in applications as drug carriers, electronic components, and stabilizers for emulsions. Controlled fabrication of organized aggregates using these Janus particles as novel building blocks is becoming well concerned. Several assembly strategies, including bulk, interfacial and environmental modulated organization, have been developed based on the amphiphilic modification and functionality of Janus particles. This review summarizes recent progress on the preparation, modification, and assembly techniques for Janus particles. Some novel methods, including one-step synthesis, self-assembly of polymers, and seed directed growth, are discussed in detail and compared. Trends for designing new functional Janus particles and their potential applications are identified.

Key words: Janus particle, Surface modification, Asymmetry, Amphiphilicity, Assembly

YANG Yi, YE Wei, CHEN Xiao. Preparation and Controlled Assembly of Asymmetric Janus Particles[J]. Acta Phys. -Chim. Sin. 2012, 28(11), 2525-2535. doi: 10.3866/PKU.WHXB201208222

References

(1) De Gennes, P. G. Angew. Chem. Int. Edit. 1992, 31, 842.doi: 10.1002/(ISSN)1521-3773
(2) Binks, B. P. Curr. Opinion Colloid Interface Sci. 2002, 7, 21.doi: 10.1016/S1359-0294(02)00008-0
(3) Takei, H.; Shimizu, N. Langmuir 1997, 13, 1865.
(4) Liang, F. X.; Liu, J. G.; Zhang, C. G.; Qu, X. Z.; Li, J. L.; Yang,Z. Z. Chem. Commun. 2011, 47, 1231. doi: 10.1039/c0cc03599h
(5) Tanaka, T.; Okayama, M.; Minami, H.; Okubo, M. Langmuir2010, 26, 11732. doi: 10.1021/la101237c
(6) Liu, Y.; Li,W.; Perez, T.; Gunton, J. D.; Brett, G. Langmuir2012, 28, 3. doi: 10.1021/la2032303
(7) Choi, J. S. ; Jun, Y.W.; Yeon, S. I.; Kim, H. C.; Shin, J. S.;Cheon, J.W. J. Am. Chem. Soc. 2006, 128, 15982. doi: 10.1021/ja066547g
(8) Jiang, S.; Chen, Q.; Tripathy, M.; Luijten, E.; Schweizer, K. S.;Granick, S. Adv. Mater. 2010, 22, 1060. doi: 10.1002/adma.200904094
(9) Howse, J. R.; Jones, R. A.; Ryan, A. J.; Gough, T.; Vafabakhsh,R.; Golestanian, R. Phys. Rev. Lett. 2007, 99, 048102. doi: 10.1103/PhysRevLett.99.048102
(10) Dupont, J.; Liu, G. J. Soft Matter 2010, 6, 3654. doi: 10.1039/c0sm00044b
(11) Tanaka, T.; Okayama, M.; Kitayama, Y.; Kagawa, Y.; Okubo, M.Langmuir 2010, 26, 7843. doi: 10.1021/la904701r
(12) Wang, Q.; Yang, X. L.; Yang, Y. J.; Xu, H. B. Chin. J. Appl. Chem. 2010, 27, 745. [王芹, 杨祥良, 杨亚江, 徐辉碧. 应用化学, 2010, 27, 745.]
(13) Chen, Y. H.;Wang, C. Y.; Li, Y.; Tong, Z. Prog. Chem. 2009, 21,615. [陈云华, 王朝阳, 李煜, 童真. 化学进展, 2009, 21,615.]
(14) Lattuada, M.; Hatton, T. A. Nano Today 2011, 6, 286. doi: 10.1016/j.nantod.2011.04.008
(15) Kim, S. H.; Lim, J. M.; Lee, S. K.; Heo, C. J.; Yang, S. M. Soft Matter 2010, 6, 1092. doi: 10.1039/b920611f
(16) Yuan, Y.; Zhang, M. Z.; Zhang, H.; Ni, P. H. Acta Chim. Sin.2010, 68, 1537. [袁媛, 张明祖, 张虎, 倪沛红. 化学学报, 2010, 68, 1537.]
(17) Lee, R. S.;Wu, K. P. J. Polymer Sci. Part A 2011, 49, 3163.doi: 10.1002/pola.24753
(18) Perro, A.; Reculusa, S.; Ravaine, S.; Lami, E. B.; Duguet, E.J. Mater. Chem. 2005, 15, 3745. doi: 10.1039/b505099e
(19) Erhardt, R.; Böker, A.; Zettl, H.; Kaya, H.; Hintzen,W. P.;Krausch, G.; Abetz, V.; Müller, A. Macromolecules 2001, 34,1069. doi: 10.1021/ma000670p
(20) Liu, Y. F.; Abetz, V.; Müller, A. Macromolecules 2003, 36, 7894.doi: 10.1021/ma0345551
(21) Walther, A.; André, X.; Drechsler, M.; Abetz, V.; Müller, A. H.E. J. Am. Chem. Soc. 2007, 129, 6187. doi: 10.1021/ja068153v
(22) Walther, A.; Drechsler, M.; Müller, A. H. E. Soft Matter 2009, 5,385. doi: 10.1039/b812321g
(23) Yu, H.; Chen, M.; Rice, P. M.;Wang, S. X.; White, R. L.; Sun,S. H. Nano Lett. 2005, 5, 378.
(24) Wang, C.;Wei, Y. J.; Jiang, H. Y.; Sun, S. H. Nano Lett. 2009, 9,4544. doi: 10.1021/nl903077t
(25) Huang, J. M.; Sun, Y. H.; Huang, S. H.; Yu, K.; Zhao, Q.; Peng,F.; Yu, H.;Wang, H. J.; Yang, J. J. Mater. Chem. 2011, 21,17930. doi: 10.1039/c1jm13045e
(26) Kuang, H, M.; Deng, Z. X.; Li, C. H.; Sun, X. M.; Zhuang, J.;Li, Y. D. Acta Phys. -Chim. Sin. 2002, 18, 477. [匡汉茂, 邓兆祥, 李春辉, 孙晓明, 庄京, 李亚栋. 物理化学学报, 2002, 18,477.] doi: 10.3866/PKU.WHXB20020520
(27) Mokari, T.; Sztrum, C. G.; Salant, A.; Rabani, E.; Banin, U. Nat. Mater. 2005, 4, 855. doi: 10.1038/nmat1505
(28) Maynadié, J.; Salant, A.; Falqui, A.; Respaud, M.; Shaviv, E.;Banin, U.; Soulantica, K.; Chaudret, B. Angew. Chem . Int. Edit.2009, 48, 1814. doi: 10.1002/anie.v48:10
(29) Wang, C.; Daimon, H.; Sun, S. H. Nano Lett. 2009, 9, 1493. doi: 10.1021/nl8034724
(30) Habas, S. E.; Lee, H.; Yang, P. Nat. Mater. 2007, 6, 692. doi: 10.1038/nmat1957
(31) Shi,W. L.; Zeng, H.; Sahoo, Y.; Ohulchanskyy, T. Y.; Ding, Y.;Wang, Z. L.; Swihart, M.; Prasad, P. N. Nano Lett. 2006, 6, 875.doi: 10.1021/nl0600833
(32) Gu, H.W.; Zheng, R. K.; Zhang, X. X.; Xu, B. J. Am. Chem. Soc. 2004, 126, 5664. doi: 10.1021/ja0496423
(33) Gu, H.W.; Yang, Z. M.; Gao, J. H.; Chang, C. K.; Xu, B. J. Am. Chem. Soc. 2005, 127, 34. doi: 10.1021/ja045220h
(34) Hong, L.; Jiang, S.; Granick, S. Langmuir 2006, 22, 9495.doi: 10.1021/la062716z
(35) Jiang, S.; Granick, S. Langmuir 2008, 24, 2438. doi: 10.1021/la703274a
(36) Liu, B.; Zhang, C. L.; Liu, J. G.;Qu, X. Z.; Yang, Z. Z. Chem. Commun. 2009, 3871.
(37) Liu, B.;Wei,W.; Qu, X. Z.; Yang, Z. Z. Angew. Chem. Int. Edit.2008, 47, 3973.
(38) Suzuki, D.; Tsuji, S.; Kawaguchi, H. J. Am. Chem. Soc. 2007,129, 8088. doi: 10.1021/ja072258w
(39) Duan, C. Y.; Zhou, J. F.;Wu, Z. S.; Dang, H. X. Acta Phys. -Chim. Sin. 2003, 19, 1049. [段春英, 周静芳, 吴志申,党鸿辛. 物理化学学报, 2003, 19, 1049.] doi: 10.3866/PKU.WHXB20031113
(40) Wang, B. B.; Li, B.; Zhao, B.; Li, C. Y. J. Am. Chem. Soc. 2008,130, 11594. doi: 10.1021/ja804192e
(41) Zhang, L.; Zhang, F.; Dong,W. F.; Song, J. F.; Huo, Q. S.; Sun,H. B. Chem. Commun. 2011, 47, 1225. doi: 10.1039/c0cc03946b
(42) Li, Z. T.; Cheng, E. J.; Huang,W. X.; Zhang, T.; Yang, Z. Q.;Liu, D. S.; Tang, Z. Y. J. Am. Chem. Soc. 2011, 133, 15284.doi: 10.1021/ja205712a
(43) Chen, T.; Yang, M. X.;Wang, X. J.; Tan, L. H.; Chen, H. Y.J. Am. Chem. Soc. 2008, 130, 11858. doi: 10.1021/ja8040288
(44) Chen, T.; Chen, G.; Xing, S. G.;Wu, T.; Chen, H. Y. Chem. Mater. 2010, 22, 3826. doi: 10.1021/cm101155v
(45) Jiang, S.; Schultz, M. J.; Chen, Q.; Moore, J. S.; Granick, S.Langmuir 2008, 24, 10073. doi: 10.1021/la800895g
(46) Perro, A.; Reculusa, S.; Pereira, F.; Delville, M. H.; Mingotaud,C.; Duguet, E.; Lami, E. B.; Ravaine, S. Chem. Commun. 2005,5542.
(47) Liu, L. Y.; Ren, M.W.; Yang,W. T. Langmuir 2009, 25, 11048.doi: 10.1021/la901364a
(48) Teo, B. M.; Suh, S. K.; Hatton, T. A.; Ashokkumar, M.; Grieser,F. Langmuir 2011, 27, 30. doi: 10.1021/la104284v
(49) Liang, F. X.; Shen, K.; Qu, X. Z.; Zhang, C. L.;Wang, Q.; Li, J.L.; Liu, J. G.; Yang, Z. Z.; Angew. Chem. Int. Edit. 2011, 123,2427.
(50) Hong, L.; Cacciuto, A.; Luijten, E.; Granick, S. Langmuir 2008,24, 621. doi: 10.1021/la7030818
(51) Dendukuri, D.; Hatton, T. A.; Doyle, P. S. Langmuir 2007, 23,4669. doi: 10.1021/la062512i
(52) Biji, P.; Sarangi, N. K.; Patnaik, A. Langmuir 2010, 26, 14047.doi: 10.1021/la102371v
(53) Chen, Q.; Whitmer, J. K.; Jiang, S.; Bae, S. C.; Luijten, E.;Granick, S. Science 2011, 331, 199. doi: 10.1126/science.1197451
(54) Rosenthal, G.; Gubbins, K, E.; Klapp, S. H. L. J. Chem. Phys.2012, 136, 174901. doi: 10.1063/1.4707954
(55) Zhao, N. N.; Liu, K.; Greener, J.; Nie, Z.; Kumacheva, E. Nano Lett. 2009, 9, 3077. doi: 10.1021/nl901567a
(56) Zhao, N. N.; Vickery, J.; Guerin, G.; Park, J. I.;Winnik, M. A.;Kumacheva, E. Angew. Chem. Int. Edit. 2011, 50, 4606. doi: 10.1002/anie.201004915
(57) Herrikhuyzen, J. V.; Portale, G.; Gielen, J. C.; Christianen, P. C.M.; Sommerdijk, N. A. J. M.; Meskers, S. C. J.; Schenning, A.P. H. J. Chem. Commun. 2008, 697.
(58) Nørgaard, K.;Weygand, M.; Kjaer, K.; Brust, M.; Bjørnholm, T.Faraday Discuss. 2004, 125, 221. doi: 10.1039/b303117a
(59) Xu, Q.; Kang, X.W.; Bogomolni, R. A.; Chen, S.W. Langmuir2010, 26, 14923. doi: 10.1021/la102540n
(60) He, J.; Hourwitz, M. J.; Liu, Y. J.; Perez, M. T.; Nie, Z. H.Chem. Commun. 2011, 47, 12450. doi: 10.1039/c1cc15603a
(61) Guo, Y. Y.; Saei, S. H.; Izumi, C. M. S.; Moffitt, M. G. ACS Nano 2011, 3309.
(62) Cheng, L.; Zhang, G. Z.; Zhu, L.; Dao, Y.; Chen, D. Y.; Jiang,M. Angew. Chem. Int. Edit. 2008, 47, 10171. doi: 10.1002/anie.v47:52
(63) Walther, A.; Drechsler, M.; Rosenfeldt, S.; Harnau, L.; Ballauff,M.; Abetz, V.; Müller, A. H. E. J. Am. Chem. Soc. 2009, 131,4720. doi: 10.1021/ja808614q
(64) Isojima, T.; Lattuada, M.; Vander Sande, J. B.; Hatton, T. A.ACS Nano 2008, 9, 1799.
(65) Binks, B. P.; Lumsdon, S. O. I. Langmuir 2001, 17, 4540. doi: 10.1021/la0103822
(66) Jiang, S.; Granick, S. J. Chem. Phys. 2007, 127, 161102. doi: 10.1063/1.2803420
(67) Cheung, D. L.; Bon, S. Soft Matter 2009, 5, 3969. doi: 10.1039/b908462b
(68) Miller,W. L.; Cacciuto, A. Phys. Rev. E 2009, 80, 1539.
(69) Yang, M.;Wang,W.; Lieberwirth, I.;Wegner, G. J. Am. Chem. Soc. 2009, 131, 6283. doi: 10.1021/ja900739e
(70) Brugarolas, T.; Park, B. J.; Lee, M. H.; Lee, D. Adv. Funct. Mater. 2011, 21, 3924. doi: 10.1002/adfm.v21.20
(71) Sashuk, V.; Holyst, R.;Wojciechowski, T.; Fialkowski, M.J. Colloid Interface Sci. 2012, 375, 180. doi: 10.1016/j.jcis.2012.02.057
(72) Ruhland, T. M.; Gröschel, A. H.;Walther, A.; Müller, A.Langmuir 2011, 27, 9807. doi: 10.1021/la201863x
(73) Park, B. J.; Brugarolas, T.; Lee, D. Soft Matter 2011, 7, 6413.doi: 10.1039/c1sm05460k
(74) Wang, Y. Z.; Fan, D. Q.; He, J. P.; Yang, Y. L. Colloid Polym. Sci. 2011, 289, 1885. doi: 10.1007/s00396-011-2506-9
(75) Virgilio, N.; Favis, B. D. Macromolecules 2011, 44, 5850. doi: 10.1021/ma200647t
(76) Yin, Y. Y.; Zhou, S. X.; You, B.;Wu, L. M. J. Polym. Sci. Part A2011, 49, 3272. doi: 10.1002/pola.v49.15
(77) Gangwal, S.; Cayre, O. J.; Velev, O. D. Langmuir 2008, 24,13312.
(78) Kretzschmar, I.; Song, J. H. Curr. Opin. Colloid Interface Sci.2011, 16, 84. doi: 10.1016/j.cocis.2011.01.002
(79) Yuet, K. P.; Hwang, D. K.; Haghgooie, R.; Doyle, P. S.Langmuir 2010, 26, 4281. doi: 10.1021/la903348s
(80) Smoukov, S. K.; Gangwal, S.; Marquez, M.; Velev, O. D. Soft Matter 2009, 5, 1285. doi: 10.1039/b814304h
(81) Ren, B.; Ruditskiy, A.; Song, J. H.; Kretzschmar, I. Langmuir2012, 28, 1149. doi: 10.1021/la203969f

[1]	Xin Zhou, Yiting Huo, Songyu Yang, Bowen He, Xiaojing Wang, Zhen Wu, Jianjun Zhang. Understanding the effect of pH on protonated COF during photocatalytic H₂O₂ production by femtosecond transient absorption spectroscopy [J]. Acta Phys. -Chim. Sin., 2025, 41(12): 100160-.
[2]	Jiayao Wang, Guixu Pan, Ning Wang, Shihan Wang, Yaolin Zhu, Yunfeng Li. Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production [J]. Acta Phys. -Chim. Sin., 2025, 41(12): 100168-.
[3]	Qianwen Han, Tenglong Zhu, Qiuqiu Lü, Mahong Yu, Qin Zhong. Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell [J]. Acta Phys. -Chim. Sin., 2025, 41(1): 100005-.
[4]	Renjie Xue, Chao Ma, Jing He, Xuechao Li, Yanning Tang, Lifeng Chi, Haiming Zhang. Catassembly in the Host-Guest Recognition of 2D Metastable Self-Assembled Networks [J]. Acta Phys. -Chim. Sin., 2024, 40(9): 2309011-.
[5]	Shijie Ren, Mingze Gao, Rui-Ting Gao, Lei Wang. Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting [J]. Acta Phys. -Chim. Sin., 2024, 40(7): 2307040-.
[6]	Youwen Rong, Jiaqi Sang, Li Che, Dunfeng Gao, Guoxiong Wang. Designing Electrolytes for Aqueous Electrocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2212027-0.
[7]	Erjun Lu, Junqian Tao, Can Yang, Yidong Hou, Jinshui Zhang, Xinchen Wang, Xianzhi Fu. Carbon-Encapsulated Pd/TiO₂ for Photocatalytic H₂ Evolution Integrated with Photodehydrogenative Coupling of Amines to Imines [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2211029-0.
[8]	Jingwen Zhang, Hualong Ma, Jun Ma, Meixue Hu, Qihao Li, Sheng Chen, Tianshu Ning, Chuangxin Ge, Xi Liu, Li Xiao, Lin Zhuang, Yixiao Zhang, Liwei Chen. Cone Shaped Surface Array Structure on an Alkaline Polymer Electrolyte Membrane Improves Fuel Cell Performance [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2111037-0.
[9]	Ye Fan, Chongmei Cao, Yun Fang, Yongmei Xia. Fabrication of Fluorescent Nanodots by Self-Crosslinking Ufasomes of Conjugated Linoleic Acid and Their Unique Fluorescence Properties [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2002032-.
[10]	Meihui Jiang, Lizhi Sheng, Chao Wang, Lili Jiang, Zhuangjun Fan. Graphene Film for Supercapacitors: Preparation, Foundational Unit Structure and Surface Regulation [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2012085-.
[11]	Tao Liang, Bin Wang. Interlayer Covalently Enhanced Graphene Materials: Construction, Properties, and Applications [J]. Acta Phys. -Chim. Sin., 2022, 38(1): 2011059-.
[12]	Liliang Tian, Weiqi Zhang, Zheng Xie, Kai Peng, Qiang Ma, Qian Xu, Sivakumar Pasupathi, Huaneng Su. Enhanced Performance and Durability of High-Temperature Polymer Electrolyte Membrane Fuel Cell by Incorporating Covalent Organic Framework into Catalyst Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009049-.
[13]	Jujia Zhang, Jin Zhang, Haining Wang, Yan Xiang, Shanfu Lu. Advancement in Distribution and Control Strategy of Phosphoric Acid in Membrane Electrode Assembly of High-Temperature Polymer Electrolyte Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2010071-.
[14]	Yunfeng Li, Min Zhang, Liang Zhou, Sijia Yang, Zhansheng Wu, Ma Yuhua. Recent Advances in Surface-Modified g-C₃N₄-Based Photocatalysts for H₂ Production and CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2009030-.
[15]	Dunfeng Gao, Pengfei Wei, Hefei Li, Long Lin, Guoxiong Wang, Xinhe Bao. Designing Electrolyzers for Electrocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009021-.

Preparation and Controlled Assembly of Asymmetric Janus Particles

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0